CA1063055A - Dessoufrage d'hydrocarbures de petrole - Google Patents

Dessoufrage d'hydrocarbures de petrole

Info

Publication number: CA1063055A
Authority: CA; Canada
Prior art keywords: weight; calculated; cobalt; catalyst; molybdenum
Prior art date: 1975-06-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA253,936A

Other languages

English (en)

Inventor

Porter Clements

Michael R. Basila

Gerald R. Feistel

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ChampionX LLC

Original Assignee

Nalco Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-06-27

Filing date

1976-06-02

Publication date

1979-09-25

1976-06-02 Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co

1979-09-25 Application granted granted Critical

1979-09-25 Publication of CA1063055A publication Critical patent/CA1063055A/fr

Status Expired legal-status Critical Current

Links

239000003208 petroleum Substances 0.000 title claims abstract description 13
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 8
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 8
238000006477 desulfuration reaction Methods 0.000 title description 5
230000023556 desulfurization Effects 0.000 title description 5
239000003054 catalyst Substances 0.000 claims abstract description 46
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 19
229910052717 sulfur Inorganic materials 0.000 claims abstract description 19
239000011593 sulfur Substances 0.000 claims abstract description 19
238000005984 hydrogenation reaction Methods 0.000 claims abstract description 7
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 38
238000000034 method Methods 0.000 claims description 19
229910052739 hydrogen Inorganic materials 0.000 claims description 16
239000001257 hydrogen Substances 0.000 claims description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
229910052698 phosphorus Inorganic materials 0.000 claims description 13
239000011574 phosphorus Substances 0.000 claims description 13
239000010941 cobalt Substances 0.000 claims description 12
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
229910017052 cobalt Inorganic materials 0.000 claims description 11
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
229910052750 molybdenum Inorganic materials 0.000 claims description 9
239000011733 molybdenum Substances 0.000 claims description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
238000009835 boiling Methods 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
229910052759 nickel Inorganic materials 0.000 claims description 4
239000003209 petroleum derivative Substances 0.000 claims description 3
229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
229910044991 metal oxide Inorganic materials 0.000 claims description 2
229910000480 nickel oxide Inorganic materials 0.000 claims description 2
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
229960005349 sulfur Drugs 0.000 claims 4
235000001508 sulfur Nutrition 0.000 claims 4
150000004706 metal oxides Chemical class 0.000 claims 1
AXFKVYBBROZOGA-UHFFFAOYSA-N [P].[Mo].[Co] Chemical compound [P].[Mo].[Co] AXFKVYBBROZOGA-UHFFFAOYSA-N 0.000 abstract description 4
CKQGJVKHBSPKST-UHFFFAOYSA-N [Ni].P#[Mo] Chemical compound [Ni].P#[Mo] CKQGJVKHBSPKST-UHFFFAOYSA-N 0.000 abstract description 2
WYWPWLUDBKATGV-UHFFFAOYSA-N [P].[Mo].[Ni].[Co] Chemical compound [P].[Mo].[Ni].[Co] WYWPWLUDBKATGV-UHFFFAOYSA-N 0.000 abstract description 2
239000004215 Carbon black (E152) Substances 0.000 abstract 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 15
239000003921 oil Substances 0.000 description 9
235000014786 phosphorus Nutrition 0.000 description 9
239000011148 porous material Substances 0.000 description 9
230000000694 effects Effects 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
239000007789 gas Substances 0.000 description 6
150000002739 metals Chemical class 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
230000003009 desulfurizing effect Effects 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 3
239000000969 carrier Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
208000036366 Sensation of pressure Diseases 0.000 description 2
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
229910000001 cobalt(II) carbonate Inorganic materials 0.000 description 2
230000005484 gravity Effects 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
239000006187 pill Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
241000282326 Felis catus Species 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
229910001981 cobalt nitrate Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
239000002131 composite material Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
239000000727 fraction Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
-1 hydrogen - Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
DWAHIRJDCNGEDV-UHFFFAOYSA-N nickel(2+);dinitrate;hydrate Chemical compound O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DWAHIRJDCNGEDV-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA253,936A 1975-06-27 1976-06-02 Dessoufrage d'hydrocarbures de petrole Expired CA1063055A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US59095875A	1975-06-27	1975-06-27

Publications (1)

