CA1048951A - Fractionnement catalytique a emission reduite de gaz nocifs - Google Patents

Fractionnement catalytique a emission reduite de gaz nocifs

Info

Publication number: CA1048951A
Authority: CA; Canada
Prior art keywords: catalyst; cracking; sulfur; particles; zone
Prior art date: 1975-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA78302247A

Other languages

English (en)

Inventor

Iacovos A. Vasalos

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-12-19

Filing date

1978-04-28

Publication date

1979-02-20

1976-12-15 Priority claimed from CA76267991A external-priority patent/CA1048991A/fr

1978-04-28 Application filed by Standard Oil Co filed Critical Standard Oil Co

1979-02-20 Application granted granted Critical

1979-02-20 Publication of CA1048951A publication Critical patent/CA1048951A/fr

Status Expired legal-status Critical Current

Links

239000007789 gas Substances 0.000 title claims abstract description 77
238000004523 catalytic cracking Methods 0.000 title claims abstract description 27
230000002829 reductive effect Effects 0.000 title abstract description 15
230000001473 noxious effect Effects 0.000 title abstract description 4
239000003054 catalyst Substances 0.000 claims abstract description 292
238000005336 cracking Methods 0.000 claims abstract description 168
239000002245 particle Substances 0.000 claims abstract description 134
238000011069 regeneration method Methods 0.000 claims abstract description 128
230000008929 regeneration Effects 0.000 claims abstract description 125
238000000034 method Methods 0.000 claims abstract description 115
239000007787 solid Substances 0.000 claims abstract description 99
239000000376 reactant Substances 0.000 claims abstract description 96
229910052751 metal Inorganic materials 0.000 claims abstract description 89
230000008569 process Effects 0.000 claims abstract description 71
229910052717 sulfur Inorganic materials 0.000 claims abstract description 53
239000011593 sulfur Substances 0.000 claims abstract description 53
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 52
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims abstract description 46
229910052815 sulfur oxide Inorganic materials 0.000 claims abstract description 43
230000000694 effects Effects 0.000 claims abstract description 34
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 24
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 24
229910052708 sodium Inorganic materials 0.000 claims abstract description 22
239000011734 sodium Substances 0.000 claims abstract description 22
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 16
229910052802 copper Inorganic materials 0.000 claims abstract description 16
239000010949 copper Substances 0.000 claims abstract description 16
229910052725 zinc Inorganic materials 0.000 claims abstract description 16
239000011701 zinc Substances 0.000 claims abstract description 16
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 14
229910052742 iron Inorganic materials 0.000 claims abstract description 12
238000010521 absorption reaction Methods 0.000 claims abstract description 10
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 10
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 9
229910052804 chromium Inorganic materials 0.000 claims abstract description 9
239000011651 chromium Substances 0.000 claims abstract description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052793 cadmium Inorganic materials 0.000 claims abstract description 8
229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 8
150000002910 rare earth metals Chemical class 0.000 claims abstract description 8
239000010936 titanium Substances 0.000 claims abstract description 8
229910052719 titanium Inorganic materials 0.000 claims abstract description 8
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 7
229910052787 antimony Inorganic materials 0.000 claims abstract description 7
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 7
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 7
229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
239000010941 cobalt Substances 0.000 claims abstract description 7
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
125000004122 cyclic group Chemical group 0.000 claims abstract description 7
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
239000011733 molybdenum Substances 0.000 claims abstract description 7
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
229910052706 scandium Inorganic materials 0.000 claims abstract description 6
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 6
238000006243 chemical reaction Methods 0.000 claims description 70
229930195733 hydrocarbon Natural products 0.000 claims description 31
150000002430 hydrocarbons Chemical class 0.000 claims description 31
239000004215 Carbon black (E152) Substances 0.000 claims description 25
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 24
229910052760 oxygen Inorganic materials 0.000 claims description 24
239000001301 oxygen Substances 0.000 claims description 24
239000000203 mixture Substances 0.000 claims description 17
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 10
229910001882 dioxygen Inorganic materials 0.000 claims description 9
150000002898 organic sulfur compounds Chemical class 0.000 claims description 6
