CA1053650A - Catalysts and carriers therefor - Google Patents

Catalysts and carriers therefor

Info

Publication number: CA1053650A
Authority: CA; Canada
Prior art keywords: radical; carbon atoms; catalyst; atom; inorganic particulate
Prior art date: 1974-11-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA239,158A

Other languages

English (en)

French (fr)

Inventor

Grish Chandra

Brian J. Griffiths

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Silicones UK Ltd

Original Assignee

Dow Corning Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-11-12

Filing date

1975-11-07

Publication date

1979-05-01

1975-11-07 Application filed by Dow Corning Ltd filed Critical Dow Corning Ltd

1979-05-01 Application granted granted Critical

1979-05-01 Publication of CA1053650A publication Critical patent/CA1053650A/en

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 53
239000000969 carrier Substances 0.000 title description 4
238000006243 chemical reaction Methods 0.000 claims abstract description 33
239000007787 solid Substances 0.000 claims abstract description 33
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 28
239000000126 substance Substances 0.000 claims abstract description 18
239000010948 rhodium Substances 0.000 claims abstract description 15
150000001875 compounds Chemical class 0.000 claims abstract description 14
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 13
229910052697 platinum Inorganic materials 0.000 claims abstract description 13
229910052703 rhodium Inorganic materials 0.000 claims abstract description 12
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 9
150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 5
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 5
-1 hydrocarbon radical Chemical class 0.000 claims description 34
125000004432 carbon atom Chemical group C* 0.000 claims description 26
150000003254 radicals Chemical class 0.000 claims description 24
238000000034 method Methods 0.000 claims description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
239000004215 Carbon black (E152) Substances 0.000 claims description 12
229930195733 hydrocarbon Natural products 0.000 claims description 12
125000004429 atom Chemical group 0.000 claims description 11
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
238000002360 preparation method Methods 0.000 claims description 7
125000001931 aliphatic group Chemical group 0.000 claims description 6
125000001424 substituent group Chemical group 0.000 claims description 6
229910052801 chlorine Inorganic materials 0.000 claims description 5
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
150000005840 aryl radicals Chemical group 0.000 claims description 4
125000001309 chloro group Chemical group Cl* 0.000 claims description 4
125000005375 organosiloxane group Chemical group 0.000 claims description 4
125000004430 oxygen atom Chemical group O* 0.000 claims description 4
229910000077 silane Inorganic materials 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
229910052710 silicon Inorganic materials 0.000 claims description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
229910052794 bromium Inorganic materials 0.000 claims 1
238000006459 hydrosilylation reaction Methods 0.000 abstract description 8
239000005864 Sulphur Substances 0.000 abstract description 7
238000007037 hydroformylation reaction Methods 0.000 abstract description 2
238000005984 hydrogenation reaction Methods 0.000 abstract description 2
239000000047 product Substances 0.000 description 14
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
239000000741 silica gel Substances 0.000 description 10
229910002027 silica gel Inorganic materials 0.000 description 10
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
239000008096 xylene Substances 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
235000019441 ethanol Nutrition 0.000 description 5
229910003480 inorganic solid Inorganic materials 0.000 description 5
239000002904 solvent Substances 0.000 description 5
238000001914 filtration Methods 0.000 description 4
239000000376 reactant Substances 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
239000000463 material Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000002798 polar solvent Substances 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
238000011084 recovery Methods 0.000 description 3
238000010992 reflux Methods 0.000 description 3
150000003573 thiols Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
238000001030 gas--liquid chromatography Methods 0.000 description 2
150000008282 halocarbons Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
239000003446 ligand Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000002245 particle Substances 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
229910002621 H2PtCl6 Inorganic materials 0.000 description 1
101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000009850 completed effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000011953 free-radical catalyst Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000005048 methyldichlorosilane Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000001282 organosilanes Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
229920001843 polymethylhydrosiloxane Polymers 0.000 description 1
239000010453 quartz Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000012262 resinous product Substances 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
239000000758 substrate Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
- B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/226—Sulfur, e.g. thiocarbamates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/14—Preparation thereof from optionally substituted halogenated silanes and hydrocarbons hydrosilylation reactions
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Silicon Polymers (AREA)

