CA1052585A - Extraction du zinc par echange d'ions en phase liquide - Google Patents
Extraction du zinc par echange d'ions en phase liquideInfo
- Publication number
- CA1052585A CA1052585A CA218,131A CA218131A CA1052585A CA 1052585 A CA1052585 A CA 1052585A CA 218131 A CA218131 A CA 218131A CA 1052585 A CA1052585 A CA 1052585A
- Authority
- CA
- Canada
- Prior art keywords
- hydroxyquinoline
- hydroxy
- chloro
- substituted
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011701 zinc Substances 0.000 title description 53
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title description 30
- 229910052725 zinc Inorganic materials 0.000 title description 30
- 238000000605 extraction Methods 0.000 title description 21
- 239000007788 liquid Substances 0.000 title description 3
- 238000005342 ion exchange Methods 0.000 title 1
- 239000000243 solution Substances 0.000 description 33
- 239000003153 chemical reaction reagent Substances 0.000 description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- -1 phenolic oximes Chemical class 0.000 description 21
- 239000000047 product Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 229910001868 water Inorganic materials 0.000 description 16
- 150000002923 oximes Chemical class 0.000 description 15
- 150000004325 8-hydroxyquinolines Chemical class 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000002253 acid Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 10
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 10
- 229960003540 oxyquinoline Drugs 0.000 description 10
- 239000012074 organic phase Substances 0.000 description 9
- DINPBTCLBJIABS-UHFFFAOYSA-N 7-dodec-1-enylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C=CCCCCCCCCCC)=CC=C21 DINPBTCLBJIABS-UHFFFAOYSA-N 0.000 description 8
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- TWZIVEXYNWAOMT-VAWYXSNFSA-N (e)-1-chlorododec-1-ene Chemical compound CCCCCCCCCC\C=C\Cl TWZIVEXYNWAOMT-VAWYXSNFSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 4
- UEQAYHVRGVWMRI-UHFFFAOYSA-N 5-chloro-7-dodec-1-enylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C=CCCCCCCCCCC)=CC(Cl)=C21 UEQAYHVRGVWMRI-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000012043 crude product Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 150000003248 quinolines Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- BZJTUOGZUKFLQT-UHFFFAOYSA-N 1,3,5,7-tetramethylcyclooctane Chemical group CC1CC(C)CC(C)CC(C)C1 BZJTUOGZUKFLQT-UHFFFAOYSA-N 0.000 description 3
- ABVDSXUHJIXQGQ-UHFFFAOYSA-N 5-chloro-7-dodecylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(CCCCCCCCCCCC)=CC(Cl)=C21 ABVDSXUHJIXQGQ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- CTQMJYWDVABFRZ-UHFFFAOYSA-N cloxiquine Chemical compound C1=CN=C2C(O)=CC=C(Cl)C2=C1 CTQMJYWDVABFRZ-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- DNYZBFWKVMKMRM-UHFFFAOYSA-N n-benzhydrylidenehydroxylamine Chemical compound C=1C=CC=CC=1C(=NO)C1=CC=CC=C1 DNYZBFWKVMKMRM-UHFFFAOYSA-N 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RKAMCQVGHFRILV-UHFFFAOYSA-N 1-chlorononane Chemical compound CCCCCCCCCCl RKAMCQVGHFRILV-UHFFFAOYSA-N 0.000 description 2
- DRHABPMHZRIRAH-UHFFFAOYSA-N 2,4,4,6,6-pentamethylhept-2-ene Chemical group CC(C)=CC(C)(C)CC(C)(C)C DRHABPMHZRIRAH-UHFFFAOYSA-N 0.000 description 2
- NBYLBWHHTUWMER-UHFFFAOYSA-N 2-Methylquinolin-8-ol Chemical compound C1=CC=C(O)C2=NC(C)=CC=C21 NBYLBWHHTUWMER-UHFFFAOYSA-N 0.000 description 2
