CA1049682A - Carboxyfunctional silicone containing thermoplastics - Google Patents
Carboxyfunctional silicone containing thermoplasticsInfo
- Publication number
- CA1049682A CA1049682A CA218,436A CA218436A CA1049682A CA 1049682 A CA1049682 A CA 1049682A CA 218436 A CA218436 A CA 218436A CA 1049682 A CA1049682 A CA 1049682A
- Authority
- CA
- Canada
- Prior art keywords
- average value
- radical
- percent
- units
- siloxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001169 thermoplastic Polymers 0.000 title abstract description 11
- 239000004416 thermosoftening plastic Substances 0.000 title abstract description 11
- 229920001296 polysiloxane Polymers 0.000 title abstract description 3
- -1 halogenated hydrocarbon radical Chemical group 0.000 claims description 43
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 16
- 150000003254 radicals Chemical class 0.000 claims description 16
- 239000012815 thermoplastic material Substances 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000002430 hydrocarbons Chemical group 0.000 claims description 5
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000004434 sulfur atom Chemical group 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000412 polyarylene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920001291 polyvinyl halide Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47774074A | 1974-06-10 | 1974-06-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1049682A true CA1049682A (en) | 1979-02-27 |
Family
ID=23897162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA218,436A Expired CA1049682A (en) | 1974-06-10 | 1975-01-22 | Carboxyfunctional silicone containing thermoplastics |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5344178B2 (de) |
| AT (1) | AT343361B (de) |
| CA (1) | CA1049682A (de) |
| FR (1) | FR2273849A1 (de) |
| GB (1) | GB1460128A (de) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857251A (en) * | 1988-04-14 | 1989-08-15 | Kimberly-Clark Corporation | Method of forming a nonwoven web from a surface-segregatable thermoplastic composition |
| US4923914A (en) * | 1988-04-14 | 1990-05-08 | Kimberly-Clark Corporation | Surface-segregatable, melt-extrudable thermoplastic composition |
| US4976788A (en) * | 1988-06-03 | 1990-12-11 | Kimberly-Clark Corporation | Method of cleaning melt-processing equipment with a thermoplastic polyolefin and a bifunctional siloxane |
| US5085920A (en) * | 1990-04-30 | 1992-02-04 | Kimberly-Clark Corporation | Nonwoven wipe having improved grease release |
| US5114646A (en) * | 1989-09-18 | 1992-05-19 | Kimberly-Clark Corporation | Method of increasing the delay period of nonwoven webs having delayed wettability |
| US5120888A (en) * | 1988-04-14 | 1992-06-09 | Kimberly-Clark Corporation | Surface-segregatable, melt-extrudable thermoplastic composition |
| US5145727A (en) * | 1990-11-26 | 1992-09-08 | Kimberly-Clark Corporation | Multilayer nonwoven composite structure |
| US5149576A (en) * | 1990-11-26 | 1992-09-22 | Kimberly-Clark Corporation | Multilayer nonwoven laminiferous structure |
| US5225263A (en) * | 1990-02-08 | 1993-07-06 | Frudenberg Spunweb S.A. Societe Anonyme A. Directoire | Nonwovens of synthetic continuous filaments including at least a part with modified surface properties, process for their manufacture and their applications |
| US5344862A (en) * | 1991-10-25 | 1994-09-06 | Kimberly-Clark Corporation | Thermoplastic compositions and nonwoven webs prepared therefrom |
| US5356585A (en) * | 1993-07-01 | 1994-10-18 | Dow Corning Corporation | Process of extruding snythetic thermoplastic resins using organosilicon resinous compositions as extrusion lubricants |
| US5494855A (en) * | 1994-04-06 | 1996-02-27 | Kimberly-Clark Corporation | Thermoplastic compositions and nonwoven webs prepared therefrom |
| US5641822A (en) * | 1989-09-18 | 1997-06-24 | Kimberly-Clark Corporation | Surface-segregatable compositions and nonwoven webs prepared therefrom |
| US5656361A (en) * | 1996-07-23 | 1997-08-12 | Kimberly-Clark Worldwide, Inc. | Multiple application meltblown nonwoven wet wipe and method |
| US5696191A (en) * | 1989-09-18 | 1997-12-09 | Kimberly-Clark Worldwide, Inc. | Surface-segregatable compositions and nonwoven webs prepared therefrom |
| US5708085A (en) * | 1996-08-28 | 1998-01-13 | Dow Corning Corporation | Low density polyethylene modified with silicone materials |
| US5708084A (en) * | 1996-08-28 | 1998-01-13 | Dow Corning Corporation | Organic polymers modified with silicone materials |
| US5789473A (en) * | 1995-01-17 | 1998-08-04 | Dow Corning Corporation | Polyolefin composition containing diorganopolysiloxane process aid |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6052326B2 (ja) * | 1979-10-05 | 1985-11-19 | 日本ケ−ブル・システム株式会社 | コントロ−ルケ−ブル |
| JPS6050386B2 (ja) * | 1980-07-31 | 1985-11-08 | ト−レ・シリコ−ン株式会社 | ビニル系樹脂組成物 |
| US4535113A (en) * | 1984-03-13 | 1985-08-13 | Union Carbide Corporation | Olefin polymer compositions containing silicone additives and the use thereof in the production of film material |
