CA1047966A - Elimination du mercure en solution avec du zinc particulaire comme cathode - Google Patents
Elimination du mercure en solution avec du zinc particulaire comme cathodeInfo
- Publication number
- CA1047966A CA1047966A CA290,282A CA290282A CA1047966A CA 1047966 A CA1047966 A CA 1047966A CA 290282 A CA290282 A CA 290282A CA 1047966 A CA1047966 A CA 1047966A
- Authority
- CA
- Canada
- Prior art keywords
- mercury
- particles
- zinc
- metal
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 229910052753 mercury Inorganic materials 0.000 title claims abstract description 54
- 239000011701 zinc Substances 0.000 title claims description 47
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 44
- 229910052725 zinc Inorganic materials 0.000 title claims description 43
- 238000000034 method Methods 0.000 title claims description 27
- 239000002245 particle Substances 0.000 claims abstract description 33
- 239000000243 solution Substances 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 229910000497 Amalgam Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 abstract description 36
- 239000002184 metal Substances 0.000 abstract description 36
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 27
- 229910052802 copper Inorganic materials 0.000 abstract description 10
- 239000010949 copper Substances 0.000 abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052785 arsenic Inorganic materials 0.000 abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- 238000007747 plating Methods 0.000 abstract description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 abstract description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 6
- 239000000356 contaminant Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000003643 water by type Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 208000023514 Barrett esophagus Diseases 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- -1 alkyl mercury Chemical compound 0.000 description 3
- 238000005267 amalgamation Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229940100892 mercury compound Drugs 0.000 description 3
- 150000002731 mercury compounds Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- KMKFXZBVMUGVRA-UHFFFAOYSA-M (2-carboxyphenyl)sulfanylmercury Chemical compound OC(=O)C1=CC=CC=C1S[Hg] KMKFXZBVMUGVRA-UHFFFAOYSA-M 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- 101100380241 Caenorhabditis elegans arx-2 gene Proteins 0.000 description 1
- 101100452593 Caenorhabditis elegans ina-1 gene Proteins 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- JJWSNOOGIUMOEE-UHFFFAOYSA-N Monomethylmercury Chemical compound [Hg]C JJWSNOOGIUMOEE-UHFFFAOYSA-N 0.000 description 1
- 101100270435 Mus musculus Arhgef12 gene Proteins 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 240000004543 Vicia ervilia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 101150092805 actc1 gene Proteins 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ALKZAGKDWUSJED-UHFFFAOYSA-N dinuclear copper ion Chemical compound [Cu].[Cu] ALKZAGKDWUSJED-UHFFFAOYSA-N 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940008718 metallic mercury Drugs 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24005872A | 1972-03-31 | 1972-03-31 | |
| CA166,540A CA1033686A (fr) | 1972-03-31 | 1973-03-08 | Methode d'extraction des metaux lourds en presence dans l'eau |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1047966A true CA1047966A (fr) | 1979-02-06 |
Family
ID=25667242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA290,282A Expired CA1047966A (fr) | 1972-03-31 | 1977-11-07 | Elimination du mercure en solution avec du zinc particulaire comme cathode |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1047966A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118308602A (zh) * | 2024-06-07 | 2024-07-09 | 山东黄金矿业科技有限公司选冶实验室分公司 | 一种含汞金矿石氰化浸出贵液的除汞和综合回收方法 |
-
1977
- 1977-11-07 CA CA290,282A patent/CA1047966A/fr not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118308602A (zh) * | 2024-06-07 | 2024-07-09 | 山东黄金矿业科技有限公司选冶实验室分公司 | 一种含汞金矿石氰化浸出贵液的除汞和综合回收方法 |
| CN118308602B (zh) * | 2024-06-07 | 2024-08-09 | 山东黄金矿业科技有限公司选冶实验室分公司 | 一种含汞金矿石氰化浸出贵液的除汞和综合回收方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0071443B1 (fr) | Dispositif pour le traitement des eaux usées | |
| US8545692B2 (en) | Apparatus and method for electrochemical modification of concentrations of liquid streams | |
| US3899405A (en) | Method of removing heavy metals from water and apparatus therefor | |
| US4028199A (en) | Method of producing metal powder | |
| JP4104157B2 (ja) | 重金属類による被汚染物の浄化方法及び装置 | |
| EP3294929B1 (fr) | Systèmes et procédés en boucle fermée pour le recyclage de batteries au plomb | |
| EP0074167A1 (fr) | Elimination des impuretés métalliques | |
| KR890002751B1 (ko) | 유동층을 이용한 전해방법과 전해조 | |
| US3772003A (en) | Process for the electrolytic recovery of lead, silver and zinc from their ore | |
| US3954594A (en) | Electrochemical cell for decreasing the cyanide and heavy metal content of an aqueous solution | |
| US3970531A (en) | Decreasing the cyanide and heavy metal content of an aqueous solution | |
| US4318789A (en) | Electrochemical removal of heavy metals such as chromium from dilute wastewater streams using flow through porous electrodes | |
| US5458745A (en) | Method for removal of technetium from radio-contaminated metal | |
| US4292160A (en) | Apparatus for electrochemical removal of heavy metals such as chromium from dilute wastewater streams using flow-through porous electrodes | |
| US3899404A (en) | Method of removing mercury from an aqueous solution | |
| EP0716643A1 (fr) | Dispositif et procede de recuperation des metaux a partir d'une solution aqueuse | |
| CA1065272A (fr) | Methode et appareil pour le traitement de solutions diluees de cyanures | |
| JPS6338435B2 (fr) | ||
| CA1047966A (fr) | Elimination du mercure en solution avec du zinc particulaire comme cathode | |
| JPH01162789A (ja) | 担体上に担持された金属の回収方法及び装置 | |
| Abda et al. | Removal of cadmium and associated contaminants from aqueous wastes by fibrous carbon electrodes | |
| JP4102851B2 (ja) | 被汚染物からの重金属類の溶出を行う反応槽 | |
| US5372683A (en) | Method and apparatus for the electrolytic extraction of metals from a solution containing metal ions | |
| US6309531B1 (en) | Process for extracting copper or iron | |
| US4749456A (en) | Electrolytic recovery of copper from waste water |