CA1050699A - Precurseurs resistant a l'hydrolyse pour la preparation de mousse d'urethane - Google Patents

Precurseurs resistant a l'hydrolyse pour la preparation de mousse d'urethane

Info

Publication number: CA1050699A
Authority: CA; Canada
Prior art keywords: tin; water; hydrolytically stable; catalysts; catalyst
Prior art date: 1974-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA242,078A

Other languages

English (en)

Other versions

CA242078S (en

Inventor

Melvin H. Gitlitz

Kenneth Treadwell

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

M&T Chemicals Inc

Original Assignee

M&T Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-12-19

Filing date

1975-12-18

Publication date

1979-03-13

1975-12-18 Application filed by M&T Chemicals Inc filed Critical M&T Chemicals Inc

1979-03-13 Application granted granted Critical

1979-03-13 Publication of CA1050699A publication Critical patent/CA1050699A/fr

Status Expired legal-status Critical Current

Links

239000002243 precursor Substances 0.000 title claims description 15
239000006260 foam Substances 0.000 title description 17
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 title 1
239000003054 catalyst Substances 0.000 claims abstract description 44
150000001875 compounds Chemical class 0.000 claims abstract description 10
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
239000004814 polyurethane Substances 0.000 claims description 20
229920005862 polyol Polymers 0.000 claims description 19
150000003077 polyols Chemical class 0.000 claims description 19
229920002635 polyurethane Polymers 0.000 claims description 19
230000001413 cellular effect Effects 0.000 claims description 13
238000005187 foaming Methods 0.000 claims description 9
229920001296 polysiloxane Polymers 0.000 claims description 7
239000004094 surface-active agent Substances 0.000 claims description 6
239000000460 chlorine Substances 0.000 claims description 5
229910052801 chlorine Inorganic materials 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
229920001281 polyalkylene Polymers 0.000 claims description 3
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
125000001309 chloro group Chemical group Cl* 0.000 claims description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
150000003254 radicals Chemical group 0.000 claims 1
-1 methoxy-methyl radicals Chemical class 0.000 abstract description 14
229910052718 tin Inorganic materials 0.000 abstract description 12
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 10
229920005830 Polyurethane Foam Polymers 0.000 abstract description 7
239000011496 polyurethane foam Substances 0.000 abstract description 7
239000007864 aqueous solution Substances 0.000 abstract description 4
239000004215 Carbon black (E152) Substances 0.000 abstract 1
229930195733 hydrocarbon Natural products 0.000 abstract 1
150000002430 hydrocarbons Chemical class 0.000 abstract 1
239000000203 mixture Substances 0.000 description 17
239000012948 isocyanate Substances 0.000 description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
238000009472 formulation Methods 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
150000002513 isocyanates Chemical class 0.000 description 11
239000007787 solid Substances 0.000 description 11
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
239000000243 solution Substances 0.000 description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
239000000306 component Substances 0.000 description 7
238000000034 method Methods 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
239000005056 polyisocyanate Substances 0.000 description 6
150000003606 tin compounds Chemical class 0.000 description 6
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
239000004594 Masterbatch (MB) Substances 0.000 description 5
NWCGUQGZZQIGJN-UHFFFAOYSA-L dichloro-bis(methoxymethyl)stannane Chemical compound [Cl-].[Cl-].COC[Sn+2]COC NWCGUQGZZQIGJN-UHFFFAOYSA-L 0.000 description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical class [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 5
229920001228 polyisocyanate Polymers 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
229920001451 polypropylene glycol Polymers 0.000 description 4
239000000047 product Substances 0.000 description 4
239000011369 resultant mixture Substances 0.000 description 4
KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
239000004721 Polyphenylene oxide Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
KMXRCJISUGGVJU-UHFFFAOYSA-N bis(methoxymethyl)-oxotin Chemical compound COC[Sn](=O)COC KMXRCJISUGGVJU-UHFFFAOYSA-N 0.000 description 3
PBPATXJNGCEVJD-UHFFFAOYSA-N bis(methoxymethyl)tin Chemical class COC[Sn]COC PBPATXJNGCEVJD-UHFFFAOYSA-N 0.000 description 3
239000001569 carbon dioxide Substances 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
PKKGKUDPKRTKLJ-UHFFFAOYSA-L dichloro(dimethyl)stannane Chemical compound C[Sn](C)(Cl)Cl PKKGKUDPKRTKLJ-UHFFFAOYSA-L 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000000463 material Substances 0.000 description 3
WPCSDPJAAARKRT-UHFFFAOYSA-N methoxymethyltin Chemical class COC[Sn] WPCSDPJAAARKRT-UHFFFAOYSA-N 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004604 Blowing Agent Substances 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
238000007664 blowing Methods 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
229960002887 deanol Drugs 0.000 description 2
239000012975 dibutyltin dilaurate Substances 0.000 description 2
239000012972 dimethylethanolamine Substances 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
239000004088 foaming agent Substances 0.000 description 2
235000011187 glycerol Nutrition 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
238000010992 reflux Methods 0.000 description 2
150000003512 tertiary amines Chemical class 0.000 description 2
238000012360 testing method Methods 0.000 description 2
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 2
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
ZXUJWPHOPHHZLR-UHFFFAOYSA-N 1,1,1-trichloro-2-fluoroethane Chemical compound FCC(Cl)(Cl)Cl ZXUJWPHOPHHZLR-UHFFFAOYSA-N 0.000 description 1
SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XJUZRXYOEPSWMB-UHFFFAOYSA-N Chloromethyl methyl ether Chemical compound COCCl XJUZRXYOEPSWMB-UHFFFAOYSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 1
101150089916 Miox gene Proteins 0.000 description 1
241000009328 Perro Species 0.000 description 1
229920000265 Polyparaphenylene Polymers 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000010923 batch production Methods 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001649 bromium compounds Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
KWTSZCJMWHGPOS-UHFFFAOYSA-M chloro(trimethyl)stannane Chemical compound C[Sn](C)(C)Cl KWTSZCJMWHGPOS-UHFFFAOYSA-M 0.000 description 1
229940061627 chloromethyl methyl ether Drugs 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical class CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
ATADHKWKHYVBTJ-UHFFFAOYSA-N hydron;4-[1-hydroxy-2-(methylamino)ethyl]benzene-1,2-diol;chloride Chemical compound Cl.CNCC(O)C1=CC=C(O)C(O)=C1 ATADHKWKHYVBTJ-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000011031 large-scale manufacturing process Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
239000003607 modifier Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
238000006902 nitrogenation reaction Methods 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
230000000063 preceeding effect Effects 0.000 description 1
238000004886 process control Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
229940071536 silver acetate Drugs 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
238000004154 testing of material Methods 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
125000005628 tolylene group Chemical group 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Landscapes

