CA1067144A - Electrolytes solides conducteurs d'anions et batteries a semiconducteur - Google Patents

Electrolytes solides conducteurs d'anions et batteries a semiconducteur

Info

Publication number: CA1067144A
Authority: CA; Canada
Prior art keywords: pbf2; electrochemical cell; alkali metal; electrolyte; solid
Prior art date: 1975-06-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA252,219A

Other languages

English (en)

Inventor

Charles C. Liang

Ashok V. Joshi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Duracell Inc USA

Original Assignee

PR Mallory and Co Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-06-11

Filing date

1976-05-11

Publication date

1979-11-27

1976-05-11 Application filed by PR Mallory and Co Inc filed Critical PR Mallory and Co Inc

1979-11-27 Application granted granted Critical

1979-11-27 Publication of CA1067144A publication Critical patent/CA1067144A/fr

Status Expired legal-status Critical Current

Links

239000007784 solid electrolyte Substances 0.000 title claims abstract description 36
239000007787 solid Substances 0.000 title description 10
150000001450 anions Chemical class 0.000 title 1
FPHIOHCCQGUGKU-UHFFFAOYSA-L difluorolead Chemical compound F[Pb]F FPHIOHCCQGUGKU-UHFFFAOYSA-L 0.000 claims abstract description 41
229910001508 alkali metal halide Inorganic materials 0.000 claims abstract description 18
150000008045 alkali metal halides Chemical class 0.000 claims abstract description 15
239000000203 mixture Substances 0.000 claims description 22
239000003792 electrolyte Substances 0.000 claims description 20
150000004820 halides Chemical class 0.000 claims description 7
YAFKGUAJYKXPDI-UHFFFAOYSA-J lead tetrafluoride Chemical compound F[Pb](F)(F)F YAFKGUAJYKXPDI-UHFFFAOYSA-J 0.000 claims description 6
229910052731 fluorine Inorganic materials 0.000 claims description 5
239000011737 fluorine Substances 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000006182 cathode active material Substances 0.000 claims description 4
150000002222 fluorine compounds Chemical class 0.000 claims description 4
KWVVTSALYXIJSS-UHFFFAOYSA-L silver(ii) fluoride Chemical compound [F-].[F-].[Ag+2] KWVVTSALYXIJSS-UHFFFAOYSA-L 0.000 claims description 4
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims description 3
229910052744 lithium Inorganic materials 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
229910052708 sodium Inorganic materials 0.000 claims description 3
229910021630 Antimony pentafluoride Inorganic materials 0.000 claims description 2
229910021594 Copper(II) fluoride Inorganic materials 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 claims description 2
GWFAVIIMQDUCRA-UHFFFAOYSA-L copper(ii) fluoride Chemical compound [F-].[F-].[Cu+2] GWFAVIIMQDUCRA-UHFFFAOYSA-L 0.000 claims description 2
229910001385 heavy metal Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 claims description 2
239000006104 solid solution Substances 0.000 claims description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
239000006183 anode active material Substances 0.000 claims 1
FMSYTQMJOCCCQS-UHFFFAOYSA-L difluoromercury Chemical compound F[Hg]F FMSYTQMJOCCCQS-UHFFFAOYSA-L 0.000 claims 1
239000008247 solid mixture Substances 0.000 claims 1
239000002019 doping agent Substances 0.000 abstract description 7
238000000034 method Methods 0.000 abstract description 7
239000000126 substance Substances 0.000 abstract description 3
239000011698 potassium fluoride Substances 0.000 description 30
239000008188 pellet Substances 0.000 description 11
229910001515 alkali metal fluoride Inorganic materials 0.000 description 5
239000000463 material Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
238000010348 incorporation Methods 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
238000003825 pressing Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
229910052789 astatine Inorganic materials 0.000 description 1
RYXHOMYVWAEKHL-UHFFFAOYSA-N astatine atom Chemical compound [At] RYXHOMYVWAEKHL-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
ZASWJUOMEGBQCQ-UHFFFAOYSA-L dibromolead Chemical class Br[Pb]Br ZASWJUOMEGBQCQ-UHFFFAOYSA-L 0.000 description 1
-1 fluoride ions Chemical class 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
RQQRAHKHDFPBMC-UHFFFAOYSA-L lead(ii) iodide Chemical compound I[Pb]I RQQRAHKHDFPBMC-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
235000003270 potassium fluoride Nutrition 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
230000001131 transforming effect Effects 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/182—Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Physics & Mathematics (AREA)
Condensed Matter Physics & Semiconductors (AREA)
General Physics & Mathematics (AREA)
Inorganic Chemistry (AREA)
Conductive Materials (AREA)
Secondary Cells (AREA)
Primary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)

