CA1067647A - Terpolymere de type polyamide - Google Patents

Terpolymere de type polyamide

Info

Publication number: CA1067647A
Authority: CA; Canada
Prior art keywords: weight; nylon; resin; terpolyamide; segment
Prior art date: 1975-11-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA265,390A

Other languages

English (en)

Inventor

Rolando U. Pagilagan

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-11-13

Filing date

1976-11-10

Publication date

1979-12-04

1975-11-13 Priority claimed from US05/631,692 external-priority patent/US4076664A/en

1976-11-10 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1979-12-04 Application granted granted Critical

1979-12-04 Publication of CA1067647A publication Critical patent/CA1067647A/fr

Status Expired legal-status Critical Current

Links

229920001897 terpolymer Polymers 0.000 title claims description 5
239000004952 Polyamide Substances 0.000 title description 3
229920002647 polyamide Polymers 0.000 title description 3
229920005989 resin Polymers 0.000 claims abstract description 69
239000011347 resin Substances 0.000 claims abstract description 69
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
229920000642 polymer Polymers 0.000 claims description 13
238000000034 method Methods 0.000 claims description 12
238000002360 preparation method Methods 0.000 claims description 12
150000001408 amides Chemical class 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 7
239000012266 salt solution Substances 0.000 claims description 5
239000004215 Carbon black (E152) Substances 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
238000006243 chemical reaction Methods 0.000 claims description 2
238000001704 evaporation Methods 0.000 claims description 2
239000011541 reaction mixture Substances 0.000 claims 1
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract description 54
239000004677 Nylon Substances 0.000 abstract description 44
229920001778 nylon Polymers 0.000 abstract description 44
229920000572 Nylon 6/12 Polymers 0.000 abstract description 28
239000011592 zinc chloride Substances 0.000 abstract description 27
235000005074 zinc chloride Nutrition 0.000 abstract description 27
229920002302 Nylon 6,6 Polymers 0.000 abstract description 24
KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract description 10
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 7
229920000305 Nylon 6,10 Polymers 0.000 abstract description 5
150000003839 salts Chemical class 0.000 description 50
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 26
229960001939 zinc chloride Drugs 0.000 description 26
239000000243 solution Substances 0.000 description 18
239000000203 mixture Substances 0.000 description 14
239000008188 pellet Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 11
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 9
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
239000002253 acid Substances 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 6
238000000465 moulding Methods 0.000 description 6
229920006122 polyamide resin Polymers 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 5
RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 4
229910021595 Copper(I) iodide Inorganic materials 0.000 description 4
239000001361 adipic acid Substances 0.000 description 4
235000011037 adipic acid Nutrition 0.000 description 4
LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 4
229960005082 etohexadiol Drugs 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
229940083916 aluminum distearate Drugs 0.000 description 3
RDIVANOKKPKCTO-UHFFFAOYSA-K aluminum;octadecanoate;hydroxide Chemical compound [OH-].[Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O RDIVANOKKPKCTO-UHFFFAOYSA-K 0.000 description 3
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
238000007654 immersion Methods 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
239000002904 solvent Substances 0.000 description 3
XIZNSFKZKZTGNG-UHFFFAOYSA-N 2-butylbenzenesulfonamide Chemical compound CCCCC1=CC=CC=C1S(N)(=O)=O XIZNSFKZKZTGNG-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
229920002292 Nylon 6 Polymers 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000003368 amide group Chemical group 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
238000006068 polycondensation reaction Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
USQCUKQZXOWUDF-YWZLYKJASA-N 6-chloro-n-[(3s)-1-[(2s)-1-(4-methyl-5-oxo-1,4-diazepan-1-yl)-1-oxopropan-2-yl]-2-oxopyrrolidin-3-yl]naphthalene-2-sulfonamide Chemical compound O=C([C@@H](N1C([C@@H](NS(=O)(=O)C=2C=C3C=CC(Cl)=CC3=CC=2)CC1)=O)C)N1CCN(C)C(=O)CC1 USQCUKQZXOWUDF-YWZLYKJASA-N 0.000 description 1
101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
241000353097 Molva molva Species 0.000 description 1
101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
229920000571 Nylon 11 Polymers 0.000 description 1
229920000299 Nylon 12 Polymers 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
229960000583 acetic acid Drugs 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
125000004427 diamine group Chemical group 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
-1 e.g. Substances 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000006260 foam Substances 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000000178 monomer Substances 0.000 description 1
FGTVYMTUTYLLQR-UHFFFAOYSA-N n-ethyl-1-phenylmethanesulfonamide Chemical compound CCNS(=O)(=O)CC1=CC=CC=C1 FGTVYMTUTYLLQR-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
241000894007 species Species 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
229940124543 ultraviolet light absorber Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyamides (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA265,390A 1975-11-13 1976-11-10 Terpolymere de type polyamide Expired CA1067647A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US63169375A	1975-11-13	1975-11-13
US05/631,692 US4076664A (en)	1975-11-13	1975-11-13	612 OR 610/6I or 6T/636 Polyamide terpolymer

Publications (1)

Publication Number	Publication Date
CA1067647A true CA1067647A (fr)	1979-12-04

Family

ID=27091466

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA265,390A Expired CA1067647A (fr)	1975-11-13	1976-11-10	Terpolymere de type polyamide

Country Status (7)

