CA1051778A - Pesticide stabilise et methode d'utilisation - Google Patents

Pesticide stabilise et methode d'utilisation

Info

Publication number: CA1051778A
Authority: CA; Canada
Prior art keywords: growth; proliferation; composition; bacteria; fungi
Prior art date: 1976-02-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA246,392A

Other languages

English (en)

Inventor

John D. Buckman

John D. Pera

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Buckman Laboratories International Inc

Original Assignee

Buckman Laboratories International Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-02-24

Filing date

1976-02-24

Publication date

1979-04-03

1976-02-24 Application filed by Buckman Laboratories International Inc filed Critical Buckman Laboratories International Inc

1976-02-24 Priority to CA246,392A priority Critical patent/CA1051778A/fr

1979-04-03 Application granted granted Critical

1979-04-03 Publication of CA1051778A publication Critical patent/CA1051778A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 53
238000000034 method Methods 0.000 title claims description 20
230000000361 pesticidal effect Effects 0.000 title abstract description 8
239000000463 material Substances 0.000 claims abstract description 26
-1 alkali-metal salts Chemical class 0.000 claims abstract description 11
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 10
239000012736 aqueous medium Substances 0.000 claims abstract description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 19
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 18
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 17
239000007864 aqueous solution Substances 0.000 claims description 16
241000894006 Bacteria Species 0.000 claims description 15
230000035755 proliferation Effects 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
241000233866 Fungi Species 0.000 claims description 12
239000000839 emulsion Substances 0.000 claims description 12
239000000126 substance Substances 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 7
239000002002 slurry Substances 0.000 claims description 7
241000195493 Cryptophyta Species 0.000 claims description 6
244000005700 microbiome Species 0.000 claims description 6
239000002689 soil Substances 0.000 claims description 6
241000244206 Nematoda Species 0.000 claims description 5
239000003599 detergent Substances 0.000 claims description 5
239000000976 ink Substances 0.000 claims description 5
239000003973 paint Substances 0.000 claims description 5
239000004753 textile Substances 0.000 claims description 5
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
241000607479 Yersinia pestis Species 0.000 claims description 4
239000000853 adhesive Substances 0.000 claims description 4
230000001070 adhesive effect Effects 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 4
125000002947 alkylene group Chemical group 0.000 claims description 4
239000002173 cutting fluid Substances 0.000 claims description 4
230000006866 deterioration Effects 0.000 claims description 4
239000013505 freshwater Substances 0.000 claims description 4
QDESFMLRHRZCSV-UHFFFAOYSA-M potassium;n-(hydroxymethyl)-n-methylcarbamodithioate Chemical compound [K+].OCN(C)C([S-])=S QDESFMLRHRZCSV-UHFFFAOYSA-M 0.000 claims description 4
239000001993 wax Substances 0.000 claims description 4
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 3
230000015572 biosynthetic process Effects 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
239000000498 cooling water Substances 0.000 claims description 3
230000002906 microbiologic effect Effects 0.000 claims description 3
238000011084 recovery Methods 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
150000001720 carbohydrates Chemical class 0.000 claims description 2
229920002689 polyvinyl acetate Polymers 0.000 claims description 2
239000011118 polyvinyl acetate Substances 0.000 claims description 2
239000011347 resin Substances 0.000 claims description 2
229920005989 resin Polymers 0.000 claims description 2
VLDHWMAJBNWALQ-UHFFFAOYSA-M sodium;1,3-benzothiazol-3-ide-2-thione Chemical compound [Na+].C1=CC=C2SC([S-])=NC2=C1 VLDHWMAJBNWALQ-UHFFFAOYSA-M 0.000 claims description 2
230000002401 inhibitory effect Effects 0.000 claims 7
229920005613 synthetic organic polymer Polymers 0.000 claims 3
239000012530 fluid Substances 0.000 claims 2
239000002609 medium Substances 0.000 claims 2
239000004925 Acrylic resin Substances 0.000 claims 1
229920000178 Acrylic resin Polymers 0.000 claims 1
239000003208 petroleum Substances 0.000 claims 1
ZCDTZZCMNQEDCN-UHFFFAOYSA-N hydroxymethylcarbamodithioic acid Chemical class OCNC(S)=S ZCDTZZCMNQEDCN-UHFFFAOYSA-N 0.000 abstract 1
