CA1058026A - Methode de modification de la surface de substrats inorganiques - Google Patents

Methode de modification de la surface de substrats inorganiques

Info

Publication number: CA1058026A
Authority: CA; Canada
Prior art keywords: substrate; radicals; inorganic; omega; alkoxy
Prior art date: 1971-12-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA226,819A

Other languages

English (en)

Other versions

CA226819S (en

Inventor

Richard N. Lewis

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Stauffer Chemical Co

Original Assignee

Stauffer Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1971-12-30

Filing date

1975-05-13

Publication date

1979-07-10

1971-12-30 Priority claimed from US00214406A external-priority patent/US3799962A/en

1975-05-13 Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co

1975-05-13 Priority to CA226,819A priority Critical patent/CA1058026A/fr

1979-07-10 Application granted granted Critical

1979-07-10 Publication of CA1058026A publication Critical patent/CA1058026A/fr

Status Expired legal-status Critical Current

Links

239000000758 substrate Substances 0.000 title claims abstract description 31
238000000034 method Methods 0.000 title claims abstract description 17
230000002209 hydrophobic effect Effects 0.000 claims abstract description 9
238000010438 heat treatment Methods 0.000 claims abstract description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
125000004432 carbon atom Chemical group C* 0.000 claims description 16
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
239000012744 reinforcing agent Substances 0.000 claims description 13
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
239000000945 filler Substances 0.000 claims description 9
239000000377 silicon dioxide Substances 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 5
239000003365 glass fiber Substances 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
150000003333 secondary alcohols Chemical class 0.000 claims description 5
229920002554 vinyl polymer Polymers 0.000 claims description 5
AHAMNKUVRCQJKN-UHFFFAOYSA-N hydroxy-[[[[methoxy(dimethyl)silyl]oxy-dimethylsilyl]oxy-dimethylsilyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound CO[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O AHAMNKUVRCQJKN-UHFFFAOYSA-N 0.000 claims description 4
RMYXPNWLMKQIBG-UHFFFAOYSA-N hydroxy-[[[methoxy(dimethyl)silyl]oxy-dimethylsilyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound CO[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O RMYXPNWLMKQIBG-UHFFFAOYSA-N 0.000 claims description 4
125000000075 primary alcohol group Chemical group 0.000 claims description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
229910052710 silicon Inorganic materials 0.000 claims 1
239000010703 silicon Substances 0.000 claims 1
-1 hydrocarbon radicals Chemical group 0.000 description 40
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 34
238000006243 chemical reaction Methods 0.000 description 17
235000019441 ethanol Nutrition 0.000 description 12
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 12
239000002253 acid Substances 0.000 description 11
239000006227 byproduct Substances 0.000 description 11
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
150000003254 radicals Chemical class 0.000 description 9
239000003054 catalyst Substances 0.000 description 8
125000004122 cyclic group Chemical group 0.000 description 8
230000014759 maintenance of location Effects 0.000 description 8
238000010992 reflux Methods 0.000 description 8
229920001296 polysiloxane Polymers 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 6
150000007513 acids Chemical class 0.000 description 6
235000019253 formic acid Nutrition 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
BVTLTBONLZSBJC-UHFFFAOYSA-N 2,4,6-tris(ethenyl)-2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O1 BVTLTBONLZSBJC-UHFFFAOYSA-N 0.000 description 3
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
238000004821 distillation Methods 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
239000000806 elastomer Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000004817 gas chromatography Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
239000000047 product Substances 0.000 description 3
230000002940 repellent Effects 0.000 description 3
239000005871 repellent Substances 0.000 description 3
RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical class NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
239000003377 acid catalyst Substances 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
238000003776 cleavage reaction Methods 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000007906 compression Methods 0.000 description 2
MLIREBYILWEBDM-UHFFFAOYSA-N cyanoacetic acid Chemical compound OC(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-N 0.000 description 2
125000000753 cycloalkyl group Chemical group 0.000 description 2
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
229910021485 fumed silica Inorganic materials 0.000 description 2
HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
230000003014 reinforcing effect Effects 0.000 description 2
230000007017 scission Effects 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
VCYDUTCMKSROID-UHFFFAOYSA-N 2,2,4,4,6,6-hexakis-phenyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VCYDUTCMKSROID-UHFFFAOYSA-N 0.000 description 1
VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 description 1
DGLJYEKNUTVPAE-UHFFFAOYSA-N 2,4,6-triethyl-2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound CC[Si]1(C)O[Si](C)(CC)O[Si](C)(CC)O1 DGLJYEKNUTVPAE-UHFFFAOYSA-N 0.000 description 1
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical class COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
LTIUDPOSFOYSKA-UHFFFAOYSA-N 2-ethenyl-2,4,4,6,6,8,8-heptamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C=C)O[Si](C)(C)O1 LTIUDPOSFOYSKA-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
LRHPLDYGYMQRHN-UHFFFAOYSA-N Butanol Natural products CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
VIMNUZXJJNZCEB-UHFFFAOYSA-N CO[Si](O[SiH3])(O[SiH3])OC Chemical compound CO[Si](O[SiH3])(O[SiH3])OC VIMNUZXJJNZCEB-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
230000008901 benefit Effects 0.000 description 1
235000019445 benzyl alcohol Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
230000008859 change Effects 0.000 description 1
HAURRGANAANPSQ-UHFFFAOYSA-N cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 HAURRGANAANPSQ-UHFFFAOYSA-N 0.000 description 1
239000007822 coupling agent Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000004205 dimethyl polysiloxane Substances 0.000 description 1
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
CGEQRKYERCWXQH-UHFFFAOYSA-N dimethylsilyloxy-[[hydroxy(dimethyl)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound C[SiH](C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O CGEQRKYERCWXQH-UHFFFAOYSA-N 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
238000011067 equilibration Methods 0.000 description 1
SIXBFAOZWQBKJE-UHFFFAOYSA-N ethenyl-(ethenyl-hydroxy-methylsilyl)oxy-methoxy-methylsilane Chemical compound CO[Si](C)(C=C)O[Si](C)(O)C=C SIXBFAOZWQBKJE-UHFFFAOYSA-N 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
LJWHIRABJHRRDD-UHFFFAOYSA-N hydroxy-[[methoxy(dimethyl)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound CO[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O LJWHIRABJHRRDD-UHFFFAOYSA-N 0.000 description 1
IDJGJJASJJSSEM-UHFFFAOYSA-N hydroxy-[methoxy(dimethyl)silyl]oxy-dimethylsilane Chemical compound CO[Si](C)(C)O[Si](C)(C)O IDJGJJASJJSSEM-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
229940035429 isobutyl alcohol Drugs 0.000 description 1
KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000008569 process Effects 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000000746 purification Methods 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
230000036647 reaction Effects 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA226,819A 1971-12-30 1975-05-13 Methode de modification de la surface de substrats inorganiques Expired CA1058026A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA226,819A CA1058026A (fr)	1971-12-30	1975-05-13	Methode de modification de la surface de substrats inorganiques

