CA1043617A - Photothermographic and thermographic element, composition and process - Google Patents

Photothermographic and thermographic element, composition and process

Info

Publication number: CA1043617A
Authority: CA; Canada
Prior art keywords: toner; thione; heterocyclic; silver salt; silver
Prior art date: 1974-05-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA223,845A

Other languages

English (en)

French (fr)

Other versions

CA223845S (en

Inventor

Richard L. White

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-05-02

Filing date

1975-04-29

Publication date

1978-12-05

1975-04-29 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1978-12-05 Application granted granted Critical

1978-12-05 Publication of CA1043617A publication Critical patent/CA1043617A/en

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 69
238000000034 method Methods 0.000 title claims description 27
230000008569 process Effects 0.000 title claims description 10
-1 mercapto heterocyclic compounds Chemical class 0.000 claims abstract description 88
229910052709 silver Inorganic materials 0.000 claims abstract description 70
239000004332 silver Substances 0.000 claims abstract description 70
125000000623 heterocyclic group Chemical group 0.000 claims abstract description 61
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims abstract description 60
241001061127 Thione Species 0.000 claims abstract description 58
239000003638 chemical reducing agent Substances 0.000 claims abstract description 49
238000010438 heat treatment Methods 0.000 claims abstract description 24
239000011230 binding agent Substances 0.000 claims abstract description 14
239000003795 chemical substances by application Substances 0.000 claims description 29
125000004432 carbon atom Chemical group C* 0.000 claims description 24
AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical compound SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 claims description 20
FVQQWSSTYVBNST-UHFFFAOYSA-N 2-(4-methyl-2-sulfanylidene-1,3-thiazol-3-yl)acetic acid Chemical compound CC1=CSC(=S)N1CC(O)=O FVQQWSSTYVBNST-UHFFFAOYSA-N 0.000 claims description 19
230000000007 visual effect Effects 0.000 claims description 19
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 18
229910021612 Silver iodide Inorganic materials 0.000 claims description 18
229940045105 silver iodide Drugs 0.000 claims description 18
238000000576 coating method Methods 0.000 claims description 17
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 16
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 16
125000002947 alkylene group Chemical group 0.000 claims description 16
239000011248 coating agent Substances 0.000 claims description 16
KNCMHNISYLPZBZ-UHFFFAOYSA-N 4-methyl-1,2,4-triazolidine-3,5-dithione Chemical compound CN1C(=S)NNC1=S KNCMHNISYLPZBZ-UHFFFAOYSA-N 0.000 claims description 13
HHMMSIFWVIWYNN-UHFFFAOYSA-N 4-phenyl-1,2,4-triazolidine-3,5-dithione Chemical compound S=C1NNC(=S)N1C1=CC=CC=C1 HHMMSIFWVIWYNN-UHFFFAOYSA-N 0.000 claims description 13
238000012360 testing method Methods 0.000 claims description 13
ZEQIWKHCJWRNTH-UHFFFAOYSA-N 1h-pyrimidine-2,4-dithione Chemical compound S=C1C=CNC(=S)N1 ZEQIWKHCJWRNTH-UHFFFAOYSA-N 0.000 claims description 12
VQPMXSMUUILNFZ-UHFFFAOYSA-N 3,7-dihydropurine-2,6-dithione Chemical compound S=C1NC(=S)NC2=C1NC=N2 VQPMXSMUUILNFZ-UHFFFAOYSA-N 0.000 claims description 12
WZUUZPAYWFIBDF-UHFFFAOYSA-N 5-amino-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound NC1=NNC(S)=N1 WZUUZPAYWFIBDF-UHFFFAOYSA-N 0.000 claims description 12
125000004429 atom Chemical group 0.000 claims description 12
230000006872 improvement Effects 0.000 claims description 12