| US4994532A (en) * | 1989-06-16 | 1991-02-19 | General Electric Company | Polycarbonate-silicone block copolymer compositions |
| WO2006062718A1 (en) * | 2004-12-07 | 2006-06-15 | Dow Global Technologies Inc. | Polymer containing polysiloxane processing aid and catalyst neutralizer |
| BRPI0517149A (pt) | 2004-12-07 | 2008-09-30 | Dow Global Technologies Inc | composição polimérica tendo propriedades de extrusão de fundido melhoradas |
| KR20110111287A (ko) | 2008-12-17 | 2011-10-10 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 고 투명성 용도를 위한 실리콘 폴리옥사미드 공정 첨가제 |
| US8552136B2 (en) | 2008-12-17 | 2013-10-08 | 3M Innovative Properties Company | Thermoplastic silicone-based polymer process additives for injection molding applications |
| US9896575B2 (en) | 2012-06-11 | 2018-02-20 | 3M Innovative Properties Company | Melt-processable compositions having silicone-containing polymeric process additive and synergist |
| GB2509128A (en) * | 2012-12-20 | 2014-06-25 | Dow Corning | Process for improving fire resistance of an organic polymer |
-
1975
- 1975-01-22 CA CA218,436A patent/CA1049682A/en not_active Expired
- 1975-02-21 AT AT131475A patent/AT343361B/de not_active IP Right Cessation
- 1975-03-19 JP JP3349075A patent/JPS5344178B2/ja not_active Expired
- 1975-05-21 GB GB2177775A patent/GB1460128A/en not_active Expired
- 1975-06-06 FR FR7517733A patent/FR2273849A1/fr active Granted
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857251A (en) * | 1988-04-14 | 1989-08-15 | Kimberly-Clark Corporation | Method of forming a nonwoven web from a surface-segregatable thermoplastic composition |
| US4923914A (en) * | 1988-04-14 | 1990-05-08 | Kimberly-Clark Corporation | Surface-segregatable, melt-extrudable thermoplastic composition |
| US5057262A (en) * | 1988-04-14 | 1991-10-15 | Kimberly-Clark Corporation | Process for melt extruding a surface-segregatable thermoplastic composition |
| US5120888A (en) * | 1988-04-14 | 1992-06-09 | Kimberly-Clark Corporation | Surface-segregatable, melt-extrudable thermoplastic composition |
| US4976788A (en) * | 1988-06-03 | 1990-12-11 | Kimberly-Clark Corporation | Method of cleaning melt-processing equipment with a thermoplastic polyolefin and a bifunctional siloxane |
| US5114646A (en) * | 1989-09-18 | 1992-05-19 | Kimberly-Clark Corporation | Method of increasing the delay period of nonwoven webs having delayed wettability |
| US5696191A (en) * | 1989-09-18 | 1997-12-09 | Kimberly-Clark Worldwide, Inc. | Surface-segregatable compositions and nonwoven webs prepared therefrom |
| US5641822A (en) * | 1989-09-18 | 1997-06-24 | Kimberly-Clark Corporation | Surface-segregatable compositions and nonwoven webs prepared therefrom |
| US5225263A (en) * | 1990-02-08 | 1993-07-06 | Frudenberg Spunweb S.A. Societe Anonyme A. Directoire | Nonwovens of synthetic continuous filaments including at least a part with modified surface properties, process for their manufacture and their applications |
| US5085920A (en) * | 1990-04-30 | 1992-02-04 | Kimberly-Clark Corporation | Nonwoven wipe having improved grease release |
| US5178931A (en) * | 1990-11-26 | 1993-01-12 | Kimberly-Clark Corporation | Three-layer nonwoven laminiferous structure |
| US5178932A (en) * | 1990-11-26 | 1993-01-12 | Kimberly-Clark Corporation | Three-layer nonwoven composite structure |
| US5149576A (en) * | 1990-11-26 | 1992-09-22 | Kimberly-Clark Corporation | Multilayer nonwoven laminiferous structure |
| US5145727A (en) * | 1990-11-26 | 1992-09-08 | Kimberly-Clark Corporation | Multilayer nonwoven composite structure |
| US5344862A (en) * | 1991-10-25 | 1994-09-06 | Kimberly-Clark Corporation | Thermoplastic compositions and nonwoven webs prepared therefrom |
| US5413655A (en) * | 1991-10-25 | 1995-05-09 | Kimberly-Clark Corporation | Thermoplastic compositions and nonwoven webs prepared therefrom |
| US5356585A (en) * | 1993-07-01 | 1994-10-18 | Dow Corning Corporation | Process of extruding snythetic thermoplastic resins using organosilicon resinous compositions as extrusion lubricants |
| US5494855A (en) * | 1994-04-06 | 1996-02-27 | Kimberly-Clark Corporation | Thermoplastic compositions and nonwoven webs prepared therefrom |
| US5789473A (en) * | 1995-01-17 | 1998-08-04 | Dow Corning Corporation | Polyolefin composition containing diorganopolysiloxane process aid |
| US5656361A (en) * | 1996-07-23 | 1997-08-12 | Kimberly-Clark Worldwide, Inc. | Multiple application meltblown nonwoven wet wipe and method |
| US5708085A (en) * | 1996-08-28 | 1998-01-13 | Dow Corning Corporation | Low density polyethylene modified with silicone materials |
| US5708084A (en) * | 1996-08-28 | 1998-01-13 | Dow Corning Corporation | Organic polymers modified with silicone materials |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1460128A (en) | 1976-12-31 |
| JPS5344178B2 (de) | 1978-11-27 |
| FR2273849B1 (de) | 1979-04-27 |
| DE2506667A1 (de) | 1975-12-11 |
| JPS50156555A (de) | 1975-12-17 |
| AT343361B (de) | 1978-05-26 |
| ATA131475A (de) | 1977-09-15 |
| DE2506667B2 (de) | 1976-07-08 |
| FR2273849A1 (fr) | 1976-01-02 |
| AU7761175A (en) | 1976-07-29 |
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