CA252,219A 1975-06-11 1976-05-11 Electrolytes solides conducteurs d'anions et batteries a semiconducteur Expired CA1067144A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US58594975A	1975-06-11	1975-06-11

Publications (1)

Publication Number	Publication Date
CA1067144A true CA1067144A (fr)	1979-11-27

Family

ID=24343671

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA252,219A Expired CA1067144A (fr)	1975-06-11	1976-05-11	Electrolytes solides conducteurs d'anions et batteries a semiconducteur

Country Status (12)

Country	Link
JP (1)	JPS5231332A (fr)
AU (1)	AU496776B2 (fr)
BE (1)	BE842829A (fr)
CA (1)	CA1067144A (fr)
DE (1)	DE2624941A1 (fr)
DK (1)	DK257376A (fr)
FR (1)	FR2314589A1 (fr)
GB (1)	GB1524126A (fr)
IL (1)	IL49482A (fr)
IT (1)	IT1064028B (fr)
NL (1)	NL7606259A (fr)
SE (1)	SE7606557L (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE31365E (en)	1978-12-27	1983-08-30	Union Carbide Corporation	Solid state electrolytes
US4186248A (en) *	1978-12-27	1980-01-29	Union Carbide Corporation	Solid state electrolytes
US4186249A (en) *	1978-12-27	1980-01-29	Union Carbide Corporation	Solid state electrolytes
RU2187178C2 (ru) *	1999-10-05	2002-08-10	Российский Федеральный Ядерный Центр - Всероссийский Научно-Исследовательский Институт Экспериментальной Физики	Твердотельный химический источник тока
RU2247628C1 (ru) *	2003-06-04	2005-03-10	ФГУП "Российский федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" - ФГУП "РФЯЦ-ВНИИЭФ"	Способ получения поликристаллической структуры ионного проводника
RU2295177C2 (ru)	2005-04-21	2007-03-10	Общество с ограниченной ответственностью "Высокоэнергетические батарейные системы" (ООО "ВЭБС")	Способ изготовления вторичного твердотельного источника тока
RU2295178C2 (ru)	2005-04-21	2007-03-10	Общество с ограниченной ответственностью "Высокоэнергетические батарейные системы" (ООО "ВЭБС")	Твердотельный вторичный источник тока
RU2313158C2 (ru) *	2006-01-10	2007-12-20	Общество С Ограниченной Ответственностью "Высокоэнергетические Батарейные Системы"	Твердотельный химический источник тока и способ повышения разрядной мощности
RU2413340C1 (ru) *	2009-08-10	2011-02-27	ООО "Высокоэнергетические Батарейные Системы" ("High Power Battery Systems Ltd.", HPBS)	Химический источник тока
DE102013106998A1 (de) *	2013-07-03	2015-01-08	Thyssenkrupp Industrial Solutions Ag	Verfahren sowie eine Vorrichtung zur Herstellung einer Tablette

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2258011A1 (fr) *	1974-01-12	1975-08-08	Varta Batterie

