CA1067227A - Production de produits en fibres de verre - Google Patents

Production de produits en fibres de verre

Info

Publication number: CA1067227A
Authority: CA; Canada
Prior art keywords: percent; polymeric component; phenol; urea; starch
Prior art date: 1974-03-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA308,288A

Other languages

English (en)

Inventor

Harland E. Fargo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Owens Corning

Original Assignee

Owens Corning Fiberglas Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-03-18

Filing date

1978-07-27

Publication date

1979-11-27

1974-03-18 Priority claimed from US05/452,293 external-priority patent/US4014726A/en

1974-12-13 Priority claimed from CA215,947A external-priority patent/CA1067226A/fr

1978-07-27 Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp

1978-07-27 Priority to CA308,288A priority Critical patent/CA1067227A/fr

1979-11-27 Application granted granted Critical

1979-11-27 Publication of CA1067227A publication Critical patent/CA1067227A/fr

Status Expired legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title claims abstract description 37
238000004519 manufacturing process Methods 0.000 title abstract description 6
239000011230 binding agent Substances 0.000 claims abstract description 69
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 47
239000004202 carbamide Substances 0.000 claims abstract description 47
239000000203 mixture Substances 0.000 claims abstract description 43
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 40
239000000047 product Substances 0.000 claims abstract description 38
229920002472 Starch Polymers 0.000 claims abstract description 29
235000019698 starch Nutrition 0.000 claims abstract description 29
239000008107 starch Substances 0.000 claims abstract description 28
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
238000000034 method Methods 0.000 claims abstract description 16
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 12
239000000835 fiber Substances 0.000 claims abstract description 9
239000007857 degradation product Substances 0.000 claims abstract description 8
239000007787 solid Substances 0.000 claims abstract description 8
239000002253 acid Substances 0.000 claims abstract description 7
150000001875 compounds Chemical class 0.000 claims abstract description 7
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 5
150000003863 ammonium salts Chemical class 0.000 claims abstract description 5
239000000314 lubricant Substances 0.000 claims abstract description 5
239000003607 modifier Substances 0.000 claims abstract description 5
229910000077 silane Inorganic materials 0.000 claims abstract description 5
239000011521 glass Substances 0.000 claims abstract description 3
238000011065 in-situ storage Methods 0.000 claims abstract description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 59
229960004279 formaldehyde Drugs 0.000 claims description 21
235000019256 formaldehyde Nutrition 0.000 claims description 19
238000001816 cooling Methods 0.000 claims description 9
239000000376 reactant Substances 0.000 claims description 8
239000011541 reaction mixture Substances 0.000 claims description 8
239000004375 Dextrin Substances 0.000 claims description 7
235000019425 dextrin Nutrition 0.000 claims description 7
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 6
238000000354 decomposition reaction Methods 0.000 claims description 6
239000008121 dextrose Substances 0.000 claims description 6
239000011118 polyvinyl acetate Substances 0.000 claims description 6
229920002689 polyvinyl acetate Polymers 0.000 claims description 6
229920001353 Dextrin Polymers 0.000 claims description 5
229920001732 Lignosulfonate Polymers 0.000 claims description 4
239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 3
FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 claims description 2
239000004615 ingredient Substances 0.000 claims description 2
229920005610 lignin Polymers 0.000 claims description 2
239000000306 component Substances 0.000 claims 34
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
229920005989 resin Polymers 0.000 description 9
239000011347 resin Substances 0.000 description 9
238000009833 condensation Methods 0.000 description 7
230000005494 condensation Effects 0.000 description 7
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 6
229920001568 phenolic resin Polymers 0.000 description 6
QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 5
229920000881 Modified starch Polymers 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
235000019426 modified starch Nutrition 0.000 description 4
239000000243 solution Substances 0.000 description 4
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
239000000920 calcium hydroxide Substances 0.000 description 3
229910001861 calcium hydroxide Inorganic materials 0.000 description 3
235000011116 calcium hydroxide Nutrition 0.000 description 3
229940095643 calcium hydroxide Drugs 0.000 description 3
239000000498 cooling water Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000003921 oil Substances 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
239000003039 volatile agent Substances 0.000 description 3
229920001807 Urea-formaldehyde Polymers 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 2
229910001863 barium hydroxide Inorganic materials 0.000 description 2
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
229920001187 thermosetting polymer Polymers 0.000 description 2
WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
239000006087 Silane Coupling Agent Substances 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
229920003180 amino resin Polymers 0.000 description 1
239000010426 asphalt Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000010000 carbonizing Methods 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000003292 glue Substances 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
230000001473 noxious effect Effects 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000011295 pitch Substances 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Landscapes

Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)

CA308,288A 1974-03-18 1978-07-27 Production de produits en fibres de verre Expired CA1067227A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA308,288A CA1067227A (fr)	1974-03-18	1978-07-27	Production de produits en fibres de verre

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US05/452,293 US4014726A (en)	1974-03-18	1974-03-18	Production of glass fiber products
CA215,947A CA1067226A (fr)	1974-03-18	1974-12-13	Fabrication de produits en fibre de verre
CA308,288A CA1067227A (fr)	1974-03-18	1978-07-27	Production de produits en fibres de verre

Publications (1)

Publication Number	Publication Date
CA1067227A true CA1067227A (fr)	1979-11-27

Family

ID=27163746

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA308,288A Expired CA1067227A (fr)	1974-03-18	1978-07-27	Production de produits en fibres de verre

Country Status (1)

Country	Link
CA (1)	CA1067227A (fr)

1978
- 1978-07-27 CA CA308,288A patent/CA1067227A/fr not_active Expired

Publication	Publication Date	Title
US4014726A (en)	1977-03-29	Production of glass fiber products
US5719228A (en)	1998-02-17	Glass fiber binding compositions, process of making glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions
CA2068242C (fr)	2004-02-24	Methode de preparation de liant phenolique
EP0642476B1 (fr)	1996-08-14	Compositions de liaison de fibres de verre, procede de liaison de fibres de verre, et compositions de fibres de verre
US9580354B2 (en)	2017-02-28	Phenolic resin, preparation process, sizing composition for mineral fibers and resulting product
KR101478652B1 (ko)	2015-01-02	페놀 수지, 조제 방법, 광물성 섬유를 위한 사이징 조성물, 및 최종 제품
KR101479196B1 (ko)	2015-01-05	페놀 수지, 조제 방법, 광물성 섬유를 위한 사이징 조성물, 및 최종 제품
CA1118926A (fr)	1982-02-23	Liant a l'epreuve des temperatures elevees pour fibres minerales
US4904516A (en)	1990-02-27	Phenol-formaldehyde resin solution containing water soluble alkaline earth metal salt
US5270434A (en)	1993-12-14	Phenolic resin, procedure for preparation of the resin, and sizing composition for mineral fibers containing this resin
US6646094B1 (en)	2003-11-11	Low emission formaldehyde resin and binder for mineral fiber insulation
CA2034399A1 (fr)	1991-08-07	Liant pour isolant en fibres de verre
US5473012A (en)	1995-12-05	Process for preparing phenolic binder
IE912578A1 (en)	1992-04-22	Phenolic resin, process for preparing the resin and¹composition for sizing mineral fibres containing this resin
CA1067226A (fr)	1979-11-27	Fabrication de produits en fibre de verre
CA1067227A (fr)	1979-11-27	Production de produits en fibres de verre
US4235950A (en)	1980-11-25	High temperature mineral fiber binder
WO1994026677A1 (fr)	1994-11-24	Compositions emulsifiees de liaison de fibres de verre, a base de resine furannique, et procede de liaison de fibres de verre
US3876467A (en)	1975-04-08	Modification of starch
JP7559035B2 (ja)	2024-10-01	ミネラルウール製品の製造方法
SU859386A1 (ru)	1981-08-30	Способ получени фенолформальдегидного св зующего