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 39
239000000243 solution Substances 0.000 description 15
DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical class NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 13
239000012990 dithiocarbamate Substances 0.000 description 9
239000000047 product Substances 0.000 description 9
239000002253 acid Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 6
239000002244 precipitate Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
239000003619 algicide Substances 0.000 description 4
230000001069 nematicidal effect Effects 0.000 description 4
239000005645 nematicide Substances 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
239000004480 active ingredient Substances 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 3
150000004659 dithiocarbamates Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000004816 latex Substances 0.000 description 3
229920000126 latex Polymers 0.000 description 3
230000003641 microbiacidal effect Effects 0.000 description 3
229940124561 microbicide Drugs 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000006283 soil fumigant Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
239000003899 bactericide agent Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
239000000417 fungicide Substances 0.000 description 2
125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 2
UOULMNPQNCAUDL-UHFFFAOYSA-N hydroxymethyl(methyl)carbamodithioic acid Chemical compound OCN(C)C(S)=S UOULMNPQNCAUDL-UHFFFAOYSA-N 0.000 description 2
HYVVJDQGXFXBRZ-UHFFFAOYSA-N metam Chemical compound CNC(S)=S HYVVJDQGXFXBRZ-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
DQRQIQZHRCRSDB-UHFFFAOYSA-M potassium;n-methylcarbamodithioate Chemical compound [K+].CNC([S-])=S DQRQIQZHRCRSDB-UHFFFAOYSA-M 0.000 description 2
238000007639 printing Methods 0.000 description 2
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
238000003860 storage Methods 0.000 description 2
241000228245 Aspergillus niger Species 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
241000221955 Chaetomium Species 0.000 description 1
241000543381 Cliftonia monophylla Species 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
241000982822 Ficus obtusifolia Species 0.000 description 1
241000295146 Gallionellaceae Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
241001072332 Monia Species 0.000 description 1
VLCDUOXHFNUCKK-UHFFFAOYSA-N N,N'-Dimethylthiourea Chemical compound CNC(=S)NC VLCDUOXHFNUCKK-UHFFFAOYSA-N 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
240000000064 Penicillium roqueforti Species 0.000 description 1
235000002233 Penicillium roqueforti Nutrition 0.000 description 1
241000589516 Pseudomonas Species 0.000 description 1
241000212342 Sium Species 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
UELITFHSCLAHKR-UHFFFAOYSA-N acibenzolar-S-methyl Chemical compound CSC(=O)C1=CC=CC2=C1SN=N2 UELITFHSCLAHKR-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
125000005263 alkylenediamine group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
IEQPZXXXPVAXRJ-UHFFFAOYSA-N butylcarbamodithioic acid Chemical compound CCCCNC(S)=S IEQPZXXXPVAXRJ-UHFFFAOYSA-N 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
239000004568 cement Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000010730 cutting oil Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
230000000855 fungicidal effect Effects 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
238000007429 general method Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
TTXOPCIZFSDOAQ-UHFFFAOYSA-N hydroxymethyl n-methylcarbamodithioate Chemical compound CNC(=S)SCO TTXOPCIZFSDOAQ-UHFFFAOYSA-N 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
VSTJXOLPHDGBPA-UHFFFAOYSA-N methyl n-methylcarbamodithioate Chemical compound CNC(=S)SC VSTJXOLPHDGBPA-UHFFFAOYSA-N 0.000 description 1
KFIGICHILYTCJF-UHFFFAOYSA-N n'-methylethane-1,2-diamine Chemical compound CNCCN KFIGICHILYTCJF-UHFFFAOYSA-N 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229960005419 nitrogen Drugs 0.000 description 1
PVGGCFFBPJDIGT-UHFFFAOYSA-N pentylcarbamodithioic acid Chemical compound CCCCCNC(S)=S PVGGCFFBPJDIGT-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
TWIOETHNYAHVFS-UHFFFAOYSA-N propylcarbamodithioic acid Chemical compound CCCNC(S)=S TWIOETHNYAHVFS-UHFFFAOYSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
241000894007 species Species 0.000 description 1
238000009987 spinning Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
229910000406 trisodium phosphate Inorganic materials 0.000 description 1
235000019801 trisodium phosphate Nutrition 0.000 description 1