VABISHCLVYMGAU-UHFFFAOYSA-N 7,9-dihydropurine-8-thione Chemical compound N1=CN=C2NC(S)=NC2=C1 VABISHCLVYMGAU-UHFFFAOYSA-N 0.000 claims description 11
REGQHNCWPFIYFS-UHFFFAOYSA-N 1-(4-methoxyphenyl)-1,2,4-triazolidine-3,5-dithione Chemical compound COC1=CC=C(C=C1)N1NC(=S)NC1=S REGQHNCWPFIYFS-UHFFFAOYSA-N 0.000 claims description 10
BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 10
229920006322 acrylamide copolymer Polymers 0.000 claims description 6
239000000839 emulsion Substances 0.000 claims description 6
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
229910052721 tungsten Inorganic materials 0.000 claims description 6
239000010937 tungsten Substances 0.000 claims description 6
239000004698 Polyethylene Substances 0.000 claims description 5
229920000573 polyethylene Polymers 0.000 claims description 5
239000003125 aqueous solvent Substances 0.000 claims description 4
230000007935 neutral effect Effects 0.000 claims description 2
NRRDBSGYRFWANF-UHFFFAOYSA-M silver;2-(4-methyl-2-sulfanylidene-1,3-thiazol-3-yl)acetate Chemical compound [Ag+].CC1=CSC(=S)N1CC([O-])=O NRRDBSGYRFWANF-UHFFFAOYSA-M 0.000 claims description 2
150000001875 compounds Chemical class 0.000 abstract description 21
150000003378 silver Chemical class 0.000 abstract description 11
239000003381 stabilizer Substances 0.000 abstract description 6
239000002243 precursor Substances 0.000 abstract description 3
239000000463 material Substances 0.000 description 32
229940124024 weight reducing agent Drugs 0.000 description 29
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
239000010410 layer Substances 0.000 description 12
239000006185 dispersion Substances 0.000 description 10
238000002360 preparation method Methods 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 8
238000012545 processing Methods 0.000 description 8
OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical compound SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 6
239000000975 dye Substances 0.000 description 6
239000000123 paper Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
239000000376 reactant Substances 0.000 description 5
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 4
230000002411 adverse Effects 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
238000002156 mixing Methods 0.000 description 4
230000005855 radiation Effects 0.000 description 4
KZJPVUDYAMEDRM-UHFFFAOYSA-M silver;2,2,2-trifluoroacetate Chemical compound [Ag+].[O-]C(=O)C(F)(F)F KZJPVUDYAMEDRM-UHFFFAOYSA-M 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 4
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 3
GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 3
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
125000005605 benzo group Chemical group 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
239000008199 coating composition Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
150000002391 heterocyclic compounds Chemical class 0.000 description 3
125000004356 hydroxy functional group Chemical group O* 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
239000004250 tert-Butylhydroquinone Substances 0.000 description 3
235000019281 tert-butylhydroquinone Nutrition 0.000 description 3
ZKEGGSPWBGCPNF-UHFFFAOYSA-N 2,5-dihydroxy-5-methyl-3-(piperidin-1-ylamino)cyclopent-2-en-1-one Chemical compound O=C1C(C)(O)CC(NN2CCCCC2)=C1O ZKEGGSPWBGCPNF-UHFFFAOYSA-N 0.000 description 2
SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
VJIDDJAKLVOBSE-UHFFFAOYSA-N 2-ethylbenzene-1,4-diol Chemical compound CCC1=CC(O)=CC=C1O VJIDDJAKLVOBSE-UHFFFAOYSA-N 0.000 description 2
LAQYHRQFABOIFD-UHFFFAOYSA-N 2-methoxyhydroquinone Chemical compound COC1=CC(O)=CC=C1O LAQYHRQFABOIFD-UHFFFAOYSA-N 0.000 description 2