- NWSIFTLPLKCTSX-UHFFFAOYSA-N 4-chloro-2-nitrophenol Chemical compound OC1=CC=C(Cl)C=C1[N+]([O-])=O NWSIFTLPLKCTSX-UHFFFAOYSA-N 0.000 description 2
- OHYRIHZDJVDRGA-UHFFFAOYSA-N 5-bromo-7-dodecylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(CCCCCCCCCCCC)=CC(Br)=C21 OHYRIHZDJVDRGA-UHFFFAOYSA-N 0.000 description 2
- CVICEEPAFUYBJG-UHFFFAOYSA-N 5-chloro-2,2-difluoro-1,3-benzodioxole Chemical group C1=C(Cl)C=C2OC(F)(F)OC2=C1 CVICEEPAFUYBJG-UHFFFAOYSA-N 0.000 description 2
- FYMIZJXAXKUKNO-UHFFFAOYSA-N 5-chloro-7-dodec-1-enyl-3-methylquinolin-8-ol Chemical compound C1=C(C)C=NC2=C(O)C(C=CCCCCCCCCCC)=CC(Cl)=C21 FYMIZJXAXKUKNO-UHFFFAOYSA-N 0.000 description 2
- VVGBHDHVFLURBA-UHFFFAOYSA-N 5-chloro-7-dodecyl-4-methylquinolin-8-ol Chemical compound CC1=CC=NC2=C(O)C(CCCCCCCCCCCC)=CC(Cl)=C21 VVGBHDHVFLURBA-UHFFFAOYSA-N 0.000 description 2
- VOHHCUUIBNXCNP-UHFFFAOYSA-N 7-(5,5,7,7-tetramethyloct-1-en-3-yl)quinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C(C=C)CC(C)(C)CC(C)(C)C)=CC=C21 VOHHCUUIBNXCNP-UHFFFAOYSA-N 0.000 description 2
- WBVDIAQTOIUOSW-UHFFFAOYSA-N 7-dodecylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(CCCCCCCCCCCC)=CC=C21 WBVDIAQTOIUOSW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 2
- 125000001246 bromo group Chemical group Br* 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 229940000425 combination drug Drugs 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- QAOGXSMVDWPUTB-UHFFFAOYSA-N (2-nonylphenyl)-phenylmethanone Chemical compound CCCCCCCCCC1=CC=CC=C1C(=O)C1=CC=CC=C1 QAOGXSMVDWPUTB-UHFFFAOYSA-N 0.000 description 1
- DVOYYVNTAWFQAV-UHFFFAOYSA-N 1-chloro-5,5,7,7-tetramethyloct-2-ene Chemical compound CC(C)(C)CC(C)(C)CC=CCCl DVOYYVNTAWFQAV-UHFFFAOYSA-N 0.000 description 1
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- FGTCYTZEIKWZRE-UHFFFAOYSA-N 2-chloro-6-(N-hydroxy-C-phenylcarbonimidoyl)-4-nonylphenol Chemical compound CCCCCCCCCC1=CC(Cl)=C(O)C(C(=NO)C=2C=CC=CC=2)=C1 FGTCYTZEIKWZRE-UHFFFAOYSA-N 0.000 description 1
- SKWGLHQXFORVJD-UHFFFAOYSA-N 5-bromo-7-dodecyl-2-methylquinolin-8-ol Chemical compound C1=CC(C)=NC2=C(O)C(CCCCCCCCCCCC)=CC(Br)=C21 SKWGLHQXFORVJD-UHFFFAOYSA-N 0.000 description 1
- UFEVEKUEVOSRJT-UHFFFAOYSA-N 5-chloro-3-methylquinolin-8-ol Chemical compound OC1=CC=C(Cl)C2=CC(C)=CN=C21 UFEVEKUEVOSRJT-UHFFFAOYSA-N 0.000 description 1
- VKECXRPCUSXANC-UHFFFAOYSA-N 5-chloro-7-(10-methylundec-1-enyl)quinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C=CCCCCCCCC(C)C)=CC(Cl)=C21 VKECXRPCUSXANC-UHFFFAOYSA-N 0.000 description 1
- WRNNQLXYLRGUTA-UHFFFAOYSA-N 5-chloro-7-(10-methylundec-1-enyl)quinolin-8-ol 2-methylprop-1-ene Chemical compound CC(C)=C.CC(C)=C.CC(C)=C.C1=CC=NC2=C(O)C(C=CCCCCCCCC(C)C)=CC(Cl)=C21 WRNNQLXYLRGUTA-UHFFFAOYSA-N 0.000 description 1
- VPTDIGMOADCHGA-UHFFFAOYSA-N 5-chloro-7-dodecyl-2-methylquinolin-8-ol Chemical compound C1=CC(C)=NC2=C(O)C(CCCCCCCCCCCC)=CC(Cl)=C21 VPTDIGMOADCHGA-UHFFFAOYSA-N 0.000 description 1
- OEUICWRAHIHDJZ-UHFFFAOYSA-N 5-chloro-7-oct-1-enylquinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C=CCCCCCC)=CC(Cl)=C21 OEUICWRAHIHDJZ-UHFFFAOYSA-N 0.000 description 1
- YSBJUGXCWIEWLD-UHFFFAOYSA-N 7-dodec-1-enyl-2-methylquinolin-8-ol Chemical compound C1=CC(C)=NC2=C(O)C(C=CCCCCCCCCCC)=CC=C21 YSBJUGXCWIEWLD-UHFFFAOYSA-N 0.000 description 1
