CA1050917A - Procede de reforming - Google Patents

Procede de reforming

Info

Publication number: CA1050917A
Authority: CA; Canada
Prior art keywords: catalyst; alumina; weight; hydrocarbon; sulfur
Prior art date: 1973-05-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA198,677A

Other languages

English (en)

Other versions

CA198677S (en

Inventor

John Mooi

Thomas A. Collins

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Atlantic Richfield Co

Original Assignee

Atlantic Richfield Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-05-07

Filing date

1974-05-01

Publication date

1979-03-20

1974-05-01 Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co

1979-03-20 Application granted granted Critical

1979-03-20 Publication of CA1050917A publication Critical patent/CA1050917A/fr

Status Expired legal-status Critical Current

Links

229930195733 hydrocarbon Natural products 0.000 title claims abstract description 82
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 80
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 78
238000002407 reforming Methods 0.000 title claims abstract description 48
238000000034 method Methods 0.000 title claims abstract description 33
239000003054 catalyst Substances 0.000 claims abstract description 116
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 61
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 42
229910052717 sulfur Inorganic materials 0.000 claims abstract description 41
239000011593 sulfur Substances 0.000 claims abstract description 41
229910052702 rhenium Inorganic materials 0.000 claims abstract description 38
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract description 29
238000006243 chemical reaction Methods 0.000 claims abstract description 27
230000000694 effects Effects 0.000 claims abstract description 27
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 18
239000001257 hydrogen Substances 0.000 claims abstract description 18
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 61
229910052751 metal Inorganic materials 0.000 claims description 21
239000002184 metal Substances 0.000 claims description 21
229910052697 platinum Inorganic materials 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 8
150000004682 monohydrates Chemical class 0.000 claims description 7
239000007787 solid Substances 0.000 claims description 7
150000004684 trihydrates Chemical class 0.000 claims description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
150000004820 halides Chemical class 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 description 19
150000002367 halogens Chemical class 0.000 description 19
239000000463 material Substances 0.000 description 11
239000000017 hydrogel Substances 0.000 description 9
150000001875 compounds Chemical class 0.000 description 8
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 7
238000005470 impregnation Methods 0.000 description 7
239000002253 acid Substances 0.000 description 6
238000009835 boiling Methods 0.000 description 6
-1 e.g. Substances 0.000 description 6
238000012545 processing Methods 0.000 description 6
QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000000243 solution Substances 0.000 description 5
238000011282 treatment Methods 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
238000001354 calcination Methods 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
239000007789 gas Substances 0.000 description 4
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
230000003647 oxidation Effects 0.000 description 4
238000007254 oxidation reaction Methods 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
238000006722 reduction reaction Methods 0.000 description 4
229930192474 thiophene Natural products 0.000 description 4
230000002411 adverse Effects 0.000 description 3
238000011160 research Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
241000518994 Conta Species 0.000 description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
239000011737 fluorine Substances 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000002203 pretreatment Methods 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
QYSYEILYXGRUOM-UHFFFAOYSA-N [Cl].[Pt] Chemical compound [Cl].[Pt] QYSYEILYXGRUOM-UHFFFAOYSA-N 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
230000032683 aging Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229940074995 bromine Drugs 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005755 formation reaction Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
229910001679 gibbsite Inorganic materials 0.000 description 1
239000008187 granular material Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000003837 high-temperature calcination Methods 0.000 description 1
125000001145 hydrido group Chemical group *[H] 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000006187 pill Substances 0.000 description 1
150000003057 platinum Chemical class 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
150000003281 rhenium Chemical class 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
150000003577 thiophenes Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/22—Starting-up reforming operations
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA198,677A 1973-05-07 1974-05-01 Procede de reforming Expired CA1050917A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US35798973A	1973-05-07	1973-05-07

Publications (1)

Publication Number	Publication Date
CA1050917A true CA1050917A (fr)	1979-03-20

Family

ID=23407847

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA198,677A Expired CA1050917A (fr)	1973-05-07	1974-05-01	Procede de reforming

Country Status (3)

Country	Link
JP (1)	JPS5069103A (fr)
CA (1)	CA1050917A (fr)
GB (1)	GB1474109A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU537495B2 (en) *	1978-04-10	1984-06-28	Engelhard Corporation	Catalytic reforming with rhenium-platinum catalyst
CN101423774B (zh) *	2007-10-31	2012-09-05	中国石油化工股份有限公司	一种连续重整装置初始反应的钝化方法

1974
- 1974-05-01 CA CA198,677A patent/CA1050917A/fr not_active Expired
- 1974-05-03 GB GB1957974A patent/GB1474109A/en not_active Expired
- 1974-05-07 JP JP49050659A patent/JPS5069103A/ja active Pending

Also Published As

Publication number	Publication date
JPS5069103A (fr)	1975-06-09
GB1474109A (en)	1977-05-18

Publication	Publication Date	Title
US4225417A (en)	1980-09-30	Catalytic reforming process with sulfur removal
CA1299161C (fr)	1992-04-21	Conversion d'hydrocarbures avec catalyseur trimetallique
US3554902A (en)	1971-01-12	Platinum iridium
US4124490A (en)	1978-11-07	Hydrocarbon reforming process
US4255289A (en)	1981-03-10	Process for the preparation of magnetic catalysts
US3487009A (en)	1969-12-30	Low pressure reforming with a platinumrhenium-iridium catalyst
US4329220A (en)	1982-05-11	Catalytic reforming process with liquid phase sulfur removal
US3296119A (en)	1967-01-03	Catalytic reforming process and catalyst therefor
US4155836A (en)	1979-05-22	Hydrocarbon reforming process with sulfur sensitive catalyst
CA1152926A (fr)	1983-08-30	Reformage et hydrofractionnement de composes organiques a l'aide de titanat de zinc a titre d'agent de catalyse
JPH04277592A (ja)	1992-10-02	高活性、高収量、スズ変性白金−イリジウム触媒で低苛酷度で改質する方法
US4787969A (en)	1988-11-29	Reforming with polymetallic catalysts
US4070306A (en)	1978-01-24	Method of treating a used platinum group alumina catalyst with a metal promoter
US4865719A (en)	1989-09-12	Trimetallic reforming catalyst
US4319984A (en)	1982-03-16	Reforming with an improved platinum-containing catalyst
US3867314A (en)	1975-02-18	Process for the preparation of a supported iridium catalyst
CA1050917A (fr)	1979-03-20	Procede de reforming
US4714540A (en)	1987-12-22	Reforming of hydrocarbons utilizing a trimetallic catalyst
US4265786A (en)	1981-05-05	Reforming with multimetallic catalysts
US4714539A (en)	1987-12-22	Reforming of hydrocarbons utilizing a trimetallic catalyst
US3816300A (en)	1974-06-11	Platinum-rhenium hydrocarbon conversion process
KR930011923B1 (ko)	1993-12-22	다수의 촉매를 사용한 다중 구역 접촉 개질 방법
US4302358A (en)	1981-11-24	Reforming with an improved platinum-containing catalyst
US4464249A (en)	1984-08-07	Plural stage reforming with catalysts having a skewed distribution of a platinum-group metal and rhenium
EP0083875A1 (fr)	1983-07-20	Procédé pour le reforming catalytique de naphtha utilisant un catalyseur platine-rhénium