CA1052317A - Electrodeposition d'un carbure du groupe va sur un article en fer, en alliage ferreux ou en carbure cemente - Google Patents

Electrodeposition d'un carbure du groupe va sur un article en fer, en alliage ferreux ou en carbure cemente

Info

Publication number: CA1052317A
Authority: CA; Canada
Prior art keywords: article; carbide; layer; molten bath; group element
Prior art date: 1972-05-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA170,290A

Other languages

English (en)

Other versions

CA170290S (fr

Inventor

Yoshihiko Sugimoto

Tohru Arai

Noboru Komatsu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Toyota Central R&D Labs Inc

Original Assignee

Toyota Central R&D Labs Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-05-04

Filing date

1973-05-03

Publication date

1979-04-10

1972-05-04 Priority claimed from JP47043729A external-priority patent/JPS5121384B2/ja

1972-05-09 Priority claimed from JP4608072A external-priority patent/JPS5527146B2/ja

1972-06-08 Priority claimed from JP5649372A external-priority patent/JPS5216453B2/ja

1973-05-03 Application filed by Toyota Central R&D Labs Inc filed Critical Toyota Central R&D Labs Inc

1979-04-10 Application granted granted Critical

1979-04-10 Publication of CA1052317A publication Critical patent/CA1052317A/fr

Status Expired legal-status Critical Current

Links

XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 39
229910052742 iron Inorganic materials 0.000 title claims abstract description 19
229910045601 alloy Inorganic materials 0.000 title claims abstract description 17
239000000956 alloy Substances 0.000 title claims abstract description 17
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 12
230000015572 biosynthetic process Effects 0.000 title description 10
238000000034 method Methods 0.000 claims abstract description 37
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 25
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 19
239000004327 boric acid Substances 0.000 claims abstract description 19
230000000737 periodic effect Effects 0.000 claims abstract description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 51
229910052799 carbon Inorganic materials 0.000 claims description 42
229910021538 borax Inorganic materials 0.000 claims description 34
235000010339 sodium tetraborate Nutrition 0.000 claims description 34
239000000843 powder Substances 0.000 claims description 31
239000000126 substance Substances 0.000 claims description 10
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
238000000151 deposition Methods 0.000 claims description 4
238000007598 dipping method Methods 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims description 2
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 2
INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 44
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 32
229910052796 boron Inorganic materials 0.000 description 32
239000004328 sodium tetraborate Substances 0.000 description 32
UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 25
229910001315 Tool steel Inorganic materials 0.000 description 18
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 16
238000002441 X-ray diffraction Methods 0.000 description 15
229910052720 vanadium Inorganic materials 0.000 description 15
229910000628 Ferrovanadium Inorganic materials 0.000 description 14
PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 description 14
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 12
229910001935 vanadium oxide Inorganic materials 0.000 description 12
229910052751 metal Inorganic materials 0.000 description 11
239000002184 metal Substances 0.000 description 11
239000010955 niobium Substances 0.000 description 11
229910052758 niobium Inorganic materials 0.000 description 10
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 10
229910002804 graphite Inorganic materials 0.000 description 9
239000010439 graphite Substances 0.000 description 9
239000000463 material Substances 0.000 description 9
238000011282 treatment Methods 0.000 description 9
229910052715 tantalum Inorganic materials 0.000 description 8
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 8
AUVPWTYQZMLSKY-UHFFFAOYSA-N boron;vanadium Chemical compound [V]#B AUVPWTYQZMLSKY-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
238000002844 melting Methods 0.000 description 6
230000008018 melting Effects 0.000 description 6
NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 6
229910003468 tantalcarbide Inorganic materials 0.000 description 6
UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 5
239000002131 composite material Substances 0.000 description 5
238000009826 distribution Methods 0.000 description 5
239000010959 steel Substances 0.000 description 5
229910001868 water Inorganic materials 0.000 description 5
229910021550 Vanadium Chloride Inorganic materials 0.000 description 4
FSDZRQFSRALZQJ-UHFFFAOYSA-N [B].[Fe].[Fe] Chemical compound [B].[Fe].[Fe] FSDZRQFSRALZQJ-UHFFFAOYSA-N 0.000 description 4
VDZMENNHPJNJPP-UHFFFAOYSA-N boranylidyneniobium Chemical compound [Nb]#B VDZMENNHPJNJPP-UHFFFAOYSA-N 0.000 description 4
239000012298 atmosphere Substances 0.000 description 3
ZDVYABSQRRRIOJ-UHFFFAOYSA-N boron;iron Chemical compound [Fe]#B ZDVYABSQRRRIOJ-UHFFFAOYSA-N 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
229910000851 Alloy steel Inorganic materials 0.000 description 2
229910000592 Ferroniobium Inorganic materials 0.000 description 2
XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 description 2
238000001000 micrograph Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 description 1
HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
229910000975 Carbon steel Inorganic materials 0.000 description 1
101100400378 Mus musculus Marveld2 gene Proteins 0.000 description 1
229910019501 NaVO3 Inorganic materials 0.000 description 1
229910019714 Nb2O3 Inorganic materials 0.000 description 1
WRSVIZQEENMKOC-UHFFFAOYSA-N [B].[Co].[Co].[Co] Chemical compound [B].[Co].[Co].[Co] WRSVIZQEENMKOC-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
LAROCDZIZGIQGR-UHFFFAOYSA-N boron;vanadium Chemical compound B#[V]#B LAROCDZIZGIQGR-UHFFFAOYSA-N 0.000 description 1
239000010962 carbon steel Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000002050 diffraction method Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Carbon And Carbon Compounds (AREA)