230000001172 regenerating effect Effects 0.000 claims description 4
239000003546 flue gas Substances 0.000 abstract description 42
229910000323 aluminium silicate Inorganic materials 0.000 abstract description 16
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 11
239000011159 matrix material Substances 0.000 abstract description 10
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 85
239000002184 metal Substances 0.000 description 72
239000000571 coke Substances 0.000 description 68
229910002091 carbon monoxide Inorganic materials 0.000 description 56
238000002485 combustion reaction Methods 0.000 description 48
150000001875 compounds Chemical class 0.000 description 39
239000003921 oil Substances 0.000 description 35
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 28
239000000243 solution Substances 0.000 description 28
239000000758 substrate Substances 0.000 description 25
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 22
239000003570 air Substances 0.000 description 21
150000002739 metals Chemical class 0.000 description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
239000012530 fluid Substances 0.000 description 16
239000002808 molecular sieve Substances 0.000 description 16
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 16
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
229910052799 carbon Inorganic materials 0.000 description 15
229910002092 carbon dioxide Inorganic materials 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
239000001569 carbon dioxide Substances 0.000 description 14
238000007254 oxidation reaction Methods 0.000 description 14
230000003647 oxidation Effects 0.000 description 13
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 12
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
239000000047 product Substances 0.000 description 12
230000003197 catalytic effect Effects 0.000 description 11
238000004231 fluid catalytic cracking Methods 0.000 description 10
229910052749 magnesium Inorganic materials 0.000 description 10
239000011777 magnesium Substances 0.000 description 10
239000000463 material Substances 0.000 description 10
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 9
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 9
-1 nlckel Chemical compound 0.000 description 9
238000011084 recovery Methods 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 9
239000000567 combustion gas Substances 0.000 description 8
238000000151 deposition Methods 0.000 description 8
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 8
229910044991 metal oxide Inorganic materials 0.000 description 8
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
229910000037 hydrogen sulfide Inorganic materials 0.000 description 7
238000005342 ion exchange Methods 0.000 description 7
150000004706 metal oxides Chemical class 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
239000000843 powder Substances 0.000 description 7
230000009467 reduction Effects 0.000 description 7
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
230000008901 benefit Effects 0.000 description 6
230000008021 deposition Effects 0.000 description 6
239000000446 fuel Substances 0.000 description 6
238000011065 in-situ storage Methods 0.000 description 6
239000003208 petroleum Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000000126 substance Substances 0.000 description 6
239000003502 gasoline Substances 0.000 description 5
238000005470 impregnation Methods 0.000 description 5
230000001976 improved effect Effects 0.000 description 5
238000010348 incorporation Methods 0.000 description 5
239000011261 inert gas Substances 0.000 description 5
229910052697 platinum Inorganic materials 0.000 description 5
239000011148 porous material Substances 0.000 description 5
238000012545 processing Methods 0.000 description 5
238000012360 testing method Methods 0.000 description 5
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
229910052748 manganese Inorganic materials 0.000 description 4
239000011572 manganese Substances 0.000 description 4
239000013618 particulate matter Substances 0.000 description 4
230000005501 phase interface Effects 0.000 description 4
JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 4
229910052698 phosphorus Inorganic materials 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
229910052684 Cerium Inorganic materials 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
230000002411 adverse Effects 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000009835 boiling Methods 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
150000007942 carboxylates Chemical class 0.000 description 3
239000012876 carrier material Substances 0.000 description 3
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 3
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000005243 fluidization Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000010687 lubricating oil Substances 0.000 description 3
150000002823 nitrates Chemical class 0.000 description 3
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
230000000630 rising effect Effects 0.000 description 3
238000000926 separation method Methods 0.000 description 3
238000001179 sorption measurement Methods 0.000 description 3
238000012546 transfer Methods 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
229910052770 Uranium Inorganic materials 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
