CA1055179A - Composes refractaires - Google Patents

Composes refractaires

Info

Publication number: CA1055179A
Authority: CA; Canada
Prior art keywords: phenol; parts; resin; composition; lignin
Prior art date: 1974-12-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA241,686A

Other languages

English (en)

Other versions

CA241686S (en

Inventor

Kyohei Funabiki

Tetsuya Tokunaga

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sumitomo Durez Co Ltd

Original Assignee

Sumitomo Durez Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-12-11

Filing date

1975-12-11

Publication date

1979-05-22

1975-12-11 Application filed by Sumitomo Durez Co Ltd filed Critical Sumitomo Durez Co Ltd

1979-05-22 Application granted granted Critical

1979-05-22 Publication of CA1055179A publication Critical patent/CA1055179A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 59
229920005610 lignin Polymers 0.000 claims abstract description 44
235000013379 molasses Nutrition 0.000 claims abstract description 39
229920005989 resin Polymers 0.000 claims abstract description 38
239000011347 resin Substances 0.000 claims abstract description 38
239000011819 refractory material Substances 0.000 claims abstract description 32
239000011233 carbonaceous binding agent Substances 0.000 claims abstract description 16
239000007787 solid Substances 0.000 claims abstract description 8
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 59
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 33
239000003795 chemical substances by application Substances 0.000 claims description 17
150000001299 aldehydes Chemical class 0.000 claims description 12
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 11
238000000465 moulding Methods 0.000 claims description 10
229920003986 novolac Polymers 0.000 claims description 10
239000007788 liquid Substances 0.000 claims description 9
239000003377 acid catalyst Substances 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 8
239000000376 reactant Substances 0.000 claims description 8
239000002655 kraft paper Substances 0.000 claims description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
239000000463 material Substances 0.000 claims description 5
229920003987 resole Polymers 0.000 claims description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
239000012298 atmosphere Substances 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
238000009833 condensation Methods 0.000 claims description 3
230000005494 condensation Effects 0.000 claims description 3
239000000395 magnesium oxide Substances 0.000 claims description 3
-1 alkyl phenols Chemical class 0.000 claims description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
239000004927 clay Substances 0.000 claims description 2
229910052570 clay Inorganic materials 0.000 claims description 2
239000010459 dolomite Substances 0.000 claims description 2
229910000514 dolomite Inorganic materials 0.000 claims description 2
239000000377 silicon dioxide Substances 0.000 claims description 2
230000003197 catalytic effect Effects 0.000 claims 3
238000001354 calcination Methods 0.000 claims 1
230000008020 evaporation Effects 0.000 claims 1
238000001704 evaporation Methods 0.000 claims 1
230000001590 oxidative effect Effects 0.000 claims 1
238000005452 bending Methods 0.000 abstract 1
230000003292 diminished effect Effects 0.000 abstract 1
239000011230 binding agent Substances 0.000 description 25
229920001568 phenolic resin Polymers 0.000 description 17
239000005011 phenolic resin Substances 0.000 description 17
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 16
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 14
239000003054 catalyst Substances 0.000 description 13
239000000047 product Substances 0.000 description 12
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
229960004279 formaldehyde Drugs 0.000 description 8
235000019256 formaldehyde Nutrition 0.000 description 8
235000010299 hexamethylene tetramine Nutrition 0.000 description 8
239000004312 hexamethylene tetramine Substances 0.000 description 8
229960004011 methenamine Drugs 0.000 description 8
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 6
239000008098 formaldehyde solution Substances 0.000 description 6
239000003960 organic solvent Substances 0.000 description 6
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 5
229930003836 cresol Natural products 0.000 description 5
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000011134 resol-type phenolic resin Substances 0.000 description 4
239000011269 tar Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
238000003763 carbonization Methods 0.000 description 3
239000000571 coke Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000011295 pitch Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
229930040373 Paraformaldehyde Natural products 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
230000007547 defect Effects 0.000 description 2
239000007849 furan resin Substances 0.000 description 2
HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
238000004898 kneading Methods 0.000 description 2
239000010680 novolac-type phenolic resin Substances 0.000 description 2
235000006408 oxalic acid Nutrition 0.000 description 2
229920002866 paraformaldehyde Polymers 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229940093932 potassium hydroxide Drugs 0.000 description 2
235000011118 potassium hydroxide Nutrition 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
239000000565 sealant Substances 0.000 description 2
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
239000000080 wetting agent Substances 0.000 description 2
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
241000518994 Conta Species 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
229910001863 barium hydroxide Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
230000000711 cancerogenic effect Effects 0.000 description 1
231100000315 carcinogenic Toxicity 0.000 description 1
238000001816 cooling Methods 0.000 description 1
HDNHWROHHSBKJG-UHFFFAOYSA-N formaldehyde;furan-2-ylmethanol Chemical compound O=C.OCC1=CC=CO1 HDNHWROHHSBKJG-UHFFFAOYSA-N 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
230000005802 health problem Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000002609 medium Substances 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000011299 tars and pitches Substances 0.000 description 1
229940086542 triethylamine Drugs 0.000 description 1
238000009736 wetting Methods 0.000 description 1
230000003245 working effect Effects 0.000 description 1

