CA1046258A - Extraction de petrole par injection d'eau et d'une microemulsion - Google Patents

Extraction de petrole par injection d'eau et d'une microemulsion

Info

Publication number: CA1046258A
Authority: CA; Canada
Prior art keywords: microemulsion; surfactant; oil; water; cosurfactant
Prior art date: 1974-01-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA213,357A

Other languages

English (en)

Other versions

CA213357S (en

Inventor

Robert N. Healy

Walter W. Gale

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Upstream Research Co

Original Assignee

Exxon Production Research Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-01-02

Filing date

1974-11-08

Publication date

1979-01-16

1974-11-08 Application filed by Exxon Production Research Co filed Critical Exxon Production Research Co

1979-01-16 Application granted granted Critical

1979-01-16 Publication of CA1046258A publication Critical patent/CA1046258A/fr

Status Expired legal-status Critical Current

Links

239000004530 micro-emulsion Substances 0.000 title claims abstract description 183
238000000034 method Methods 0.000 title claims description 70
230000008569 process Effects 0.000 title claims description 13
239000003921 oil Substances 0.000 claims abstract description 81
239000004094 surface-active agent Substances 0.000 claims abstract description 68
239000010779 crude oil Substances 0.000 claims abstract description 54
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
230000015572 biosynthetic process Effects 0.000 claims abstract description 46
239000004064 cosurfactant Substances 0.000 claims abstract description 40
238000011084 recovery Methods 0.000 claims abstract description 38
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 34
239000012267 brine Substances 0.000 claims abstract description 27
239000012736 aqueous medium Substances 0.000 claims abstract description 23
238000002347 injection Methods 0.000 claims abstract description 20
239000007924 injection Substances 0.000 claims abstract description 20
150000003839 salts Chemical class 0.000 claims abstract description 11
238000005755 formation reaction Methods 0.000 claims description 44
150000001298 alcohols Chemical group 0.000 claims description 35
150000002989 phenols Chemical class 0.000 claims description 20
238000004519 manufacturing process Methods 0.000 claims description 15
239000000126 substance Substances 0.000 claims description 10
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
239000012530 fluid Substances 0.000 claims description 6
150000003871 sulfonates Chemical class 0.000 claims description 5
150000002169 ethanolamines Chemical class 0.000 claims description 4
229940071104 xylenesulfonate Drugs 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 35
-1 orthoxylene sulfonate Chemical compound 0.000 abstract description 23
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 27
239000000203 mixture Substances 0.000 description 25
238000006073 displacement reaction Methods 0.000 description 15
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
239000011780 sodium chloride Substances 0.000 description 14
125000000217 alkyl group Chemical group 0.000 description 13
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 12
125000003118 aryl group Chemical group 0.000 description 10
MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 9
238000010586 diagram Methods 0.000 description 9
125000004432 carbon atom Chemical group C* 0.000 description 8
239000000463 material Substances 0.000 description 8
230000000694 effects Effects 0.000 description 7
239000011148 porous material Substances 0.000 description 7
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
230000037230 mobility Effects 0.000 description 5
150000001768 cations Chemical class 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000003138 primary alcohols Chemical class 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000002562 thickening agent Substances 0.000 description 4
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
238000006424 Flood reaction Methods 0.000 description 3
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 3
239000003792 electrolyte Substances 0.000 description 3
230000035699 permeability Effects 0.000 description 3
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 2
241000237858 Gastropoda Species 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
238000007792 addition Methods 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
230000029936 alkylation Effects 0.000 description 2
238000005804 alkylation reaction Methods 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000003945 anionic surfactant Substances 0.000 description 2
MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
150000004676 glycans Chemical class 0.000 description 2
230000015784 hyperosmotic salinity response Effects 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
239000002609 medium Substances 0.000 description 2
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
229920002401 polyacrylamide Polymers 0.000 description 2
229920001282 polysaccharide Polymers 0.000 description 2
239000005017 polysaccharide Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000006277 sulfonation reaction Methods 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
229920003169 water-soluble polymer Polymers 0.000 description 2
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical class CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229920002307 Dextran Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
150000003926 acrylamides Chemical class 0.000 description 1
239000011149 active material Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
229920000615 alginic acid Polymers 0.000 description 1
235000010443 alginic acid Nutrition 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
229940074323 antara Drugs 0.000 description 1
239000010692 aromatic oil Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
229910052728 basic metal Inorganic materials 0.000 description 1
150000003818 basic metals Chemical class 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
235000009508 confectionery Nutrition 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
YMTINGFKWWXKFG-UHFFFAOYSA-N fenofibrate Chemical compound C1=CC(OC(C)(C)C(=O)OC(C)C)=CC=C1C(=O)C1=CC=C(Cl)C=C1 YMTINGFKWWXKFG-UHFFFAOYSA-N 0.000 description 1
239000008398 formation water Substances 0.000 description 1
239000001760 fusel oil Substances 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical class CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 1
QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical class CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
FZWBNHMXJMCXLU-BLAUPYHCSA-N isomaltotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)O1 FZWBNHMXJMCXLU-BLAUPYHCSA-N 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000000693 micelle Substances 0.000 description 1
239000003607 modifier Substances 0.000 description 1
SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical class CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 1
229920002113 octoxynol Polymers 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000011435 rock Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000007704 transition Effects 0.000 description 1