Publication Number	Publication Date
CA1063055A true CA1063055A (fr)	1979-09-25

Family

ID=24364435

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA253,936A Expired CA1063055A (fr)	1975-06-27	1976-06-02	Dessoufrage d'hydrocarbures de petrole

Country Status (6)

Country	Link
JP (1)	JPS525807A (fr)
CA (1)	CA1063055A (fr)
DE (1)	DE2628531A1 (fr)
FR (1)	FR2315533A1 (fr)
GB (1)	GB1514671A (fr)
IT (1)	IT1069975B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2904242B1 (fr) *	2006-07-28	2012-09-28	Inst Francais Du Petrole	Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib
EP3870680B1 (fr)	2018-10-22	2024-12-04	TotalEnergies OneTech	Désulfuration profonde d'une charge d'alimentation à faible teneur en soufre
CN109529899A (zh) *	2018-12-04	2019-03-29	宁波中科远东催化工程技术有限公司	重油加氢复合催化剂及其制备方法和使用方法

1976
- 1976-06-02 CA CA253,936A patent/CA1063055A/fr not_active Expired
- 1976-06-04 GB GB2324376A patent/GB1514671A/en not_active Expired
- 1976-06-18 FR FR7618714A patent/FR2315533A1/fr active Granted
- 1976-06-22 IT IT5006576A patent/IT1069975B/it active
- 1976-06-24 DE DE19762628531 patent/DE2628531A1/de active Pending
- 1976-06-25 JP JP51075404A patent/JPS525807A/ja active Granted

Also Published As

Publication number	Publication date
IT1069975B (it)	1985-03-25
JPS5348206B2 (fr)	1978-12-27
DE2628531A1 (de)	1976-12-30
FR2315533A1 (fr)	1977-01-21
GB1514671A (en)	1978-06-21
JPS525807A (en)	1977-01-17
FR2315533B1 (fr)	1981-09-11

Publication	Publication Date	Title
US4568449A (en)	1986-02-04	Hydrotreating catalyst and process
US4255282A (en)	1981-03-10	Hydrotreating catalyst and process for its preparation
US6037300A (en)	2000-03-14	Catalyst containing boron and silicon and its use for hydrotreating hydrocarbon feeds
US4886594A (en)	1989-12-12	Hydrotreating catalyst and process
US3114701A (en)	1963-12-17	Catalytic hydrodenitrification process
US6531054B1 (en)	2003-03-11	Process for effecting deep HDS of hydrocarbon feedstocks
US4652545A (en)	1987-03-24	Catalyst for hydroconversion of heavy oils and method of making the catalyst
US4513097A (en)	1985-04-23	Hydrotreating catalyst and a method for preparing the catalyst
US5370788A (en)	1994-12-06	Wax conversion process
CA1129839A (fr)	1982-08-17	Traitement a l'hydrogene d'un courant d'hydrocarbure pour eliminer l'azote et le soufre
CA1253839A (fr)	1989-05-09	Catalyseur de fractionnement a activite amelioree
US4568450A (en)	1986-02-04	Hydrocarbon conversion process
US4540483A (en)	1985-09-10	Hydrotreating process
CA1248513A (fr)	1989-01-10	Hydrocarbures residuels: elimination des metaux et desulfuration
EP0310165B1 (fr)	1991-05-08	Procédé d'hydrocraquage de matière première contenant des hydrocarbures
US4446248A (en)	1984-05-01	Hydrotreating catalyst
US3425934A (en)	1969-02-04	Catalytic refining with hydrogen
CA1063055A (fr)	1979-09-25	Dessoufrage d'hydrocarbures de petrole
GB2073770A (en)	1981-10-21	Two-stage Catalytic Hydroprocessing of Heavy Hydrocarbon Feedstocks
CA1048952A (fr)	1979-02-20	Desulfuration des catalyseurs
EP0158997A1 (fr)	1985-10-23	Méthode pour l'hydrogénation d'huile hydrocarbure lourde
CA1272153A (fr)	1990-07-31	Methode d'hydrotraitement mono-etage
US3931048A (en)	1976-01-06	Hydrocarbon conversion catalytic composite
US5914290A (en)	1999-06-22	Distillate hydrofining catalyst and a process for the preparation of the same
US5116484A (en)	1992-05-26	Hydrodenitrification process