Landscapes

Agricultural Chemicals And Associated Chemicals (AREA)

CA246,392A 1976-02-24 1976-02-24 Pesticide stabilise et methode d'utilisation Expired CA1051778A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA246,392A CA1051778A (fr)	1976-02-24	1976-02-24	Pesticide stabilise et methode d'utilisation

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA246,392A CA1051778A (fr)	1976-02-24	1976-02-24	Pesticide stabilise et methode d'utilisation

Publications (1)

Publication Number	Publication Date
CA1051778A true CA1051778A (fr)	1979-04-03

Family

ID=4105302

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA246,392A Expired CA1051778A (fr)	1976-02-24	1976-02-24	Pesticide stabilise et methode d'utilisation

Country Status (1)

Country	Link
CA (1)	CA1051778A (fr)

1976
- 1976-02-24 CA CA246,392A patent/CA1051778A/fr not_active Expired

Publication	Publication Date	Title
EP0194146A2 (fr)	1986-09-10	Stabilisation de 5-chloro-3-isothiazolones
EP0139404A1 (fr)	1985-05-02	Traitement de l'eau par un agent biocide
JPH0818932B2 (ja)	1996-02-28	安定化されたイソチアゾロン組成物
EP1515605A1 (fr)	2005-03-23	Formulation biocide et procedes permettant sa preparation
US3856851A (en)	1974-12-24	Potassium n-hydroxylmethyl-n-methyldithiocarbamate
US4824957A (en)	1989-04-25	Stabilization of non-aqueous solutions of 3-isothiazolones
US3914301A (en)	1975-10-21	Acrylamide derivatives of 3-isothiazolones
US5250194A (en)	1993-10-05	N-dodecyl heterocyclic compounds useful as industrial microbicides and preservatives
US3973034A (en)	1976-08-03	Certain stabilized dithiocarbomate pesticidal compositions and methods of using same
JP2000038306A (ja)	2000-02-08	工業的防腐防かび方法
CA1051778A (fr)	1979-04-03	Pesticide stabilise et methode d'utilisation
JPH0515672B2 (fr)	1993-03-02
DE4138089A1 (de)	1993-05-27	1,3,5-triazin-2,4,6-tris- alkylaminocarbonsaeureaminoester, diese enthaltende biozide mittel sowie verfahren zu ihrer herstellung
JPS6236303A (ja)	1987-02-17	イソチアゾロン化合物の塩基性水性溶液
US5424007A (en)	1995-06-13	1-methyl-3,5,7-triaza-1-azoniatricyclodecane compounds, a method for preparing these compounds, their use in the control of microorganisms in aqueous systems, and their use in the inhibition of corrosion
US4518599A (en)	1985-05-21	2-Amino-3-cyano-5-halo-6-(substituted)pyrazine
JPH029881A (ja)	1990-01-12	１―メチル―３，５，７―トリアザ―１―アゾニアトリシクロデカン化合物、その製法及びその用途
US3819609A (en)	1974-06-25	Fungicidal-2-alkoxy-5-halogeno-benzene diazonium cyanides
US3772277A (en)	1973-11-13	Sulfonamide compounds
US3647793A (en)	1972-03-07	2-piperidino-3-phenylquinoxaline compounds
JPS62277361A (ja)	1987-12-02	ニコチン酸誘導体をベ−スとする殺菌組成物、新規なニコチン酸誘導体及びその製法
EP0051884A1 (fr)	1982-05-19	Dérivés d'acides amino cyclopropyl carboxyliques pour détacher les fruits et/ou feuilles de plantes
US4517186A (en)	1985-05-14	2-Amino-3,5-dicyano-6-(substituted)pyrazine antimicrobial compounds
US3826846A (en)	1974-07-30	Antifungal composition and method of alkylenebisdithiocarbamate complex compounds
US3709676A (en)	1973-01-09	Herbicidally active compositions