CA1065208A - Methode de fabrication de lentilles resistant a l'abrasion - Google Patents

Methode de fabrication de lentilles resistant a l'abrasion

Info

Publication number: CA1065208A
Authority: CA; Canada
Prior art keywords: coating; lens; allyl diglycol; diglycol carbonate; hydrolyzed
Prior art date: 1976-04-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA250,226A

Other languages

English (en)

Inventor

Albert R. Leboeuf

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

American Optical Corp

Original Assignee

American Optical Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-04-13

Filing date

1976-04-13

Publication date

1979-10-30

1976-04-13 Application filed by American Optical Corp filed Critical American Optical Corp

1976-04-13 Priority to CA250,226A priority Critical patent/CA1065208A/fr

1979-10-30 Application granted granted Critical

1979-10-30 Publication of CA1065208A publication Critical patent/CA1065208A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 19
238000005299 abrasion Methods 0.000 title abstract description 21
230000003287 optical effect Effects 0.000 title abstract description 5
238000004519 manufacturing process Methods 0.000 title abstract description 4
238000000576 coating method Methods 0.000 claims abstract description 46
239000011248 coating agent Substances 0.000 claims abstract description 43
229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 26
239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 24
NNWNNQTUZYVQRK-UHFFFAOYSA-N 5-bromo-1h-pyrrolo[2,3-c]pyridine-2-carboxylic acid Chemical compound BrC1=NC=C2NC(C(=O)O)=CC2=C1 NNWNNQTUZYVQRK-UHFFFAOYSA-N 0.000 claims abstract description 21
229920002574 CR-39 Polymers 0.000 claims abstract description 21
150000002148 esters Chemical class 0.000 claims abstract description 17
239000002253 acid Substances 0.000 claims abstract description 11
229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 4
239000011118 polyvinyl acetate Substances 0.000 claims abstract description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
229910052710 silicon Inorganic materials 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 3
238000001035 drying Methods 0.000 claims description 3
235000012239 silicon dioxide Nutrition 0.000 claims description 3
239000003039 volatile agent Substances 0.000 claims description 3
238000007598 dipping method Methods 0.000 claims description 2
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
239000008199 coating composition Substances 0.000 claims 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
238000004528 spin coating Methods 0.000 claims 1
239000000243 solution Substances 0.000 description 19
229920000642 polymer Polymers 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 6
238000012360 testing method Methods 0.000 description 5
JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
239000003513 alkali Substances 0.000 description 4
229940102838 methylmethacrylate Drugs 0.000 description 4
238000009987 spinning Methods 0.000 description 4
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
238000013019 agitation Methods 0.000 description 3
239000002585 base Substances 0.000 description 3
238000009833 condensation Methods 0.000 description 3
230000005494 condensation Effects 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
239000000463 material Substances 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000005266 casting Methods 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
239000005331 crown glasses (windows) Substances 0.000 description 2
125000004185 ester group Chemical group 0.000 description 2
-1 ethyl silicate Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
239000000203 mixture Substances 0.000 description 2
229920000307 polymer substrate Polymers 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
239000000080 wetting agent Substances 0.000 description 2
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
229920004890 Triton X-100 Polymers 0.000 description 1
229920001807 Urea-formaldehyde Polymers 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
239000003518 caustics Substances 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
229910001651 emery Inorganic materials 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000033444 hydroxylation Effects 0.000 description 1
238000005805 hydroxylation reaction Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229960004592 isopropanol Drugs 0.000 description 1
239000011368 organic material Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Landscapes

Surface Treatment Of Optical Elements (AREA)

CA250,226A 1976-04-13 1976-04-13 Methode de fabrication de lentilles resistant a l'abrasion Expired CA1065208A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA250,226A CA1065208A (fr)	1976-04-13	1976-04-13	Methode de fabrication de lentilles resistant a l'abrasion

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA250,226A CA1065208A (fr)	1976-04-13	1976-04-13	Methode de fabrication de lentilles resistant a l'abrasion

Publications (1)

Publication Number	Publication Date
CA1065208A true CA1065208A (fr)	1979-10-30

Family

ID=4105712

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA250,226A Expired CA1065208A (fr)	1976-04-13	1976-04-13	Methode de fabrication de lentilles resistant a l'abrasion

Country Status (1)

Country	Link
CA (1)	CA1065208A (fr)

1976
- 1976-04-13 CA CA250,226A patent/CA1065208A/fr not_active Expired

Publication	Publication Date	Title
US3971872A (en)	1976-07-27	Process for the production of an abrasion resistant optical element
US4127697A (en)	1978-11-28	Abrasion-resistant lenses and process of making
CA1293655C (fr)	1991-12-31	Article optique antireflechissement, et sa preparation
JP3186768B2 (ja)	2001-07-11	疎水性および耐摩耗性を有する反射防止材および基材上に反射防止性、疎水性、耐摩耗性被覆を付着させる方法
US4127682A (en)	1978-11-28	Abrasion and antifog-resistant optical element
AU750507B2 (en)	2002-07-18	Coating composition and method for preparing the same, and scuff-resistant plastic lense
JP5686728B2 (ja)	2015-03-18	コーティング組成物
JPH0218048A (ja)	1990-01-22	防曇性被膜
US4120992A (en)	1978-10-17	Abrasion-resistant optical element
US4229228A (en)	1980-10-21	Coating composition
JPH0455615B2 (fr)	1992-09-03
US4783347A (en)	1988-11-08	Method for primerless coating of plastics
CA1065208A (fr)	1979-10-30	Methode de fabrication de lentilles resistant a l'abrasion
CA1105784A (fr)	1981-07-28	Traduction non-disponible
US4401718A (en)	1983-08-30	Process for applying a second silicone resin coating composition over a first silicone resin coating composition
CN111542575B (zh)	2022-12-23	涂覆组合物和具有硬涂膜的光学物品
JPH03172369A (ja)	1991-07-25	硬化膜およびその硬化膜を有する光学部材
JPS6011727B2 (ja)	1985-03-27	硬化性樹脂組成物
JPH0137268B2 (fr)	1989-08-04
EP0922501A1 (fr)	1999-06-16	Procede permettant d'eliminer des revetements durs de lentilles en plastique
US4413025A (en)	1983-11-01	Coating composition for polycarbonate moldings containing partially hydrolyzed alkyltrialkoxysilane and polyvinylbutyral
JPS5931450B2 (ja)	1984-08-02	摩耗抵抗性レンズの製法
JPS62247302A (ja)	1987-10-28	光学物品の製造方法
JPH11109105A (ja)	1999-04-23	防曇反射防止光学物品
JPS6327565A (ja)	1988-02-05	コ−テイング組成物