CA1041037A - Methode de fabrication du cuivre electrolytique - Google Patents
Methode de fabrication du cuivre electrolytiqueInfo
- Publication number
- CA1041037A CA1041037A CA218,933A CA218933A CA1041037A CA 1041037 A CA1041037 A CA 1041037A CA 218933 A CA218933 A CA 218933A CA 1041037 A CA1041037 A CA 1041037A
- Authority
- CA
- Canada
- Prior art keywords
- copper
- slurry
- sulfide
- solids
- liquid phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010949 copper Substances 0.000 title claims abstract description 64
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 58
- 230000008569 process Effects 0.000 title claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000002002 slurry Substances 0.000 claims abstract description 50
- 239000003792 electrolyte Substances 0.000 claims abstract description 25
- 238000002386 leaching Methods 0.000 claims abstract description 20
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 claims abstract description 18
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 37
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 31
- 239000007787 solid Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000007791 liquid phase Substances 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 230000003472 neutralizing effect Effects 0.000 claims description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 10
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 6
- 230000036961 partial effect Effects 0.000 claims description 6
- 230000002829 reductive effect Effects 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 229910052785 arsenic Inorganic materials 0.000 claims description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- -1 calcium arsenates Chemical class 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 230000000717 retained effect Effects 0.000 claims description 3
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 3
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 claims description 2
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 claims description 2
- 238000010936 aqueous wash Methods 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- ZOCLAPYLSUCOGI-UHFFFAOYSA-M potassium hydrosulfide Chemical compound [SH-].[K+] ZOCLAPYLSUCOGI-UHFFFAOYSA-M 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 230000008719 thickening Effects 0.000 claims description 2
- 229960005069 calcium Drugs 0.000 claims 6
- 235000001465 calcium Nutrition 0.000 claims 6
- 235000019628 coolness Nutrition 0.000 claims 1
- 229920000136 polysorbate Polymers 0.000 claims 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims 1
- 229910052979 sodium sulfide Inorganic materials 0.000 claims 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 11
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 abstract description 7
- 239000012141 concentrate Substances 0.000 abstract description 7
- 229910052951 chalcopyrite Inorganic materials 0.000 abstract description 6
- 230000008021 deposition Effects 0.000 abstract description 6
- 238000005188 flotation Methods 0.000 abstract description 3
- 239000002562 thickening agent Substances 0.000 description 11
- 229960000355 copper sulfate Drugs 0.000 description 7
- 235000019738 Limestone Nutrition 0.000 description 6
- 239000006028 limestone Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 229910052925 anhydrite Inorganic materials 0.000 description 5
- 235000008504 concentrate Nutrition 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052595 hematite Inorganic materials 0.000 description 3
- 239000011019 hematite Substances 0.000 description 3
- 238000009854 hydrometallurgy Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005363 electrowinning Methods 0.000 description 2
- 229960004887 ferric hydroxide Drugs 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- SMNDYUVBFMFKNZ-UHFFFAOYSA-N 2-furoic acid Chemical compound OC(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-N 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002311 subsequent effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0086—Treating solutions by physical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44631474 US3917519A (en) | 1974-02-27 | 1974-02-27 | Process for the manufacture of electrolytic copper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1041037A true CA1041037A (fr) | 1978-10-24 |
Family
ID=23772125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA218,933A Expired CA1041037A (fr) | 1974-02-27 | 1975-01-29 | Methode de fabrication du cuivre electrolytique |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3917519A (fr) |
| JP (1) | JPS5817814B2 (fr) |
| AU (1) | AU7791975A (fr) |
| CA (1) | CA1041037A (fr) |
| DE (1) | DE2505417A1 (fr) |
| GB (1) | GB1484976A (fr) |
