CA1057764A - Catalyseur sur support pour l'oxydation de l'o-xylene ou du naphtalene en anhydride phtalique - Google Patents

Catalyseur sur support pour l'oxydation de l'o-xylene ou du naphtalene en anhydride phtalique

Info

Publication number: CA1057764A
Authority: CA; Canada
Prior art keywords: weight; supported catalyst; anatase; active material; catalyst
Prior art date: 1974-05-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA224A

Other languages

English (en)

Inventor

Kurt Blechschmitt

Paul Hornberger

Peter Reuter

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-05-03

Filing date

1975-04-15

Publication date

1979-07-03

1974-05-03 Priority claimed from DE2421406A external-priority patent/DE2421406C2/de

1975-04-15 Application filed by BASF SE filed Critical BASF SE

1979-07-03 Application granted granted Critical

1979-07-03 Publication of CA1057764A publication Critical patent/CA1057764A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 33
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 title claims abstract description 20
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 title claims abstract description 12
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 title claims abstract description 10
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 title claims abstract description 10
229940078552 o-xylene Drugs 0.000 title claims abstract description 10
230000003647 oxidation Effects 0.000 title claims abstract description 8
238000007254 oxidation reaction Methods 0.000 title claims abstract description 8
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 30
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 23
239000011149 active material Substances 0.000 claims abstract description 16
238000000034 method Methods 0.000 claims abstract description 12
230000003197 catalytic effect Effects 0.000 claims abstract description 11
150000001875 compounds Chemical class 0.000 claims abstract description 8
229910052792 caesium Inorganic materials 0.000 claims abstract description 6
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 6
229910052701 rubidium Inorganic materials 0.000 claims abstract description 6
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
239000011593 sulfur Substances 0.000 claims abstract description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
229910052787 antimony Inorganic materials 0.000 claims description 2
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
229910052785 arsenic Inorganic materials 0.000 claims description 2
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052758 niobium Inorganic materials 0.000 claims description 2
239000010955 niobium Substances 0.000 claims description 2
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
229910052698 phosphorus Inorganic materials 0.000 claims description 2
239000011574 phosphorus Substances 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
229910052726 zirconium Inorganic materials 0.000 claims description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical group 0.000 description 6
239000000463 material Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
229940022663 acetate Drugs 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001339 alkali metal compounds Chemical class 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910000024 caesium carbonate Inorganic materials 0.000 description 2
238000007600 charging Methods 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000203 mixture Substances 0.000 description 2
OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
241000286904 Leptothecata Species 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
-1 aluminas Inorganic materials 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000011049 filling Methods 0.000 description 1
229940044170 formate Drugs 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
238000011068 loading method Methods 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229940039748 oxalate Drugs 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
235000011837 pasties Nutrition 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
239000010453 quartz Substances 0.000 description 1
WPFGFHJALYCVMO-UHFFFAOYSA-L rubidium carbonate Chemical compound [Rb+].[Rb+].[O-]C([O-])=O WPFGFHJALYCVMO-UHFFFAOYSA-L 0.000 description 1
229910000026 rubidium carbonate Inorganic materials 0.000 description 1
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
229960001860 salicylate Drugs 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Catalysts (AREA)
Furan Compounds (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA224A 1974-05-03 1975-04-15 Catalyseur sur support pour l'oxydation de l'o-xylene ou du naphtalene en anhydride phtalique Expired CA1057764A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2421406A DE2421406C2 (de)	1972-12-12	1974-05-03	Verfahren zur Herstellung von Phthalsäureanhydrid

Publications (1)

Publication Number	Publication Date
CA1057764A true CA1057764A (fr)	1979-07-03

Family

ID=5914571

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA224A Expired CA1057764A (fr)	1974-05-03	1975-04-15	Catalyseur sur support pour l'oxydation de l'o-xylene ou du naphtalene en anhydride phtalique

Country Status (3)