CA239,158A 1974-11-12 1975-11-07 Catalysts and carriers therefor Expired CA1053650A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB49028/74A GB1527598A (en)	1974-11-12	1974-11-12	Catalysts and carriers therefor

Publications (1)

Publication Number	Publication Date
CA1053650A true CA1053650A (en)	1979-05-01

Family

ID=10450847

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA239,158A Expired CA1053650A (en)	1974-11-12	1975-11-07	Catalysts and carriers therefor

Country Status (6)

Country	Link
US (1)	US4005046A (2)
JP (1)	JPS5542078B2 (2)
CA (1)	CA1053650A (2)
DE (1)	DE2550660C3 (2)
FR (1)	FR2290949A1 (2)
GB (1)	GB1527598A (2)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1526324A (en) *	1976-07-14	1978-09-27	Dow Corning Ltd	Hydrosilylation catalysts
DE2858038C2 (de) *	1978-08-08	1983-11-10	Degussa Ag, 6000 Frankfurt	Monomere, polymere und traegerfixierte rhodiumkomplexverbindungen, verfahren zu ihrer herstellung und verwendung als katalysatoren
NL7902964A (nl) *	1979-04-14	1980-10-16	Nl Org Zuiver Wetenschapp	Heterogene katalysator op basis van een metaal- organisch complex.
GB8322318D0 (en) *	1983-08-18	1983-09-21	Dow Corning Ltd	Organic compounds
US4503160A (en) *	1983-08-29	1985-03-05	General Electric Company	Hydrosilylation method, catalyst and method for making
CA1245675A (en) *	1984-09-21	1988-11-29	Ronald H. Baney	Ceramic materials from silazane polymers
US5028575A (en) *	1990-04-27	1991-07-02	University Of Pittsburgh	Process for the chemical modification of aluminum oxide supported rhodium catalysts and associated automotive catalyst
GB9126049D0 (en) *	1991-12-07	1992-02-05	Dow Corning	Hydrosilylation process
DE19540497A1 (de) *	1995-10-31	1997-05-07	Degussa	Sulfonat- und mercaptogruppenhaltige anorganische Trägermaterialien, Verfahren zu ihrer Herstellung und Verwendung als Katalysatoren
DE69703728T2 (de) *	1996-10-31	2001-06-28	Repsol Quimica S.A., Madrid	Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
DE19816921A1 (de) *	1998-04-16	1999-10-21	Wacker Chemie Gmbh	Verfahren für kontinuierliche polymeranaloge Umsetzungen
DE69914012T2 (de) *	1998-04-27	2004-12-09	Repsol Quimica S.A.	Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
DE69916358T2 (de) *	1998-04-29	2005-04-21	Repsol Quimica Sa	Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6184171B1 (en) *	1998-10-05	2001-02-06	W.R. Grace & Co. -Conn	Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US9982095B2 (en)	2004-08-04	2018-05-29	Phosphonics Ltd	Substituted organopolysiloxanes and use thereof
GB0602811D0 (en) *	2006-02-10	2006-03-22	Phosphonics Ltd	Substituted Organopolysiloxanes And Use Thereof
EP1996321A2 (en) *	2006-03-10	2008-12-03	PPG Industries Ohio, Inc.	Heterogeneous hydrosilylation catalysts, polymers formed therewith, and related coating compositions
EP2446965A1 (en) *	2010-11-02	2012-05-02	Evonik Degussa GmbH	Process for preparation of supported catalysts and use of the catalyst for the esterification of free fatty acids in vegetable oil
CN112007634B (zh) *	2019-05-28	2023-08-29	新特能源股份有限公司	乙烯基三氯硅烷新型催化剂及其制备方法、及其催化制备乙烯基三氯硅烷的方法