CA170,290A 1972-05-04 1973-05-03 Electrodeposition d'un carbure du groupe va sur un article en fer, en alliage ferreux ou en carbure cemente Expired CA1052317A (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
JP47043729A JPS5121384B2 (fr)	1972-05-04	1972-05-04
JP4608072A JPS5527146B2 (fr)	1972-05-09	1972-05-09
JP5649372A JPS5216453B2 (fr)	1972-06-08	1972-06-08

Publications (1)

Publication Number	Publication Date
CA1052317A true CA1052317A (fr)	1979-04-10

Family

ID=27291652

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA170,290A Expired CA1052317A (fr)	1972-05-04	1973-05-03	Electrodeposition d'un carbure du groupe va sur un article en fer, en alliage ferreux ou en carbure cemente

Country Status (2)

Country	Link
US (1)	US3887443A (fr)
CA (1)	CA1052317A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5429847A (en) *	1977-08-11	1979-03-06	Toyoda Chuo Kenkyusho Kk	Method of forming composite carbide layer of chromium and one or more of 5a group elements on surface of iron alloy
US4430170A (en)	1983-01-17	1984-02-07	The United States Of America As Represented By The Secretary Of The Navy	Electrodeposition of refractory metal carbides
US6458218B1 (en)	2001-01-16	2002-10-01	Linamar Corporation	Deposition and thermal diffusion of borides and carbides of refractory metals

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2950233A (en) *	1954-04-29	1960-08-23	Horizons Inc	Production of hard surfaces on base metals
US2984605A (en) *	1959-03-16	1961-05-16	Walter M Weil	Deposition of boron from fused salt baths
US3024176A (en) *	1959-08-04	1962-03-06	Gen Electric	Corrosion resistant coating
US3444058A (en) *	1967-01-16	1969-05-13	Union Carbide Corp	Electrodeposition of refractory metals

1973
- 1973-04-27 US US355283A patent/US3887443A/en not_active Expired - Lifetime
- 1973-05-03 CA CA170,290A patent/CA1052317A/fr not_active Expired

Also Published As

Publication number	Publication date
US3887443A (en)	1975-06-03

Publication	Publication Date	Title
Dearnley et al.	1985	Engineering the surface with boron based materials
EP0264448B1 (fr)	1990-02-07	Procede de traitement de la surface de ferro-alliages
US3719518A (en)	1973-03-06	Process of forming a carbide layer of vanadium, niobium or tantalum upon a steel surface
CN101910471B (zh)	2012-07-04	利用高速电解工序硼化涂层的方法
CA1098254A (fr)	1981-03-31	Traduction non-disponible
US3922405A (en)	1975-11-25	Method for forming of a carbide layer of a V-a group element of the periodic table on the surface of an iron, ferrous alloy or cemented carbide article
US4453987A (en)	1984-06-12	Method for producing edged tools
US3885059A (en)	1975-05-20	Method for forming a carbide layer of a IV-b group element of the periodic table on the surface of a cemented carbide article
US3912827A (en)	1975-10-14	Method for forming a chromium carbide layer on the surface of an iron, ferrous alloy or cemented carbide article
US4818351A (en)	1989-04-04	Method for the surface treatment of an iron or iron alloy article
CA1036976A (fr)	1978-08-22	Dissolution d'un element anodique de groupe v-a dans un bain de borate en fusion
CN106995910B (zh)	2020-11-27	一种覆有碳化物涂层的金属基材料及制备方法
US3671297A (en)	1972-06-20	Method of chromizing in a fused salt bath
US2950233A (en)	1960-08-23	Production of hard surfaces on base metals
US3589927A (en)	1971-06-29	Chromising of ferrous metal substrates
US3885064A (en)	1975-05-20	Method for forming a chromium carbide layer on the surface of an iron, ferrous alloy or cemented carbide article
US3887443A (en)	1975-06-03	Method for forming a carbide layer of an element selected from the group consisting of V, Nb, Ta and mixtures thereof on the surface of an iron, ferrous alloy or cemented carbide article
US11834746B2 (en)	2023-12-05	Methods and systems for electroless plating a first metal onto a second metal in a molten salt bath, and surface pretreatments therefore
US3959092A (en)	1976-05-25	Method for a surface treatment of cemented carbide article
EP0122529B1 (fr)	1987-03-18	Méthode pour endurcir la surface d'un objet en alliage ferreux et produit en résultant
EP0063386B1 (fr)	1985-08-28	Procédé pour la formation d'une couche de carbure sur la surface d'un objet en alliage de fer ou d'un carbure cimenté
US4804445A (en)	1989-02-14	Method for the surface treatment of an iron or iron alloy article
JPH05140725A (ja)	1993-06-08	チタン材料の表面処理法
Sahayaraj et al.	2014	Effect of heat treatment temperature on the corrosion performance of electroless Ni-P/Ni-P-TiO2 deposits on carbon steel
JP3083292B1 (ja)	2000-09-04	鋼表面へのアルミニウム拡散方法