Country	Link
JP (2)	JPS50150688A (fr)
CA (1)	CA1057764A (fr)
IT (1)	IT1049403B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7022643B2 (en)	2002-08-20	2006-04-04	Nippon Shokubai Co., Ltd.	Production process for catalyst
JP4295521B2 (ja)	2003-02-13	2009-07-15	株式会社日本触媒	アクリル酸製造用触媒およびアクリル酸の製造方法
EP2295136A4 (fr)	2008-06-30	2011-12-28	Nippon Catalytic Chem Ind	Procédé de conditionnement d'une substance particulaire solide dans un réacteur multitubulaire à lit fixe
JP2011121048A (ja)	2009-12-09	2011-06-23	Rohm & Haas Co	固体触媒物質をブレンドし、管状構造物に装填する方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2212964C3 (de) *	1972-03-17	1980-01-31	Basf Ag, 6700 Ludwigshafen	Vanadinpentoxid, Titandioxid und gegebenenfalls Zirkondioxid, Phosphor sowie weitere Metalloxide enthaltender Trägerkatalysator

1975
- 1975-04-08 IT IT22124/75A patent/IT1049403B/it active
- 1975-04-15 CA CA224A patent/CA1057764A/fr not_active Expired
- 1975-05-06 JP JP50053285A patent/JPS50150688A/ja active Pending
1980
- 1980-12-12 JP JP55174786A patent/JPS5815176B2/ja not_active Expired

Also Published As

Publication number	Publication date
JPS50150688A (fr)	1975-12-03
JPS5815176B2 (ja)	1983-03-24
IT1049403B (it)	1981-01-20
JPS5695337A (en)	1981-08-01

Publication	Publication Date	Title
US3909457A (en)	1975-09-30	Supported catalyst for the oxidation of o-xylene or naphthalene into phthalic anhydride
US4077984A (en)	1978-03-07	Manufacture of phthalic anhydride from o-xylene or naphthalene
US3509179A (en)	1970-04-28	Process for the production of phthalic anhydride
US4879387A (en)	1989-11-07	Method for manufacture of phthalic anhydride
US3894971A (en)	1975-07-15	Oxidation catalysts
US3565829A (en)	1971-02-23	Supported catalysts containing vanadium pentoxide and titanium dioxide
US4582912A (en)	1986-04-15	Process for preparing carboxylic anhydride using improved catalysts
US4096094A (en)	1978-06-20	Supported catalysts containing vanadium pentoxide and titanium dioxide
EP0951351A1 (fr)	1999-10-27	Utilisation d'un catalysateur a coque pour la preparation d'acide acetique par oxydation en phase gazeuse d'hydrocarbures c 4 insatures
US4835126A (en)	1989-05-30	Process for preparing a catalyst for the preparation of a carboxylic anhydride
CA1146153A (fr)	1983-05-10	Catalyseurs sur support, contenant du pentoxyde de vanadium, du dioxyde de titane, du phosphore, du rubidium et (ou) du cesium, avec ou sans dioxyde de zirconium
EP0170383B1 (fr)	1989-07-19	Catalyseurs pour la préparation d'anhydride d'acide carboxylique aromatique
US3830755A (en)	1974-08-20	Supported catalysts containing vanadium pentoxide and zirconium dioxide
US4007136A (en)	1977-02-08	Supported catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride
CA1057764A (fr)	1979-07-03	Catalyseur sur support pour l'oxydation de l'o-xylene ou du naphtalene en anhydride phtalique
US4076731A (en)	1978-02-28	Process for preparing phthalic anhydride
US3898249A (en)	1975-08-05	Process for making phthalic anhydride
US4469878A (en)	1984-09-04	Method for manufacture of phthalic anhydride
KR870000919B1 (ko)	1987-05-07	무수 프탈산의 제조방법
CA1267654A (fr)	1990-04-10	Catalyseurs pour la preparation d'anhydrides aromatiques carboxyliques
US4791092A (en)	1988-12-13	Aromatic carboxylic anhydride catalyst
US4814317A (en)	1989-03-21	Process for preparing catalysts for preparation of aromatic carboxylic anhydrides
US4931572A (en)	1990-06-05	Aromatic carboxylic anhydride catalyst
US3005831A (en)	1961-10-24	Preparation of maleic anhydrides and catalysts thereof
US5185309A (en)	1993-02-09	Fluid catalyst for use in gas phase oxidation of aromatic hydrocarbons