CA1055243A - Injection d'un liquide de fracturation dans une formation souterraine - Google Patents

Injection d'un liquide de fracturation dans une formation souterraine

Info

Publication number: CA1055243A
Authority: CA; Canada
Prior art keywords: liquid; gum; emulsion; aqueous liquid; borate
Prior art date: 1975-05-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA252,489A

Other languages

English (en)

Inventor

Dustin L. Free

Alfred R. Hendrickson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-05-14

Filing date

1976-05-13

Publication date

1979-05-29

1976-05-13 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1979-05-29 Application granted granted Critical

1979-05-29 Publication of CA1055243A publication Critical patent/CA1055243A/fr

Status Expired legal-status Critical Current

Links

230000015572 biosynthetic process Effects 0.000 title claims abstract description 30
239000007788 liquid Substances 0.000 claims abstract description 68
239000000839 emulsion Substances 0.000 claims abstract description 47
239000012530 fluid Substances 0.000 claims abstract description 44
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 22
239000000872 buffer Substances 0.000 claims abstract description 19
150000001875 compounds Chemical class 0.000 claims abstract description 17
229920000926 Galactomannan Polymers 0.000 claims abstract description 14
230000002378 acidificating effect Effects 0.000 claims abstract description 14
229940063013 borate ion Drugs 0.000 claims abstract description 10
OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims abstract description 9
238000000034 method Methods 0.000 claims description 29
238000005755 formation reaction Methods 0.000 claims description 27
239000000203 mixture Substances 0.000 claims description 16
-1 borate ions Chemical class 0.000 claims description 14
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
229930195733 hydrocarbon Natural products 0.000 claims description 11
150000002430 hydrocarbons Chemical class 0.000 claims description 11
239000004215 Carbon black (E152) Substances 0.000 claims description 10
150000007514 bases Chemical class 0.000 claims description 10
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
229920002907 Guar gum Polymers 0.000 claims description 9
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 9
239000004327 boric acid Substances 0.000 claims description 9
238000004132 cross linking Methods 0.000 claims description 9
239000000665 guar gum Substances 0.000 claims description 9
235000010417 guar gum Nutrition 0.000 claims description 9
229960002154 guar gum Drugs 0.000 claims description 9
239000000395 magnesium oxide Substances 0.000 claims description 9
235000012245 magnesium oxide Nutrition 0.000 claims description 9
239000000470 constituent Substances 0.000 claims description 8
229960000869 magnesium oxide Drugs 0.000 claims description 8
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 8
239000000463 material Substances 0.000 claims description 8
239000003995 emulsifying agent Substances 0.000 claims description 7
239000007787 solid Substances 0.000 claims description 7
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
239000008346 aqueous phase Substances 0.000 claims description 5
150000003839 salts Chemical class 0.000 claims description 4
229940040526 anhydrous sodium acetate Drugs 0.000 claims description 3
230000003111 delayed effect Effects 0.000 claims description 3
238000002347 injection Methods 0.000 claims description 3
239000007924 injection Substances 0.000 claims description 3
150000007524 organic acids Chemical class 0.000 claims description 3
229940061631 citric acid acetate Drugs 0.000 claims 1
230000000149 penetrating effect Effects 0.000 abstract 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
239000000243 solution Substances 0.000 description 26
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 22
238000012360 testing method Methods 0.000 description 19
239000003921 oil Substances 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
239000001103 potassium chloride Substances 0.000 description 11
235000011164 potassium chloride Nutrition 0.000 description 11
244000303965 Cyamopsis psoralioides Species 0.000 description 9
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 9
239000004354 Hydroxyethyl cellulose Substances 0.000 description 8
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
239000003350 kerosene Substances 0.000 description 6
230000035699 permeability Effects 0.000 description 6
239000012071 phase Substances 0.000 description 6
230000036571 hydration Effects 0.000 description 5
238000006703 hydration reaction Methods 0.000 description 5
230000008569 process Effects 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
239000012267 brine Substances 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
235000013312 flour Nutrition 0.000 description 4
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
150000001639 boron compounds Chemical class 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
229960004106 citric acid Drugs 0.000 description 3
230000000694 effects Effects 0.000 description 3
125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 3
238000012986 modification Methods 0.000 description 3
230000004048 modification Effects 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
239000004576 sand Substances 0.000 description 3
239000001632 sodium acetate Substances 0.000 description 3
235000017281 sodium acetate Nutrition 0.000 description 3
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
229960002303 citric acid monohydrate Drugs 0.000 description 2
MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
230000001804 emulsifying effect Effects 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
239000001530 fumaric acid Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000007764 o/w emulsion Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
229920003169 water-soluble polymer Polymers 0.000 description 2
CASHWAGXBJSQDV-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)-1,3,5-triazine Chemical group C1=NC=NC(C=2N=CN=CN=2)=N1 CASHWAGXBJSQDV-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
235000002687 Caesalpinia echinata Nutrition 0.000 description 1
235000017399 Caesalpinia tinctoria Nutrition 0.000 description 1
241000531229 Caryopteris x clandonensis Species 0.000 description 1
235000006693 Cassia laevigata Nutrition 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
REJHVSOVQBJEBF-UHFFFAOYSA-N DSD-acid Natural products OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
244000230012 Gleditsia triacanthos Species 0.000 description 1
235000013813 Gleditsia triacanthos Nutrition 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
229920000161 Locust bean gum Polymers 0.000 description 1
241000282372 Panthera onca Species 0.000 description 1
241000127464 Paubrasilia echinata Species 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
241000522641 Senna Species 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
241000388430 Tara Species 0.000 description 1
FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
UKFWSNCTAHXBQN-UHFFFAOYSA-N ammonium iodide Chemical class [NH4+].[I-] UKFWSNCTAHXBQN-UHFFFAOYSA-N 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
230000003139 buffering effect Effects 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
125000004181 carboxyalkyl group Chemical group 0.000 description 1
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000000945 filler Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
230000000887 hydrating effect Effects 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000003317 industrial substance Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000009533 lab test Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000711 locust bean gum Substances 0.000 description 1
235000010420 locust bean gum Nutrition 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
229920001206 natural gum Polymers 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
238000005086 pumping Methods 0.000 description 1
239000002455 scale inhibitor Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
238000013112 stability test Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
DPUZPWAFXJXHBN-UHFFFAOYSA-N tetrasodium dioxidoboranyloxy(dioxido)borane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]B([O-])OB([O-])[O-] DPUZPWAFXJXHBN-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Landscapes