| PH (1) | PH10724A (fr) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4225571A (en) | 1979-03-09 | 1980-09-30 | Berenice Isabelle de Denus | Electrowinning of metal from sulphide ores and recovery of water soluble sulphides |
| JPS5825050B2 (ja) * | 1979-07-16 | 1983-05-25 | 住友金属鉱山株式会社 | 複合銅−砒素化合物の製造方法 |
| US4364773A (en) * | 1980-12-23 | 1982-12-21 | Marcel Veronneau | Waste metal conversion process and products |
| US4606764A (en) * | 1983-08-17 | 1986-08-19 | Resource Technology Associates | Method of recovering metals from ores using a formate reducing agent |
| AP538A (en) * | 1992-06-26 | 1996-09-18 | Intec Pty Ltd | Production of metal from minerals |
| US5431788A (en) * | 1993-06-28 | 1995-07-11 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical copper extraction |
| KR950014070B1 (ko) * | 1993-11-08 | 1995-11-21 | 엘지금속주식회사 | 전기동(電氣銅) 생산시 발생되는 폐전해액의 처리방법 |
| US5573739A (en) * | 1994-10-28 | 1996-11-12 | Noranda, Inc. | Selective bismuth and antimony removal from copper electrolyte |
| US5535992A (en) * | 1995-03-07 | 1996-07-16 | Goro Nickel S.A. | Apparatus and method for acidic leaching of lateritic ores |
| US5783057A (en) * | 1996-09-19 | 1998-07-21 | Nippon Mining & Metals Co., Ltd. | Method of purifying copper electrolytic solution |
| US6497745B2 (en) * | 2000-07-25 | 2002-12-24 | Phelps Dodge Corporation | Method for processing elemental sulfur-bearing materials using high temperature pressure leaching |
| US7476308B2 (en) * | 2001-07-25 | 2009-01-13 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US20050126923A1 (en) * | 2001-07-25 | 2005-06-16 | Phelps Dodge Corporation | Process for recovery of copper from copper-bearing material using medium temperature pressure leaching, direct electrowinning and solvent/solution extraction |
| US6451089B1 (en) * | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Process for direct electrowinning of copper |
| FI20060712A7 (fi) * | 2004-01-07 | 2006-09-15 | Hydromet Pty Ltd | Eksotermiset paineliuotusautoklaavin kierrot |
| BRPI0419190A (pt) * | 2004-10-29 | 2008-01-22 | Phelps Dodge Corp | método de recuperar cobre a partir de um material cuprìfero |
| WO2006049632A1 (fr) * | 2004-10-29 | 2006-05-11 | Phelps Dodge Corporation | Procede de recuperation de cuivre a partir d'un materiau renfermant du cuivre au moyen de lixiviation sous pression, electroextraction directe et extraction par solvant/solution |
| US7736487B2 (en) * | 2004-10-29 | 2010-06-15 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction |
| US20060117908A1 (en) * | 2004-12-03 | 2006-06-08 | Virnig Michael J | Processes for recovering metals from ores using organic solvent extraction and aqueous stripping at selected temperature differentials |
| DE602007013737D1 (de) * | 2006-05-01 | 2011-05-19 | Freeport Mcmoran Corp | Verfahren zur kupfergewinnung aus kupferhaltigem material mittels drucklaugung, direkter elektrogewinnung und lösemittel-/lösunsgextraktion |
| JP5423046B2 (ja) * | 2009-02-26 | 2014-02-19 | 住友金属鉱山株式会社 | 硫化銅鉱物を含む銅原料の浸出方法 |
| JP5760954B2 (ja) * | 2011-10-31 | 2015-08-12 | 住友金属鉱山株式会社 | 銅及び鉄を含有する硫化鉱物から銅を回収する方法 |
| FI125693B (en) * | 2013-02-08 | 2016-01-15 | Outotec Oyj | Method and Arrangement to Reduce Autoflash and Slurry Migration in Autoclave Flash Systems |
| PE20180808A1 (es) * | 2015-07-06 | 2018-05-09 | Sherritt Int Corporation | Recuperacion de cobre de una alimentacion de proceso que contiene arsenico |
| PE20191621A1 (es) | 2017-04-14 | 2019-11-06 | Sherritt Int Corporation | Lixiviacion oxidativa presurizada, de bajo contenido de solidos y baja acidez de materiales de alimentacion sulfurados |
| CN109261346B (zh) * | 2018-08-23 | 2020-12-04 | 北京矿冶科技集团有限公司 | 一种含易浮钙镁矿物铜钴矿的选矿方法 |
| CN111485118B (zh) * | 2020-04-14 | 2022-05-06 | 长沙有色冶金设计研究院有限公司 | 一种硫化铜精矿控温氧压平行浸出回收电积铜的方法 |
| CN114561542B (zh) * | 2022-02-25 | 2024-02-02 | 盛隆资源再生(无锡)有限公司 | 一种提高含铁铜废液中铜回收率的方法 |
| KR102703301B1 (ko) * | 2023-11-14 | 2024-09-06 | 고려아연 주식회사 | 구리를 회수하는 방법 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3637371A (en) * | 1967-02-10 | 1972-01-25 | Sherritt Gordon Mines Ltd | Direct pressure leaching of copper-iron sulphides |
-
1974
- 1974-02-27 US US44631474 patent/US3917519A/en not_active Expired - Lifetime
-
1975
- 1975-01-29 GB GB384675A patent/GB1484976A/en not_active Expired
- 1975-01-29 CA CA218,933A patent/CA1041037A/fr not_active Expired
- 1975-02-05 AU AU77919/75A patent/AU7791975A/en not_active Expired
- 1975-02-07 PH PH16784A patent/PH10724A/en unknown
- 1975-02-08 DE DE19752505417 patent/DE2505417A1/de active Pending
- 1975-02-26 JP JP50023794A patent/JPS5817814B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AU7791975A (en) | 1976-08-05 |
| JPS5817814B2 (ja) | 1983-04-09 |
| US3917519A (en) | 1975-11-04 |
| DE2505417A1 (de) | 1975-08-28 |
| PH10724A (en) | 1977-08-25 |
| JPS50121112A (fr) | 1975-09-22 |
| GB1484976A (en) | 1977-09-08 |
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