230000004913 activation Effects 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
239000012080 ambient air Substances 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
238000011021 bench scale process Methods 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 2
239000002131 composite material Substances 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
239000002178 crystalline material Substances 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
230000008030 elimination Effects 0.000 description 2
238000003379 elimination reaction Methods 0.000 description 2
125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 2
239000002360 explosive Substances 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000006872 improvement Effects 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
238000012423 maintenance Methods 0.000 description 2
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
150000005309 metal halides Chemical class 0.000 description 2
238000002156 mixing Methods 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
230000036961 partial effect Effects 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
238000005120 petroleum cracking Methods 0.000 description 2
239000003209 petroleum derivative Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
230000004044 response Effects 0.000 description 2
239000007921 spray Substances 0.000 description 2
229910052712 strontium Inorganic materials 0.000 description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
238000005979 thermal decomposition reaction Methods 0.000 description 2
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
239000002912 waste gas Substances 0.000 description 2
KLFRPGNCEJNEKU-FDGPNNRMSA-L (z)-4-oxopent-2-en-2-olate;platinum(2+) Chemical compound [Pt+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O KLFRPGNCEJNEKU-FDGPNNRMSA-L 0.000 description 1
XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 1
BSFODEXXVBBYOC-UHFFFAOYSA-N 8-[4-(dimethylamino)butan-2-ylamino]quinolin-6-ol Chemical compound C1=CN=C2C(NC(CCN(C)C)C)=CC(O)=CC2=C1 BSFODEXXVBBYOC-UHFFFAOYSA-N 0.000 description 1
241001024304 Mino Species 0.000 description 1
101100409194 Rattus norvegicus Ppargc1b gene Proteins 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
229910052769 Ytterbium Inorganic materials 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
239000011609 ammonium molybdate Substances 0.000 description 1
235000018660 ammonium molybdate Nutrition 0.000 description 1
229940010552 ammonium molybdate Drugs 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
239000002585 base Substances 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
229940077388 benzenesulfonate Drugs 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910000420 cerium oxide Inorganic materials 0.000 description 1
229910052676 chabazite Inorganic materials 0.000 description 1
230000008859 change Effects 0.000 description 1
238000002144 chemical decomposition reaction Methods 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
WEMFUFMJQFVTSW-UHFFFAOYSA-N compositin Natural products CC=C(C)C(=O)OC1CC(O)C2(C)COC3C2C1(C)C1CCC2(C)C(CC=C2C1(C)C3OC(=O)C(C)=CC)c1ccoc1 WEMFUFMJQFVTSW-UHFFFAOYSA-N 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000005474 detonation Methods 0.000 description 1
125000004989 dicarbonyl group Chemical group 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical group CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
239000000539 dimer Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
238000010574 gas phase reaction Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229940097789 heavy mineral oil Drugs 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
JCYWCSGERIELPG-UHFFFAOYSA-N imes Chemical class CC1=CC(C)=CC(C)=C1N1C=CN(C=2C(=CC(C)=CC=2C)C)[C]1 JCYWCSGERIELPG-UHFFFAOYSA-N 0.000 description 1
230000001433 inducive effect Effects 0.000 description 1
206010022000 influenza Diseases 0.000 description 1
238000009434 installation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
235000012254 magnesium hydroxide Nutrition 0.000 description 1
229960000816 magnesium hydroxide Drugs 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
125000001741 organic sulfur group Chemical group 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000012255 powdered metal Substances 0.000 description 1
239000012716 precipitator Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000000644 propagated effect Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000007670 refining Methods 0.000 description 1
239000003870 refractory metal Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000010517 secondary reaction Methods 0.000 description 1
238000005204 segregation Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
238000010998 test method Methods 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
229910000348 titanium sulfate Inorganic materials 0.000 description 1
239000002341 toxic gas Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
230000007306 turnover Effects 0.000 description 1
229910002007 uranyl nitrate Inorganic materials 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
JRPGMCRJPQJYPE-UHFFFAOYSA-N zinc;carbanide Chemical group [CH3-].[CH3-].[Zn+2] JRPGMCRJPQJYPE-UHFFFAOYSA-N 0.000 description 1