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US00214406A US3799962A (en)	1971-12-30	1971-12-30	Alkoxysiloxanols
CA159,897A CA997363A (en)	1971-12-30	1972-12-27	Alkoxysiloxanols
CA226,819A CA1058026A (fr)	1971-12-30	1975-05-13	Methode de modification de la surface de substrats inorganiques

Publications (1)

Publication Number	Publication Date
CA1058026A true CA1058026A (fr)	1979-07-10

Family

ID=27162505

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA226,819A Expired CA1058026A (fr)	1971-12-30	1975-05-13	Methode de modification de la surface de substrats inorganiques

Country Status (1)

Country	Link
CA (1)	CA1058026A (fr)

1975
- 1975-05-13 CA CA226,819A patent/CA1058026A/fr not_active Expired

Publication	Publication Date	Title
US3979546A (en)	1976-09-07	Alkoxysiloxanol modified surfaces
US5282998A (en)	1994-02-01	Mixtures of linear and cyclic siloxanes or siloxane oligomers and a process for their preparation
US4529752A (en)	1985-07-16	Solvent resistant vulcanizable silicone rubber composition
EP0711776B1 (fr)	2000-05-24	Alkyl hydrido siloxanes
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US5330836A (en)	1994-07-19	Functionalized silica particle and use thereof for cross-linking silicones
EP0179598B1 (fr)	1990-07-11	Compositions de polyorganosiloxane
US4395563A (en)	1983-07-26	Hydrolysis of alkoxysilanes
US3088964A (en)	1963-05-07	2-phenylpropyl organosiloxanes
KR910004530B1 (ko)	1991-07-05	불소화 오가노실록산 공중합체의 제조방법
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US4111973A (en)	1978-09-05	Process for producing a cyclotrisiloxane in a cracking reaction
US4536265A (en)	1985-08-20	Siloxane polyphotoinitiators of the substituted acetophenone type
AU603256B2 (en)	1990-11-08	Polyalkoxysilylalkylenedisilazanes and silylamines
US3799962A (en)	1974-03-26	Alkoxysiloxanols
JPS5928580B2 (ja)	1984-07-13	線状ポリシロキサンの製法
US5576408A (en)	1996-11-19	Process for preparing low molecular weight organosiloxane terminated with silanol group
US5783609A (en)	1998-07-21	Process for recovering organoalkoxysilane from polyorganosiloxane
US4113690A (en)	1978-09-12	Silicone elastomers containing alkoxysiloxanols
CA1058026A (fr)	1979-07-10	Methode de modification de la surface de substrats inorganiques
US3818064A (en)	1974-06-18	Low temperature fluorosilicone compositions
USRE29211E (en)	1977-05-10	Alkoxysiloxanols
US4737563A (en)	1988-04-12	Method for the preparation of an ω,ω-dihydroorganopolysiloxane
US4348532A (en)	1982-09-07	Monoorganosiloxy containing siloxane fluids