Polyurethanes Or Polyureas (AREA)

CA242,078A 1974-12-19 1975-12-18 Precurseurs resistant a l'hydrolyse pour la preparation de mousse d'urethane Expired CA1050699A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US53449074A	1974-12-19	1974-12-19

Publications (1)

Publication Number	Publication Date
CA1050699A true CA1050699A (fr)	1979-03-13

Family

ID=24130279

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA242,078A Expired CA1050699A (fr)	1974-12-19	1975-12-18	Precurseurs resistant a l'hydrolyse pour la preparation de mousse d'urethane

Country Status (2)

Country	Link
JP (1)	JPS5186596A (fr)
CA (1)	CA1050699A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2582303B1 (fr) *	1985-05-21	1987-07-10	Rhone Poulenc Spec Chim	Procede de stabilisation de solutions organiques de polyisocyanates

1975
- 1975-12-18 CA CA242,078A patent/CA1050699A/fr not_active Expired
- 1975-12-19 JP JP50150751A patent/JPS5186596A/ja active Pending

Also Published As

Publication number	Publication date
JPS5186596A (fr)	1976-07-29

Publication	Publication Date	Title
US4032468A (en)	1977-06-28	Hydrolytically stable urethane foam precursors
US3397158A (en)	1968-08-13	Cellular polyurethanes
CA1076747A (fr)	1980-04-29	Mode de fabrication de polyurethanne cellulaire
KR20100131974A (ko)	2010-12-16	발포된 비변색성 폴리우레탄 성형 부품
US3681272A (en)	1972-08-01	Urethane foam forming process using as a gel catalyst a mixture of 2-ethylhexoic acid and a stannous compound
US4031049A (en)	1977-06-21	Polyurethane cross-linking agents
US4824595A (en)	1989-04-25	Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure
US3342757A (en)	1967-09-19	Process for preparation of polyurethane foam
US3933692A (en)	1976-01-20	Urethane foam catalyst
US3239480A (en)	1966-03-08	Polyurethanes synthesized with the aid of carboxylic acid salts
US3037947A (en)	1962-06-05	Foamed polyurethane polymer and method of making same
US4228248A (en)	1980-10-14	Morpholine derivatives and use as polyurethane catalyst
US3391091A (en)	1968-07-02	Technique for preparation of polyurethanes employing a tin compound as a gel catalyst and a metal soap as a blowing catalyst
JPS6063220A (ja)	1985-04-11	ポリウレタンフオ−ムの製造法
EP1532186B1 (fr)	2008-04-16	Catalyseurs a l'etain a faible emission
EP0318242A2 (fr)	1989-05-31	Polyols polymériques à haute teneur en solides
US4085072A (en)	1978-04-18	Process for preparing oxidatively stable polyurethane foam
CA1050699A (fr)	1979-03-13	Precurseurs resistant a l'hydrolyse pour la preparation de mousse d'urethane
CA1073150A (fr)	1980-03-04	Polyurethanne alveolaire a stabilite thermique et oxydative
US3914189A (en)	1975-10-21	Method for production of polyurethane foam using oxazolines as catalysts
JPS62158713A (ja)	1987-07-14	潜錫触媒を含むポリイソシアネ−ト配合物およびその製造方法
US4579875A (en)	1986-04-01	Use of liquid oxazolines in polyurethane/polyisocyanurate rigid foams as reactive compatibilizers
CA1081198A (fr)	1980-07-08	Precurseurs stables durant le stockage, pour la fabrication de mousses rigides de polyurethanne
EP0082597B1 (fr)	1986-09-17	Système de catalyseur-solvant pour mousses de polyuréthane
CA1120459A (fr)	1982-03-23	Agent de catalyse pour mousses d'urethane souples