UWIVVEVTDCLBGF-UHFFFAOYSA-N 4,5-dihydroxy-2-propan-2-yl-1h-pyrimidin-6-one Chemical compound CC(C)C1=NC(O)=C(O)C(=O)N1 UWIVVEVTDCLBGF-UHFFFAOYSA-N 0.000 description 2
108010010803 Gelatin Proteins 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
229920002359 Tetronic® Polymers 0.000 description 2
235000010323 ascorbic acid Nutrition 0.000 description 2
239000011668 ascorbic acid Substances 0.000 description 2
229960005070 ascorbic acid Drugs 0.000 description 2
125000004181 carboxyalkyl group Chemical group 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
238000011161 development Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
230000003595 spectral effect Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
DBCKMJVEAUXWJJ-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Cl)=C1Cl DBCKMJVEAUXWJJ-UHFFFAOYSA-N 0.000 description 1
SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
GPASWZHHWPVSRG-UHFFFAOYSA-N 2,5-dimethylbenzene-1,4-diol Chemical compound CC1=CC(O)=C(C)C=C1O GPASWZHHWPVSRG-UHFFFAOYSA-N 0.000 description 1
125000004959 2,6-naphthylene group Chemical group [H]C1=C([H])C2=C([H])C([*:1])=C([H])C([H])=C2C([H])=C1[*:2] 0.000 description 1
ZCHQLCDAVFQHAZ-UHFFFAOYSA-N 2-(4-methyl-2-sulfanylidene-1,3-thiazol-3-yl)propanoic acid Chemical compound OC(=O)C(C)N1C(C)=CSC1=S ZCHQLCDAVFQHAZ-UHFFFAOYSA-N 0.000 description 1
IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
CIWBSHSKHKDKBQ-SZSCBOSDSA-N 2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one Chemical compound OC[C@H](O)C1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-SZSCBOSDSA-N 0.000 description 1
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 1
PHNGKIFUTBFGAG-UHFFFAOYSA-N 2-ethoxybenzene-1,4-diol Chemical compound CCOC1=CC(O)=CC=C1O PHNGKIFUTBFGAG-UHFFFAOYSA-N 0.000 description 1
HDBQZGJWHMCXIL-UHFFFAOYSA-N 3,7-dihydropurine-2-thione Chemical class SC1=NC=C2NC=NC2=N1 HDBQZGJWHMCXIL-UHFFFAOYSA-N 0.000 description 1
YRZCFCHJGYSSML-UHFFFAOYSA-N 3-(2-sulfanylidene-1,3-benzothiazol-3-yl)propanoic acid Chemical compound C1=CC=C2SC(=S)N(CCC(=O)O)C2=C1 YRZCFCHJGYSSML-UHFFFAOYSA-N 0.000 description 1
QUSAZJGKDUUSPZ-UHFFFAOYSA-N 3-(2-sulfanylidene-1,3-benzoxazol-3-yl)propanoic acid Chemical compound C1=CC=C2OC(=S)N(CCC(=O)O)C2=C1 QUSAZJGKDUUSPZ-UHFFFAOYSA-N 0.000 description 1
FFLZTNGZMAMDKD-UHFFFAOYSA-N 3-(3-methyl-2-sulfanylideneimidazolidin-1-yl)propanoic acid Chemical compound CN1CCN(CCC(O)=O)C1=S FFLZTNGZMAMDKD-UHFFFAOYSA-N 0.000 description 1
CDZMWAHBQLPCHD-UHFFFAOYSA-N 3-(4-carboxyphenyl)-1,1,3-trimethyl-2h-indene-5-carboxylic acid Chemical compound C12=CC(C(O)=O)=CC=C2C(C)(C)CC1(C)C1=CC=C(C(O)=O)C=C1 CDZMWAHBQLPCHD-UHFFFAOYSA-N 0.000 description 1
KZFMGQGVVIBTIH-UHFFFAOYSA-N 3-(4-methyl-2-sulfanylidene-1,3-thiazol-3-yl)propanoic acid Chemical compound CC1=CSC(=S)N1CCC(O)=O KZFMGQGVVIBTIH-UHFFFAOYSA-N 0.000 description 1
ZIPUYIFGZVWVPP-UHFFFAOYSA-N 3-(4-phenyl-5-sulfanylidene-1,2,4-triazol-1-yl)propanoic acid Chemical compound S=C1N(CCC(=O)O)N=CN1C1=CC=CC=C1 ZIPUYIFGZVWVPP-UHFFFAOYSA-N 0.000 description 1
YVOHGWDGWGHNRF-UHFFFAOYSA-N 3-(5-phenyl-2-sulfanylidene-1,3,4-oxadiazol-3-yl)propanoic acid Chemical compound O1C(=S)N(CCC(=O)O)N=C1C1=CC=CC=C1 YVOHGWDGWGHNRF-UHFFFAOYSA-N 0.000 description 1
NRTCEKLNEVXROH-UHFFFAOYSA-N 3-(5-phenyl-2-sulfanylidene-1,3,4-thiadiazol-3-yl)propanoic acid Chemical compound S1C(=S)N(CCC(=O)O)N=C1C1=CC=CC=C1 NRTCEKLNEVXROH-UHFFFAOYSA-N 0.000 description 1
MZZWYKPKOLXPHO-UHFFFAOYSA-N 3-[3-(2-carboxyethyl)-2-sulfanylidenebenzimidazol-1-yl]propanoic acid Chemical compound C1=CC=C2N(CCC(O)=O)C(=S)N(CCC(=O)O)C2=C1 MZZWYKPKOLXPHO-UHFFFAOYSA-N 0.000 description 1
KJYHAYFHCPSPOL-UHFFFAOYSA-N 3-[3-(2-carboxyethyl)-2-sulfanylideneimidazolidin-1-yl]propanoic acid Chemical compound OC(=O)CCN1CCN(CCC(O)=O)C1=S KJYHAYFHCPSPOL-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