Landscapes

Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA78302247A 1975-12-19 1978-04-28 Fractionnement catalytique a emission reduite de gaz nocifs Expired CA1048951A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US64254275A	1975-12-19	1975-12-19
CA76267991A CA1048991A (fr)	1975-12-19	1976-12-15	Fractionnement catalytique a emission reduite de gaz nocifs

Publications (1)

Publication Number	Publication Date
CA1048951A true CA1048951A (fr)	1979-02-20

Family

ID=25668410

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA78302247A Expired CA1048951A (fr)	1975-12-19	1978-04-28	Fractionnement catalytique a emission reduite de gaz nocifs

Country Status (1)

Country	Link
CA (1)	CA1048951A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4504381A (en) *	1983-12-09	1985-03-12	Exxon Research And Engineering Co.	Passivation of cracking catalysts with cadmium and tin
CN120519224A (zh) *	2025-07-25	2025-08-22	湖北安耐吉环保科技有限公司	一种废润滑油的深度裂解与再生提纯方法

1978
- 1978-04-28 CA CA78302247A patent/CA1048951A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4504381A (en) *	1983-12-09	1985-03-12	Exxon Research And Engineering Co.	Passivation of cracking catalysts with cadmium and tin
CN120519224A (zh) *	2025-07-25	2025-08-22	湖北安耐吉环保科技有限公司	一种废润滑油的深度裂解与再生提纯方法

Publication	Publication Date	Title
CA1048991A (fr)	1979-02-20	Fractionnement catalytique a emission reduite de gaz nocifs
US4153535A (en)	1979-05-08	Catalytic cracking with reduced emission of noxious gases
US4238317A (en)	1980-12-09	Catalytic cracking with reduced emission of noxious gases
US4221677A (en)	1980-09-09	Catalytic cracking with reduced emission of noxious gases
US4146463A (en)	1979-03-27	Removal of carbon monoxide and sulfur oxides from refinery flue gases
CA1048009A (fr)	1979-02-06	Fractionnement catalytique avec regeneration du catalyseur et repression des emanations de co
EP0263171B1 (fr)	1992-11-25	Composition de spinelle contenant des metaux, et procede d'utilisation
US4206039A (en)	1980-06-03	Catalytic cracking with reduced emission of noxious gases
US4137151A (en)	1979-01-30	Hydrocarbon conversion with cracking catalyst having co-combustion promoters lanthanum and iron
US4093535A (en)	1978-06-06	Catalytic cracking process
US5037538A (en)	1991-08-06	Catalytic cracking process with isolated catalyst for conversion of NO.sub.x
US4381991A (en)	1983-05-03	Process for removing sulfur oxides from a gas
EP0072653B1 (fr)	1986-03-05	Enlèvement endothermique de coke déposé sur des matériaux sorbantes lors de la conversion d'huiles contenant des précurseurs de coke et des métaux lourds
US4414098A (en)	1983-11-08	Upgrading carbo-metallic oils with used catalyst
US5002654A (en)	1991-03-26	Reducing NOx emissions with zinc catalyst
US4495305A (en)	1985-01-22	Catalyst for conversion of hydrocarbons
US4267072A (en)	1981-05-12	Catalytic cracking catalyst with reduced emission of noxious gases
CA1093050A (fr)	1981-01-06	Craquage catalytique avec emission reduite de gaz nocifs
US4341623A (en)	1982-07-27	Catalytic cracking using a mixture of cracking catalyst particles with particles of platinum group metal or rhenium on inert substrates regenerated to up to about 0.1% coke
CA1113417A (fr)	1981-12-01	Controle de la teneur en oxydes de soufre au cours du craquage catalytique
US4218344A (en)	1980-08-19	Catalytic cracking with reduced emission of noxious gases
US4435282A (en)	1984-03-06	Catalytic cracking using a cracking catalyst in admixture with particles of platinum group metal or rhenium on a substrate regenerated to up to about 0.1% coke
WO1987006156A1 (fr)	1987-10-22	Composition de spinelle contenant des metaux de terre rare et du vanadium, et procede d'utilisation
US4187199A (en)	1980-02-05	Hydrocarbon conversion catalyst
CA1048951A (fr)	1979-02-20	Fractionnement catalytique a emission reduite de gaz nocifs

CA1048951A - Fractionnement catalytique a emission reduite de gaz nocifs - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=25668410

Family Applications (1)

Country Status (1)

Cited By (2)

Cited By (2)

Similar Documents