Landscapes

Compositions Of Oxide Ceramics (AREA)
Ceramic Products (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA241,686A 1974-12-11 1975-12-11 Composes refractaires Expired CA1055179A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP14147674A JPS5619312B2 (fr)	1974-12-11	1974-12-11

Publications (1)

Publication Number	Publication Date
CA1055179A true CA1055179A (fr)	1979-05-22

Family

ID=15292765

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA241,686A Expired CA1055179A (fr)	1974-12-11	1975-12-11	Composes refractaires

Country Status (2)

Country	Link
JP (1)	JPS5619312B2 (fr)
CA (1)	CA1055179A (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2435566A1 (fr) *	1978-08-16	1980-04-04	Piat Moise	Mecanisme de chasse d'eau pour appareil sanitaire
JPS5527853A (en) *	1978-08-18	1980-02-28	Mitsui Toatsu Chemicals	Manufacture of binder for refractories and composition therefor
NL8302955A (nl) *	1983-08-24	1985-03-18	Hoogovens Groep Bv	Werkwijze voor het vervaardigen van een magnesia-koolstofsteen, magnesia-koolstofsteen vervaardigd met de werkwijze en converter voorzien van een slijtvoering, die althans gedeeltelijk bestaat uit magnesia-koolstofstenen vervaardigd met de werkwijze.
CN105873970B (zh) *	2014-03-28	2019-09-10	住友电木株式会社	酚改性木质素树脂和其制造方法、以及树脂组合物、橡胶组合物和固化物
CN117800687B (zh) *	2023-12-29	2025-04-25	长大市政工程(广东)有限公司	一种增加透水混凝土粒间粘结强度的混合料及其制备方法

1974
- 1974-12-11 JP JP14147674A patent/JPS5619312B2/ja not_active Expired
1975
- 1975-12-11 CA CA241,686A patent/CA1055179A/fr not_active Expired

Also Published As

Publication number	Publication date
JPS5168611A (fr)	1976-06-14
JPS5619312B2 (fr)	1981-05-07

Publication	Publication Date	Title
US4058403A (en)	1977-11-15	Refractory compositions
US4918116A (en)	1990-04-17	High temperature resistant molding materials
US4072531A (en)	1978-02-07	Plugging compositions for blast furnace tap holes
JP3693733B2 (ja)	2005-09-07	耐火性骨材と共に用いるためのフェノールノボラックの混合物及びそれらを作る方法
US5304225A (en)	1994-04-19	Binder mixture
GB2096985A (en)	1982-10-27	Carbon containing refractory bricks and shapes and methods of making such bricks and shapes
US20060119018A1 (en)	2006-06-08	Cold-curing binder and process ror producing molding with the same
JP5536299B2 (ja)	2014-07-02	環境に優しい炭素結合した耐火性生成物の低温混合方法による製造
CA1055179A (fr)	1979-05-22	Composes refractaires
US5254639A (en)	1993-10-19	Binding agents
US6046252A (en)	2000-04-04	Curatives for phenolic novolacs
US4501836A (en)	1985-02-26	Liquid refractory binder
US7204878B2 (en)	2007-04-17	Refractory mixes containing condensed tannin and furfuryl alcohol, and their uses
US4521357A (en)	1985-06-04	Carbon bonded refractories
JPS6026065B2 (ja)	1985-06-21	塩基性耐火物の製造法
EP0270377B1 (fr)	1992-04-15	Procédé de fabrication de corps réfractaires
US6620901B2 (en)	2003-09-16	High carbon yield phenolic resole
RU2337926C2 (ru)	2008-11-10	Продукты поликонденсации, способ их получения и их применение
JP4684464B2 (ja)	2011-05-18	耐火物組成物
JPS60221361A (ja)	1985-11-06	耐火物用組成物
JPS6144831B2 (fr)	1986-10-04
GB2131789A (en)	1984-06-27	Binder for calcined dolomite refractory compositions
JPH0216267B2 (fr)	1990-04-16
JP2005029394A (ja)	2005-02-03	不定形耐火物用結合剤組成物
JPS58179217A (ja)	1983-10-20	熱硬化性樹脂の製造法