KRLPDKPZKGOOMF-UHFFFAOYSA-N 4,5-dihydroxy-2,3-diphenyl-1,2-dihydropyrimidin-6-one Chemical compound OC1=C(O)C(=O)NC(C=2C=CC=CC=2)N1C1=CC=CC=C1 KRLPDKPZKGOOMF-UHFFFAOYSA-N 0.000 description 1
RUWHBHLPFMKMIA-UHFFFAOYSA-N 4,5-dihydroxy-3-methyl-2-propan-2-yl-1,2-dihydropyrimidin-6-one Chemical compound CC(C)C1NC(=O)C(O)=C(O)N1C RUWHBHLPFMKMIA-UHFFFAOYSA-N 0.000 description 1
DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
QEABJJFAUKWVNJ-UHFFFAOYSA-N 5-(disulfanyl)-1h-pyrazole Chemical class SSC1=CC=NN1 QEABJJFAUKWVNJ-UHFFFAOYSA-N 0.000 description 1
YPXQSGWOGQPLQO-UHFFFAOYSA-N 5-nitro-1,3-dihydrobenzimidazole-2-thione Chemical compound [O-][N+](=O)C1=CC=C2N=C(S)NC2=C1 YPXQSGWOGQPLQO-UHFFFAOYSA-N 0.000 description 1
244000215068 Acacia senegal Species 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
229920002307 Dextran Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229920000084 Gum arabic Polymers 0.000 description 1
239000002211 L-ascorbic acid Substances 0.000 description 1
235000000069 L-ascorbic acid Nutrition 0.000 description 1
150000000996 L-ascorbic acids Chemical class 0.000 description 1
239000000020 Nitrocellulose Substances 0.000 description 1
240000002834 Paulownia tomentosa Species 0.000 description 1
235000010678 Paulownia tomentosa Nutrition 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
206010070834 Sensitisation Diseases 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
239000011358 absorbing material Substances 0.000 description 1
239000000205 acacia gum Substances 0.000 description 1
235000010489 acacia gum Nutrition 0.000 description 1
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000007754 air knife coating Methods 0.000 description 1
IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
235000015241 bacon Nutrition 0.000 description 1
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
229910001864 baryta Inorganic materials 0.000 description 1
230000008901 benefit Effects 0.000 description 1
238000005282 brightening Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000007766 curtain coating Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000003618 dip coating Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002081 enamines Chemical class 0.000 description 1
238000007765 extrusion coating Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229960004251 hydroquinine Drugs 0.000 description 1
150000002443 hydroxylamines Chemical class 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
JABGXPCRNXUENL-UHFFFAOYSA-N mercaptopurine Chemical compound S=C1N=CNC2=NC=N[C]12 JABGXPCRNXUENL-UHFFFAOYSA-N 0.000 description 1
229960001428 mercaptopurine Drugs 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229920001220 nitrocellulos Polymers 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
150000004986 phenylenediamines Chemical class 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920006289 polycarbonate film Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920002557 polyglycidol polymer Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000012260 resinous material Substances 0.000 description 1
230000000452 restraining effect Effects 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
230000008313 sensitization Effects 0.000 description 1
230000001235 sensitizing effect Effects 0.000 description 1
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
239000002356 single layer Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
150000003549 thiazolines Chemical class 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49836—Additives
- G03C1/49845—Active additives, e.g. toners, stabilisers, sensitisers