Landscapes

Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

CA213,357A 1974-01-02 1974-11-08 Extraction de petrole par injection d'eau et d'une microemulsion Expired CA1046258A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US43033174A	1974-01-02	1974-01-02

Publications (1)

Publication Number	Publication Date
CA1046258A true CA1046258A (fr)	1979-01-16

Family

ID=23707074

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA213,357A Expired CA1046258A (fr)	1974-01-02	1974-11-08	Extraction de petrole par injection d'eau et d'une microemulsion

Country Status (1)

Country	Link
CA (1)	CA1046258A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102008053902A1 (de)	2008-10-30	2010-05-20	Hölter, Heinz, Prof. Dr.sc. Dr.-Ing. Dr.hc.	Kalt-technische Ölgewinnung aus Ölsand bzw. Ölschiefer aufgemahlen zu Ölsand und Gewinnung von Schwermetallen aus Ölsand

1974
- 1974-11-08 CA CA213,357A patent/CA1046258A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102008053902A1 (de)	2008-10-30	2010-05-20	Hölter, Heinz, Prof. Dr.sc. Dr.-Ing. Dr.hc.	Kalt-technische Ölgewinnung aus Ölsand bzw. Ölschiefer aufgemahlen zu Ölsand und Gewinnung von Schwermetallen aus Ölsand

Publication	Publication Date	Title
US3981361A (en)	1976-09-21	Oil recovery method using microemulsions
US3983940A (en)	1976-10-05	Water-external microemulsion and method of recovering oil therewith
US3946812A (en)	1976-03-30	Use of materials as waterflood additives
US3977471A (en)	1976-08-31	Oil recovery method using a surfactant
US3508612A (en)	1970-04-28	Waterflood oil recovery using calciumcompatible mixture of anionic surfactants
US4597879A (en)	1986-07-01	Micellar slug for oil recovery
US4463806A (en)	1984-08-07	Method for surfactant waterflooding in a high brine environment
US4544033A (en)	1985-10-01	Oil recovery process
US4110229A (en)	1978-08-29	Salinity tolerant surfactant oil recovery process
US3945437A (en)	1976-03-23	Process for displacing oil using aqueous anionic surfactant systems containing aromatic ether polysulfonates
US4077471A (en)	1978-03-07	Surfactant oil recovery process usable in high temperature, high salinity formations
CA1040409A (fr)	1978-10-17	Extraction du petrole a l'aide de microemulsions
US4293428A (en)	1981-10-06	Propoxylated ethoxylated surfactants and method of recovering oil therewith
US4194565A (en)	1980-03-25	Surfactant oil recovery method for use in high temperature formations containing water having high salinity and hardness
US4549607A (en)	1985-10-29	Micellar slug for oil recovery
US4555351A (en)	1985-11-26	Micellar slug for oil recovery
CA1066612A (fr)	1979-11-20	Procede de recuperation du petrole par un surfactant efficace en milieu salin
US4042030A (en)	1977-08-16	Oil recovery by viscous waterflooding
US3500923A (en)	1970-03-17	Use of highly saline ethoxylated surfactant system for oil recovery
US4154301A (en)	1979-05-15	Surfactant oil recovery process usable in a formation having high salinity connate water
US4271907A (en)	1981-06-09	Microemulsions which compatibly incorporate viscosifiers and their use in enhanced oil recovery
US3885626A (en)	1975-05-27	Oil recovery process utilizing higher alkyl toluene sulfonate
US4013569A (en)	1977-03-22	Aqueous anionic surfactant systems containing aromatic ether polysulfonates
US3638728A (en)	1972-02-01	Secondary oil recovery process with incremental injection of surfactant slugs
US4138345A (en)	1979-02-06	Oil recovery by surfactant waterflooding

CA1046258A - Extraction de petrole par injection d'eau et d'une microemulsion - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=23707074

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Similar Documents