CA1069064A - Adsorption du monoxyde de carbone a l'aide de zeolite a l'argent - Google Patents

Adsorption du monoxyde de carbone a l'aide de zeolite a l'argent

Info

Publication number: CA1069064A
Authority: CA; Canada
Prior art keywords: gas stream; carbon monoxide; zeolite; adsorption; sio2
Prior art date: 1975-09-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA260,168A

Other languages

English (en)

Inventor

Charles L. Angell

James N. Francis

Jule A. Rabo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-09-26

Filing date

1976-08-30

Publication date

1980-01-01

1976-08-30 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1980-01-01 Application granted granted Critical

1980-01-01 Publication of CA1069064A publication Critical patent/CA1069064A/fr

Status Expired legal-status Critical Current

Links

UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 7
229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 7
229910052709 silver Inorganic materials 0.000 title claims abstract description 6
239000004332 silver Substances 0.000 title claims abstract description 6
239000010457 zeolite Substances 0.000 title abstract description 21
238000001179 sorption measurement Methods 0.000 title abstract description 6
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
239000002808 molecular sieve Substances 0.000 claims abstract description 6
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 6
-1 Ag+ cations Chemical class 0.000 claims abstract description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
229910052681 coesite Inorganic materials 0.000 claims abstract description 5
229910052906 cristobalite Inorganic materials 0.000 claims abstract description 5
239000000377 silicon dioxide Substances 0.000 claims abstract description 5
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 5
229910052682 stishovite Inorganic materials 0.000 claims abstract description 5
229910052905 tridymite Inorganic materials 0.000 claims abstract description 5
229910052593 corundum Inorganic materials 0.000 claims abstract 3
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract 3
238000000034 method Methods 0.000 claims description 24
239000003463 adsorbent Substances 0.000 claims description 9
239000000470 constituent Substances 0.000 claims description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 20
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
229910021536 Zeolite Inorganic materials 0.000 description 18
239000007789 gas Substances 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000000126 substance Substances 0.000 description 6
239000003570 air Substances 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
239000000243 solution Substances 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
241000894007 species Species 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000002156 adsorbate Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000000746 purification Methods 0.000 description 2
230000001603 reducing effect Effects 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
239000002912 waste gas Substances 0.000 description 2
229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
241001050985 Disco Species 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
RVKFQAJIXCZXQY-CBZIJGRNSA-N [(8r,9s,13s,14s)-13-methyl-17-oxo-7,8,9,11,12,14,15,16-octahydro-6h-cyclopenta[a]phenanthren-3-yl] sulfamate Chemical compound NS(=O)(=O)OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 RVKFQAJIXCZXQY-CBZIJGRNSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000012080 ambient air Substances 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
150000001875 compounds Chemical group 0.000 description 1
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
229940045803 cuprous chloride Drugs 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000003378 silver Chemical class 0.000 description 1
229940054334 silver cation Drugs 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
238000010025 steaming Methods 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1

Landscapes

Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CA260,168A 1975-09-26 1976-08-30 Adsorption du monoxyde de carbone a l'aide de zeolite a l'argent Expired CA1069064A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US61708275A	1975-09-26	1975-09-26

Publications (1)

Publication Number	Publication Date
CA1069064A true CA1069064A (fr)	1980-01-01

Family

ID=24472174

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA260,168A Expired CA1069064A (fr)	1975-09-26	1976-08-30	Adsorption du monoxyde de carbone a l'aide de zeolite a l'argent

Country Status (1)

Country	Link
CA (1)	CA1069064A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112755956A (zh) *	2020-12-29	2021-05-07	洛阳建龙微纳新材料股份有限公司	一种高选择性一氧化碳吸附剂及其制备方法和应用

1976
- 1976-08-30 CA CA260,168A patent/CA1069064A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112755956A (zh) *	2020-12-29	2021-05-07	洛阳建龙微纳新材料股份有限公司	一种高选择性一氧化碳吸附剂及其制备方法和应用
CN112755956B (zh) *	2020-12-29	2023-12-01	洛阳建龙微纳新材料股份有限公司	一种高选择性一氧化碳吸附剂及其制备方法和应用

Legal Events

Date	Code	Title	Description
1997-01-01	MKEX	Expiry

Publication	Publication Date	Title
US4019880A (en)	1977-04-26	Adsorption of carbon monoxide using silver zeolites
US4019879A (en)	1977-04-26	Selective adsorption of carbon monoxide from gas streams
JP5732451B2 (ja)	2015-06-10	天然ガス処理における、ｒｈｏ構造を備えるゼオライト特性の微孔性結晶性材料の使用
AU768949B2 (en)	2004-01-08	Zeolite adsorbents, method for obtaining them and their use for removing carbonates from a gas stream
US5120515A (en)	1992-06-09	Simultaneous dehydration and removal of residual impurities from gaseous hydrocarbons
AU742832B2 (en)	2002-01-10	Decarbonating gas streams using zeolite adsorbents
CN1229907A (zh)	1999-09-29	在低温蒸馏前通过吸附将空气净化的方法
CA1074765A (fr)	1980-04-01	Production de cu-zeolithes
CA2413513A1 (fr)	2002-01-03	Elimination d'hydrocarbures d'un gaz d'alimentation de claus
FI111245B (fi)	2003-06-30	Menetelmä ammoniakin erottamiseksi kaasuseoksesta ja adsorbenttikoostumuksen käyttö tässä erotuksessa
US5190908A (en)	1993-03-02	Racked bed for removal of residual mercury from gaseous hydrocarbons
US5160512A (en)	1992-11-03	Gas separation process
WO2010113173A2 (fr)	2010-10-07	Adsorbants à base de zéolite x échangée contre du baryum et du potassium pour l'élimination du co2 d'un mélange gazeux et préparation desdits adsorbants
US7319082B2 (en)	2008-01-15	Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air
US5223237A (en)	1993-06-29	Process for removing sulfur oxides from a gas stream
CN100482319C (zh)	2009-04-29	氨气或甲醇一步法净化方法
CN1043311C (zh)	1999-05-12	高选择性吸附一氧化碳的沸石吸附剂的制备方法
US3186789A (en)	1965-06-01	Method of removing hydrogen sulfide from gases
JPH035845B2 (fr)	1991-01-28
RU2624297C1 (ru)	2017-07-03	Способ получения двуокиси углерода из дымовых газов
AU2009323821A1 (en)	2011-07-07	Process for gas separation
Zhang et al.	1992	Adsorption-desorption properties of nitrogen monoxide on metal ion-exchanged zeolites
CA1304343C (fr)	1992-06-30	Adsorbants servant a la separation de l'oxyde de carbone et des hydrocarbures non satures de melanges gazeux
JPH0373334B2 (fr)	1991-11-21
JPH10128106A (ja)	1998-05-19	酸素ｐｓａ用吸着剤、その製造法並びにそれを用いた酸素製造方法