- BHWWGVDLAQGFOR-UHFFFAOYSA-N 7-dodecyl-2-methylquinolin-8-ol Chemical compound C1=CC(C)=NC2=C(O)C(CCCCCCCCCCCC)=CC=C21 BHWWGVDLAQGFOR-UHFFFAOYSA-N 0.000 description 1
- 101000856746 Bos taurus Cytochrome c oxidase subunit 7A1, mitochondrial Proteins 0.000 description 1
- BGWNEGDRVYDLBK-UHFFFAOYSA-N CC=C.CC=C.CC=C.CC=C.C1=CC=NC2=C(O)C(C=CCCCCCCCC(C)C)=CC(Cl)=C21 Chemical compound CC=C.CC=C.CC=C.CC=C.C1=CC=NC2=C(O)C(C=CCCCCCCCC(C)C)=CC(Cl)=C21 BGWNEGDRVYDLBK-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 102100025597 Caspase-4 Human genes 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101100273284 Homo sapiens CASP4 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- YXAJNVUUZOLUSA-UHFFFAOYSA-N acetohydrazide;pyridin-1-ium;chloride Chemical compound [Cl-].CC(=O)NN.C1=CC=[NH+]C=C1 YXAJNVUUZOLUSA-UHFFFAOYSA-N 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- YFBPWLXQILLTFR-UHFFFAOYSA-N n-[(2-nonylphenyl)-phenylmethylidene]hydroxylamine Chemical compound CCCCCCCCCC1=CC=CC=C1C(=NO)C1=CC=CC=C1 YFBPWLXQILLTFR-UHFFFAOYSA-N 0.000 description 1
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- FNXKBSAUKFCXIK-UHFFFAOYSA-M sodium;hydrogen carbonate;8-hydroxy-7-iodoquinoline-5-sulfonic acid Chemical class [Na+].OC([O-])=O.C1=CN=C2C(O)=C(I)C=C(S(O)(=O)=O)C2=C1 FNXKBSAUKFCXIK-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/406—Mixtures at least one compound thereof being a heterocyclic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Quinoline Compounds (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44763074A | 1974-03-04 | 1974-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1052585A true CA1052585A (fr) | 1979-04-17 |
Family
ID=23777116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA218,131A Expired CA1052585A (fr) | 1974-03-04 | 1975-01-17 | Extraction du zinc par echange d'ions en phase liquide |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS50120421A (fr) |
| AU (1) | AU7777875A (fr) |
| CA (1) | CA1052585A (fr) |
| GB (1) | GB1499139A (fr) |
| ZA (1) | ZA75411B (fr) |
| ZM (1) | ZM1675A1 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE408268B (sv) * | 1977-07-11 | 1979-06-05 | Berol Kemi Ab | Sett att selektivt extrahera metalljoner ur en vattenlosning samt extraktionsreagens for detta |
| LU83449A1 (fr) * | 1981-06-22 | 1983-04-06 | Metallurgie Hoboken | Procede pour separer du germanium d'une solution aqueuse a l'aide d'un alpha-hydroxyoxime |
| AT388570B (de) * | 1986-11-07 | 1989-07-25 | Bleiberger Bergwerks Union Ag | Extraktionsmittel sowie verfahren zur aufarbeitung von ge-haeltigen waesserigen loesungen durch fluessig/fluessigextraktion |
| DE3719437A1 (de) * | 1987-06-11 | 1988-12-22 | Hoechst Ag | Verfahren zur gewinnung von gallium aus basisch waessrigen natriumaluminatloesungen durch fluessig-fluessigextraktion |
-
1975
- 1975-01-17 CA CA218,131A patent/CA1052585A/fr not_active Expired
- 1975-01-21 ZA ZA00750411A patent/ZA75411B/xx unknown
- 1975-01-31 AU AU77778/75A patent/AU7777875A/en not_active Expired
- 1975-02-10 ZM ZM16/75A patent/ZM1675A1/xx unknown
- 1975-02-26 JP JP50022989A patent/JPS50120421A/ja active Pending
- 1975-03-04 GB GB8932/75A patent/GB1499139A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1499139A (en) | 1978-01-25 |
| ZA75411B (en) | 1976-01-28 |
| JPS50120421A (fr) | 1975-09-20 |
| ZM1675A1 (en) | 1975-12-22 |
| AU7777875A (en) | 1976-08-05 |
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