Country	Link
JP (1)	JPS5262399A (fr)
CA (1)	CA1067647A (fr)
DE (1)	DE2651741A1 (fr)
FR (1)	FR2331583A1 (fr)
GB (1)	GB1558800A (fr)
IT (1)	IT1063996B (fr)
NL (1)	NL171278C (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57212252A (en) *	1981-06-25	1982-12-27	Ube Ind Ltd	Polyamide composition resistant to calcium chloride
JPS5853950A (ja) *	1981-09-29	1983-03-30	Toray Ind Inc	自動車用アンダ−フ−ド部品
JPS5853949A (ja) *	1981-09-29	1983-03-30	Toray Ind Inc	自動車用アンダ−フ−ド部品
JPS58120665A (ja) *	1982-01-12	1983-07-18	Toray Ind Inc	自動車用アンダ−フ−ド部品
DE3436362A1 (de) *	1984-10-04	1986-04-10	Basf Ag, 6700 Ludwigshafen	Schlagzaehe polyamid-formmassen mit verminderter spannungsrissanfaelligkeit
JP3476037B2 (ja) *	1995-04-21	2003-12-10	矢崎総業株式会社	ポリアミド樹脂組成物
US5852165A (en) *	1994-05-31	1998-12-22	Ube Industries, Ltd.	Terpolymer polyamide, polyamide resin composition containing the same, and automotive parts obtaining from these
EP0685505B1 (fr)	1994-05-31	2000-08-16	Ube Industries, Ltd.	Polyamide terpolymère, composition de résine polyamide contenant ceci et éléments de véhicule préparés à partir de ceux-ci
US7696301B2 (en) *	2004-10-27	2010-04-13	E.I. Du Pont De Nemours And Company	Marine umbilical comprising hydrolysis resistant polyamides
US20070083033A1 (en) *	2005-10-06	2007-04-12	Fish Robert B Jr	Hydrolysis resistant polyamide compositions, and articles formed therefrom
DE502008001769D1 (de) *	2008-07-11	2010-12-23	Ems Patent Ag	Copolyamid sowie Blends und Folien mit einem solchen Copolyamid
EP2406301A1 (fr) *	2009-03-11	2012-01-18	E. I. du Pont de Nemours and Company	Compositions de polyamide résistantes aux sels
EP2802615A4 (fr) *	2012-01-12	2015-08-12	Shakespeare Co Llc	Copolymères transmettant la lumière

1976
- 1976-11-10 CA CA265,390A patent/CA1067647A/fr not_active Expired
- 1976-11-10 FR FR7633919A patent/FR2331583A1/fr active Granted
- 1976-11-11 GB GB4707076A patent/GB1558800A/en not_active Expired
- 1976-11-11 JP JP13475476A patent/JPS5262399A/ja active Granted
- 1976-11-12 IT IT2932276A patent/IT1063996B/it active
- 1976-11-12 DE DE19762651741 patent/DE2651741A1/de not_active Ceased
- 1976-11-12 NL NL7612628A patent/NL171278C/xx not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPS5262399A (en)	1977-05-23
NL171278C (nl)	1983-03-01
FR2331583A1 (fr)	1977-06-10
IT1063996B (it)	1985-02-18
JPS551299B2 (fr)	1980-01-12
GB1558800A (en)	1980-01-09
DE2651741A1 (de)	1977-05-18
FR2331583B1 (fr)	1981-05-22
NL171278B (nl)	1982-10-01
NL7612628A (nl)	1977-05-17

Publication	Publication Date	Title
US4076664A (en)	1978-02-28	612 OR 610/6I or 6T/636 Polyamide terpolymer
CA1067647A (fr)	1979-12-04	Terpolymere de type polyamide
EP0070001B2 (fr)	1990-01-10	Mélanges de polyamides
CA1167996A (fr)	1984-05-22	Polyamides
US3784495A (en)	1974-01-08	Room temperature soluble melt-condensed polyamide interpolymers
KR101908121B1 (ko)	2018-10-15	폴리아마이드-이미드 필름 및 이의 제조방법
US3341492A (en)	1967-09-12	Polyamides stabilized with iodine and/or bromine substituted phenols
KR940011164B1 (ko)	1994-11-24	신규한 코폴리아미드와 그의 제조방법
CA1063293A (fr)	1979-09-25	Polyamides transparents
JPH07228689A (ja)	1995-08-29	ポリアミド樹脂
JPS62121726A (ja)	1987-06-03	透明なコポリアミドの製法
US2393972A (en)	1946-02-05	Polyamides and process for obtaining them
FI85278B (fi)	1991-12-13	Foerfarande foer framstaellning av kopolyamider, vilka baserar sig pao hexametylendiamin, adipinsyra, moejligen aotminstone en annan kortkedjig dikarboxylsyra och en dimer syra.
US4556697A (en)	1985-12-03	Alternating copolyamide prepared on a polymer matrix
JPH0234632A (ja)	1990-02-05	高いガラス転移温度を有する透明な非晶質ポリアミド
KR940011163B1 (ko)	1994-11-24	신규한 코폴리아미드와 그의 제조방법
FI80894C (fi)	1990-08-10	Tekniska kopolyeteramider, som aer boejliga i laoga temperaturer.
JPH0245528A (ja)	1990-02-15	高分子量ポリ（トルエンジアミンアラミド）及びそれらの製造方法
US3719640A (en)	1973-03-06	Poly(amide-imide)polymers having recurring diketopiperazine groups
US3511819A (en)	1970-05-12	Thermally durable aromatic copolyamides
GB1590056A (en)	1981-05-28	Transparent copolyamides
US4931533A (en)	1990-06-05	Filament-, fiber- or film-forming aromatic copolyamide from aromatic diamine mixture
US3654236A (en)	1972-04-04	Terpolyamides
US4429109A (en)	1984-01-31	Polyamides with high glass transition temperatures prepared from N,N'-terephthaloyldi-beta-alanine and a diamine
KR100580869B1 (ko)	2006-05-16	접착용 폴리아미드 공중합 수지