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)

CA223,845A 1974-05-02 1975-04-29 Photothermographic and thermographic element, composition and process Expired CA1043617A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US46633174A	1974-05-02	1974-05-02

Publications (1)

Publication Number	Publication Date
CA1043617A true CA1043617A (en)	1978-12-05

Family

ID=23851350

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA223,845A Expired CA1043617A (en)	1974-05-02	1975-04-29	Photothermographic and thermographic element, composition and process

Country Status (6)

Country	Link
JP (1)	JPS50151138A (2)
BE (1)	BE828685A (2)
CA (1)	CA1043617A (2)
DE (1)	DE2519585A1 (2)
FR (1)	FR2269736B1 (2)
GB (1)	GB1501005A (2)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4168980A (en) *	1977-08-19	1979-09-25	Eastman Kodak Company	Heat developable photographic material and process
JPS5451821A (en) *	1977-10-01	1979-04-24	Oriental Photo Ind Co Ltd	Heat developable light sensitive material
US6132949A (en) *	1996-12-25	2000-10-17	Fuji Photo Film Co., Ltd.	Photothermographic material
JP3626305B2 (ja) *	1996-12-25	2005-03-09	富士写真フイルム株式会社	熱現像感光材料
JP3821410B2 (ja) *	1997-09-02	2006-09-13	富士写真フイルム株式会社	熱現像記録材料
US20040053173A1 (en) *	2002-09-18	2004-03-18	Eastman Kodak Company	Photothermographic materials containing high iodide emulsions
EP1544675A1 (en) *	2003-12-18	2005-06-22	Agfa-Gevaert	Stabilizers for use in (photo)thermographic recording materials
US7175977B2 (en)	2003-12-18	2007-02-13	Agfa-Gevaert	Stabilizers for use in thermographic recording materials

1975
- 1975-04-29 CA CA223,845A patent/CA1043617A/en not_active Expired
- 1975-05-02 DE DE19752519585 patent/DE2519585A1/de not_active Withdrawn
- 1975-05-02 GB GB1849375A patent/GB1501005A/en not_active Expired
- 1975-05-02 BE BE156028A patent/BE828685A/xx unknown
- 1975-05-02 FR FR7513777A patent/FR2269736B1/fr not_active Expired
- 1975-05-02 JP JP5259075A patent/JPS50151138A/ja active Pending

Also Published As

Publication number	Publication date
JPS50151138A (2)	1975-12-04
GB1501005A (en)	1978-02-15
DE2519585A1 (de)	1975-11-06
FR2269736A1 (2)	1975-11-28
FR2269736B1 (2)	1977-07-08
BE828685A (fr)	1975-11-03

Publication	Publication Date	Title
CA1078656A (en)	1980-06-03	Use of 2,6-dihalo-4-substituted sulfonamidophenol reducing agents in thermographic and photothermographic compositions
US4123274A (en)	1978-10-31	Heat developable imaging materials and process
US4220709A (en)	1980-09-02	Heat developable imaging materials and process
US3785830A (en)	1974-01-15	Photothermographic element,composition and process
US4201582A (en)	1980-05-06	Photothermographic and thermographic element, composition and process
US3874946A (en)	1975-04-01	Photothermographic element, composition and process
CA1193097A (en)	1985-09-10	Dye-forming developers in an imaging material and process
US3667959A (en)	1972-06-06	Photosensitive and thermosensitive element,compositions and process
US3839041A (en)	1974-10-01	Stabilizer precursors in photothermographic elements and compositions
US4088496A (en)	1978-05-09	Heat developable photographic materials and process
US3893859A (en)	1975-07-08	4-Aryl-1-carbamoyl-2-tetrazoline-5-thione stabilizer precursor in a heat stabilizable photographic element
US4168980A (en)	1979-09-25	Heat developable photographic material and process
US4021250A (en)	1977-05-03	Thermally developable photosensitive material
US3666477A (en)	1972-05-30	Element,composition and process
CA1039553A (en)	1978-10-03	Photothermographic compositions, element and process
US3761279A (en)	1973-09-25	Photothermographic element
US3751252A (en)	1973-08-07	Photothermographic element and process
US4546075A (en)	1985-10-08	Heat-developable photographic material
CA1043617A (en)	1978-12-05	Photothermographic and thermographic element, composition and process
US4452885A (en)	1984-06-05	Heat-developable photographic material
US3751249A (en)	1973-08-07	Photothermic silver halide element containing a bis-beta-naphthol reducing agent and a 1, 3-dihydroxy-benzene reducing agent
CA1122465A (en)	1982-04-27	Positive images in photothermographic materials using a saturated cyclic nitroxyl compound
CA2119601A1 (en)	1994-12-02	Stabilizers for photothermography with nitrile blocking groups
US3708304A (en)	1973-01-02	Use of divalent metal salt image amplifiers in photosensitive and thermosensitive elements
US3870523A (en)	1975-03-11	Heat developable photographic material containing azo dyes as sensitizers