CA1063340A - Composes de cristal liquide nematique - Google Patents
Composes de cristal liquide nematiqueInfo
- Publication number
- CA1063340A CA1063340A CA237,622A CA237622A CA1063340A CA 1063340 A CA1063340 A CA 1063340A CA 237622 A CA237622 A CA 237622A CA 1063340 A CA1063340 A CA 1063340A
- Authority
- CA
- Canada
- Prior art keywords
- liquid crystal
- nematic
- constituent
- biphenyl
- nematic liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 117
- 239000004988 Nematic liquid crystal Substances 0.000 title claims abstract description 50
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 88
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000000463 material Substances 0.000 claims abstract description 55
- 239000000470 constituent Substances 0.000 claims abstract description 51
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 45
- 239000004305 biphenyl Substances 0.000 claims abstract description 35
- 230000005669 field effect Effects 0.000 claims abstract description 7
- WLPATYNQCGVFFH-UHFFFAOYSA-N 2-phenylbenzonitrile Chemical group N#CC1=CC=CC=C1C1=CC=CC=C1 WLPATYNQCGVFFH-UHFFFAOYSA-N 0.000 claims description 17
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 14
- 150000004074 biphenyls Chemical class 0.000 claims description 13
- HHPCNRKYVYWYAU-UHFFFAOYSA-N 4-cyano-4'-pentylbiphenyl Chemical group C1=CC(CCCCC)=CC=C1C1=CC=C(C#N)C=C1 HHPCNRKYVYWYAU-UHFFFAOYSA-N 0.000 claims description 11
- 239000002262 Schiff base Substances 0.000 claims description 11
- 150000004753 Schiff bases Chemical class 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 7
- ZGOWXOZNUNZPAV-UHFFFAOYSA-N 4-(4-heptylphenyl)benzonitrile Chemical group C1=CC(CCCCCCC)=CC=C1C1=CC=C(C#N)C=C1 ZGOWXOZNUNZPAV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003989 dielectric material Substances 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 abstract description 20
- 239000004990 Smectic liquid crystal Substances 0.000 abstract description 17
- 230000004044 response Effects 0.000 abstract description 17
- -1 when mixed together Chemical compound 0.000 abstract description 8
- 230000000996 additive effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 description 28
- 239000013078 crystal Substances 0.000 description 26
- 239000012071 phase Substances 0.000 description 21
- 239000007788 liquid Substances 0.000 description 20
- 150000002148 esters Chemical class 0.000 description 19
- 125000003545 alkoxy group Chemical group 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 8
- 239000002585 base Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 6
- 125000004093 cyano group Chemical group *C#N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 150000001916 cyano esters Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000000153 supplemental effect Effects 0.000 description 3
- UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 210000000707 wrist Anatomy 0.000 description 2
- WCJUJMPIFZMWOZ-UHFFFAOYSA-N 1-pentyl-4-phenylcyclohexa-2,4-diene-1-carbonitrile Chemical group C1=CC(CCCCC)(C#N)CC=C1C1=CC=CC=C1 WCJUJMPIFZMWOZ-UHFFFAOYSA-N 0.000 description 1
- QXTDWCATDIBLAL-UHFFFAOYSA-N 2-(4-pentylphenyl)benzonitrile Chemical group C1=CC(CCCCC)=CC=C1C1=CC=CC=C1C#N QXTDWCATDIBLAL-UHFFFAOYSA-N 0.000 description 1
- SLCDMYPZGHPEPA-UHFFFAOYSA-N 3-pentyl-4-phenylbenzonitrile Chemical compound CCCCCC1=CC(C#N)=CC=C1C1=CC=CC=C1 SLCDMYPZGHPEPA-UHFFFAOYSA-N 0.000 description 1
- JFKUBRAOUZEZSL-UHFFFAOYSA-N 4-butylbenzoic acid Chemical compound CCCCC1=CC=C(C(O)=O)C=C1 JFKUBRAOUZEZSL-UHFFFAOYSA-N 0.000 description 1
- YWLXLRUDGLRYDR-ZHPRIASZSA-N 5beta,20-epoxy-1,7beta,10beta,13alpha-tetrahydroxy-9-oxotax-11-ene-2alpha,4alpha-diyl 4-acetate 2-benzoate Chemical compound O([C@H]1[C@H]2[C@@](C([C@H](O)C3=C(C)[C@@H](O)C[C@]1(O)C3(C)C)=O)(C)[C@@H](O)C[C@H]1OC[C@]12OC(=O)C)C(=O)C1=CC=CC=C1 YWLXLRUDGLRYDR-ZHPRIASZSA-N 0.000 description 1
- 101150052147 ALLC gene Proteins 0.000 description 1
- 102000007469 Actins Human genes 0.000 description 1
- 108010085238 Actins Proteins 0.000 description 1
- 241001253177 Anisotes Species 0.000 description 1
- 241001432959 Chernes Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 1
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101100400378 Mus musculus Marveld2 gene Proteins 0.000 description 1
- 101100238304 Mus musculus Morc1 gene Proteins 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- QZZCYIDXEBCTEJ-UHFFFAOYSA-N benzoyl 4-pentylbenzenecarboperoxoate Chemical compound C1=CC(CCCCC)=CC=C1C(=O)OOC(=O)C1=CC=CC=C1 QZZCYIDXEBCTEJ-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- AMCLOFNPEVPAGQ-UHFFFAOYSA-N phenyl 4-hexylbenzoate Chemical compound C1=CC(CCCCCC)=CC=C1C(=O)OC1=CC=CC=C1 AMCLOFNPEVPAGQ-UHFFFAOYSA-N 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HJHVQCXHVMGZNC-JCJNLNMISA-M sodium;(2z)-2-[(3r,4s,5s,8s,9s,10s,11r,13r,14s,16s)-16-acetyloxy-3,11-dihydroxy-4,8,10,14-tetramethyl-2,3,4,5,6,7,9,11,12,13,15,16-dodecahydro-1h-cyclopenta[a]phenanthren-17-ylidene]-6-methylhept-5-enoate Chemical compound [Na+].O[C@@H]([C@@H]12)C[C@H]3\C(=C(/CCC=C(C)C)C([O-])=O)[C@@H](OC(C)=O)C[C@]3(C)[C@@]2(C)CC[C@@H]2[C@]1(C)CC[C@@H](O)[C@H]2C HJHVQCXHVMGZNC-JCJNLNMISA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Liquid Crystal Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/581,009 US4083797A (en) | 1974-09-03 | 1975-05-27 | Nematic liquid crystal compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1063340A true CA1063340A (fr) | 1979-10-02 |
Family
ID=24323527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA237,622A Expired CA1063340A (fr) | 1975-05-27 | 1975-10-15 | Composes de cristal liquide nematique |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1063340A (fr) |
-
1975
- 1975-10-15 CA CA237,622A patent/CA1063340A/fr not_active Expired
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