Colloid Chemistry (AREA)

CA252,489A 1975-05-14 1976-05-13 Injection d'un liquide de fracturation dans une formation souterraine Expired CA1055243A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US57725675A	1975-05-14	1975-05-14

Publications (1)

Publication Number	Publication Date
CA1055243A true CA1055243A (fr)	1979-05-29

Family

ID=24307933

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA252,489A Expired CA1055243A (fr)	1975-05-14	1976-05-13	Injection d'un liquide de fracturation dans une formation souterraine

Country Status (2)

Country	Link
AR (1)	AR208232A1 (fr)
CA (1)	CA1055243A (fr)

1976
- 1976-01-01 AR AR26330076A patent/AR208232A1/es active
- 1976-05-13 CA CA252,489A patent/CA1055243A/fr not_active Expired

Also Published As

Publication number	Publication date
AR208232A1 (es)	1976-12-09

Publication	Publication Date	Title
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EP0962626B1 (fr)	2003-02-12	Procédé de traitement des formations souterraines
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US6987083B2 (en)	2006-01-17	Xanthan gels in brines and methods of using such xanthan gels in subterranean formations
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US4412586A (en)	1983-11-01	Methods of inhibiting the flow of water in subterranean formations
US4559149A (en)	1985-12-17	Workover fluid
US7268101B2 (en)	2007-09-11	Formate based liquid gel concentrates
US7290614B2 (en)	2007-11-06	Methods for effecting controlled break in pH dependent foamed fracturing fluid
US4237974A (en)	1980-12-09	Method of controlling fluid loss in acidizing treatment of a subterranean formation
CA1176442A (fr)	1984-10-23	Methode pour augmenter l'hydratation de composes actives d'hydroethyl cellulose
CA1055243A (fr)	1979-05-29	Injection d'un liquide de fracturation dans une formation souterraine