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US3024126A (en) *	1960-06-15	1962-03-06	Dow Corning	Method of treating reinforcing silica
US3722181A (en) *	1970-05-22	1973-03-27	Du Pont	Chromatographic packing with chemically bonded organic stationary phases
US3775452A (en) *	1971-04-28	1973-11-27	Gen Electric	Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes
DE2236862C2 (de) *	1972-07-27	1974-09-05	Istvan Prof. Dr. 6600 Saarbruecken Halasz	Sorptionsmittel für die Chromatographie

1974
- 1974-11-12 GB GB49028/74A patent/GB1527598A/en not_active Expired
1975
- 1975-11-06 US US05/629,268 patent/US4005046A/en not_active Expired - Lifetime
- 1975-11-07 CA CA239,158A patent/CA1053650A/en not_active Expired
- 1975-11-11 DE DE2550660A patent/DE2550660C3/de not_active Expired
- 1975-11-12 FR FR7534468A patent/FR2290949A1/fr active Granted
- 1975-11-12 JP JP13612975A patent/JPS5542078B2/ja not_active Expired

Also Published As

Publication number	Publication date
DE2550660A1 (de)	1976-05-13
US4005046A (en)	1977-01-25
FR2290949B1 (2)	1977-12-16
JPS5542078B2 (2)	1980-10-28
DE2550660C3 (de)	1979-01-11
FR2290949A1 (fr)	1976-06-11
GB1527598A (en)	1978-10-04
DE2550660B2 (de)	1978-04-20
JPS5171291A (2)	1976-06-19

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US4064154A (en)	1977-12-20	Catalysts and carriers therefor
US4005046A (en)	1977-01-25	Catalysts and carriers therefor
US4503160A (en)	1985-03-05	Hydrosilylation method, catalyst and method for making
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US4083803A (en)	1978-04-11	Anchored silylhydrocarbyl phosphine transition metal complex catalysts and their method of preparation
JP6486925B2 (ja)	2019-03-20	コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
Pagliaro et al.	2013	Platinum‐Based Heterogeneously Catalyzed Hydrosilylation
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CN109647532B (zh)	2021-08-27	一种非烯烃配位的铂孤原子在硅氢加成反应中的应用
Nowotny et al.	2001	Heterogeneous Dinuclear Rhodium (ii) Hydroformylation Catalysts—Performance Evaluation and Silsesquioxane‐Based Chemical Modeling
KR20250130383A (ko)	2025-09-01	망간 착물에 의해 촉매화된 하이드로실릴화 방법
EP3071585B1 (en)	2018-11-07	Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
NL7906041A (nl)	1980-02-12	Monomere, polymere en drager-gefixeerde complexe rhodiumverbindingen, werkwijze voor hun bereiding en toepassing als katalysatoren.
US3992427A (en)	1976-11-16	Preparation of organosilicon compounds
DE2731870C2 (2)	1988-09-22
US5270424A (en)	1993-12-14	Hydrosilylation process
US5142037A (en)	1992-08-25	Platinum catalyst composition and process for producing the same
US5041591A (en)	1991-08-20	Organopolysiloxane and method for its preparation
US4533744A (en)	1985-08-06	Hydrosilylation method, catalyst and method for making
EP3140037A1 (en)	2017-03-15	Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
EP0061241A1 (en)	1982-09-29	Platinum-, rhodium-, and iridium-nitrogen complex catalysts
EP0605226B1 (en)	1998-01-07	Phosphinoaliphatic silane catalysts for preparation of beta-cyanoalkylsilanes
EP2073932B1 (en)	2013-06-12	Heterogenized rhodium complexes, methods of their synthesis and application as hydrosilylation catalysts
JP3522860B2 (ja)	2004-04-26	ハイドロシリレーション法
JPH08143777A (ja)	1996-06-04	有機系硬化剤の製造方法