1976
- 1976-04-27 IL IL49482A patent/IL49482A/xx unknown
- 1976-04-30 AU AU13532/76A patent/AU496776B2/en not_active Expired
- 1976-05-11 CA CA252,219A patent/CA1067144A/fr not_active Expired
- 1976-05-24 GB GB21383/76A patent/GB1524126A/en not_active Expired
- 1976-06-03 DE DE19762624941 patent/DE2624941A1/de not_active Withdrawn
- 1976-06-10 NL NL7606259A patent/NL7606259A/xx not_active Application Discontinuation
- 1976-06-10 DK DK257376A patent/DK257376A/da unknown
- 1976-06-10 SE SE7606557A patent/SE7606557L/xx unknown
- 1976-06-10 FR FR7617607A patent/FR2314589A1/fr not_active Withdrawn
- 1976-06-10 IT IT24151/76A patent/IT1064028B/it active
- 1976-06-11 BE BE2055107A patent/BE842829A/fr unknown
- 1976-06-11 JP JP51068637A patent/JPS5231332A/ja active Pending

Also Published As

Publication number	Publication date
GB1524126A (en)	1978-09-06
DE2624941A1 (de)	1976-12-23
JPS5231332A (en)	1977-03-09
AU496776B2 (en)	1978-10-26
SE7606557L (sv)	1976-12-12
IL49482A (en)	1978-12-17
AU1353276A (en)	1977-11-03
IL49482A0 (en)	1976-06-30
NL7606259A (nl)	1976-12-14
BE842829A (fr)	1976-10-01
FR2314589A1 (fr)	1977-01-07
DK257376A (da)	1976-12-12
IT1064028B (it)	1985-02-18

Legal Events

Date	Code	Title	Description
2022-09-10	MKEX	Expiry	Effective date: 19961127

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EP3726635B1 (fr)	2022-10-19	Particules d'électrolyte solide à base de sulfure
US5599355A (en)	1997-02-04	Method for forming thin composite solid electrolyte film for lithium batteries
US4436796A (en)	1984-03-13	All-solid electrodes with mixed conductor matrix
US5360686A (en)	1994-11-01	Thin composite solid electrolyte film for lithium batteries
CA1265842A (fr)	1990-02-13	Pile au lithium utilisant un materiau actif amorphe a base d'anmydride de vanadium pour la cathode
US5051325A (en)	1991-09-24	Secondary battery
US3770506A (en)	1973-11-06	Electrical energy storage device containing a tellurium additive
US4085259A (en)	1978-04-18	Light metal galvanic element
US4717634A (en)	1988-01-05	Electric cells utilizing polyaniline as a positive electrode active material
US4687598A (en)	1987-08-18	Electrode-active material for electrochemical batteries and method of preparation
JPH07107861B2 (ja)	1995-11-15	合金化負極の製造方法
KR20230022158A (ko)	2023-02-14	고체 전해질, 전극 합제 및 전지
US4722877A (en)	1988-02-02	Long cycle life solid-state solid polymer electrolyte cells
Liang et al.	1975	Conduction characteristics of polycrystalline lead fluoride
US3713897A (en)	1973-01-30	Electrolyte materials for high voltage solid electrolyte battery systems
JPH08148180A (ja)	1996-06-07	全固体リチウム二次電池
JPS5914264A (ja)	1984-01-25	非水性媒質を用いるリチウム電池用可撓性複合アノ−ド
US6183912B1 (en)	2001-02-06	High energy glass containing carbon electrode for lithium battery
US4489143A (en)	1984-12-18	Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode
CA1184969A (fr)	1985-04-02	Pile a electrolyte solide
Shimotake et al.	1969	Secondary cells with lithium anodes and immobilized fused-salt electrolytes
Kanno et al.	1987	Rechargeable all solid-state cell with high copper ion conductor and copper chevrel phase
Schoonman et al.	1979	Fluoride‐Conducting Solid Electrolytes in Galvanic Cells
JPH07263027A (ja)	1995-10-13	非水電解液二次電池
US3567516A (en)	1971-03-02	Electrical energy storage device containing a tellurium additive