CA1071613A - Recuperation de l'hydrogene sulfure en presence dans les gaz - Google Patents

Recuperation de l'hydrogene sulfure en presence dans les gaz

Info

Publication number: CA1071613A
Authority: CA; Canada
Prior art keywords: solution; iron; chelating agent; process according; range
Prior art date: 1975-02-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA244,202A

Other languages

English (en)

Inventor

Ralph B. Thompson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

AIR RESOURCES

Original Assignee

AIR RESOURCES

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-02-20

Filing date

1976-01-26

Publication date

1980-02-12

1976-01-26 Application filed by AIR RESOURCES filed Critical AIR RESOURCES

1980-02-12 Application granted granted Critical

1980-02-12 Publication of CA1071613A publication Critical patent/CA1071613A/fr

Status Expired legal-status Critical Current

Links

239000007789 gas Substances 0.000 title claims abstract description 53
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 45
229910000037 hydrogen sulfide Inorganic materials 0.000 title claims abstract description 44
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 198
239000000243 solution Substances 0.000 claims abstract description 143
229910052742 iron Inorganic materials 0.000 claims abstract description 95
239000002738 chelating agent Substances 0.000 claims abstract description 63
238000000034 method Methods 0.000 claims abstract description 51
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 18
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 18
238000001556 precipitation Methods 0.000 claims abstract description 12
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims abstract description 11
229960004887 ferric hydroxide Drugs 0.000 claims abstract description 8
IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims abstract description 8
230000033116 oxidation-reduction process Effects 0.000 claims abstract description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
239000000203 mixture Substances 0.000 claims description 31
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 26
-1 alkali metal salts Chemical class 0.000 claims description 22
229910052783 alkali metal Inorganic materials 0.000 claims description 20
238000006243 chemical reaction Methods 0.000 claims description 19
230000008929 regeneration Effects 0.000 claims description 19
238000011069 regeneration method Methods 0.000 claims description 19
235000000346 sugar Nutrition 0.000 claims description 19
239000002253 acid Substances 0.000 claims description 17
150000007513 acids Chemical class 0.000 claims description 17
239000007864 aqueous solution Substances 0.000 claims description 13
229910000029 sodium carbonate Inorganic materials 0.000 claims description 13
239000000463 material Substances 0.000 claims description 12
230000003647 oxidation Effects 0.000 claims description 12
238000007254 oxidation reaction Methods 0.000 claims description 12
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 11
239000000600 sorbitol Substances 0.000 claims description 11
150000008163 sugars Chemical class 0.000 claims description 11
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 10
159000000000 sodium salts Chemical class 0.000 claims description 10
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 8
150000001412 amines Chemical class 0.000 claims description 8
229960001484 edetic acid Drugs 0.000 claims description 8
239000000797 iron chelating agent Substances 0.000 claims description 7
229940075525 iron chelating agent Drugs 0.000 claims description 7
URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical class OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
239000001301 oxygen Substances 0.000 claims description 5
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 4
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
229930195725 Mannitol Natural products 0.000 claims description 4
239000000594 mannitol Substances 0.000 claims description 4
235000010355 mannitol Nutrition 0.000 claims description 4
230000001590 oxidative effect Effects 0.000 claims description 2
230000001172 regenerating effect Effects 0.000 claims description 2
229940123150 Chelating agent Drugs 0.000 claims 32
150000001735 carboxylic acids Chemical class 0.000 claims 3
150000001243 acetic acids Chemical class 0.000 claims 2
239000003795 chemical substances by application Substances 0.000 claims 1
238000010521 absorption reaction Methods 0.000 abstract description 10
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract description 6
229910001447 ferric ion Inorganic materials 0.000 abstract description 5
229910001448 ferrous ion Inorganic materials 0.000 abstract description 4
238000005273 aeration Methods 0.000 abstract description 3
239000012141 concentrate Substances 0.000 description 13
229910052717 sulfur Inorganic materials 0.000 description 10
239000011593 sulfur Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
239000002002 slurry Substances 0.000 description 7
239000003153 chemical reaction reagent Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
229910021578 Iron(III) chloride Inorganic materials 0.000 description 5
239000000706 filtrate Substances 0.000 description 5
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 5
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 5
241000040710 Chela Species 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
229940032296 ferric chloride Drugs 0.000 description 4
238000007086 side reaction Methods 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
238000005201 scrubbing Methods 0.000 description 3
239000007921 spray Substances 0.000 description 3
KWMLJOLKUYYJFJ-GASJEMHNSA-N (2xi)-D-gluco-heptonic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C(O)=O KWMLJOLKUYYJFJ-GASJEMHNSA-N 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
239000012670 alkaline solution Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000003518 caustics Substances 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000010586 diagram Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011734 sodium Substances 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
239000012991 xanthate Substances 0.000 description 2
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
229920000298 Cellophane Polymers 0.000 description 1
241000861718 Chloris <Aves> Species 0.000 description 1
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
229930091371 Fructose Natural products 0.000 description 1
239000005715 Fructose Substances 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
125000003172 aldehyde group Chemical group 0.000 description 1
VREFGVBLTWBCJP-UHFFFAOYSA-N alprazolam Chemical compound C12=CC(Cl)=CC=C2N2C(C)=NN=C2CN=C1C1=CC=CC=C1 VREFGVBLTWBCJP-UHFFFAOYSA-N 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
239000000306 component Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
150000002016 disaccharides Chemical class 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
238000001914 filtration Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
239000008103 glucose Substances 0.000 description 1
235000001727 glucose Nutrition 0.000 description 1
229960001031 glucose Drugs 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
150000002505 iron Chemical class 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
239000008101 lactose Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002772 monosaccharides Chemical class 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 1
229960000965 nimesulide Drugs 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
150000003017 phosphorus Chemical class 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000009877 rendering Methods 0.000 description 1
239000010865 sewage Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
239000002912 waste gas Substances 0.000 description 1
238000009279 wet oxidation reaction Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1468—Removing hydrogen sulfide

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Treating Waste Gases (AREA)
Gas Separation By Absorption (AREA)

CA244,202A 1975-02-20 1976-01-26 Recuperation de l'hydrogene sulfure en presence dans les gaz Expired CA1071613A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US55127975A	1975-02-20	1975-02-20

Publications (1)

Publication Number	Publication Date
CA1071613A true CA1071613A (fr)	1980-02-12

Family

ID=24200600

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA244,202A Expired CA1071613A (fr)	1975-02-20	1976-01-26	Recuperation de l'hydrogene sulfure en presence dans les gaz

Country Status (4)

Country	Link
JP (1)	JPS6010773B2 (fr)
CA (1)	CA1071613A (fr)
DE (1)	DE2606277C2 (fr)
GB (1)	GB1538925A (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2740039A1 (de) *	1977-09-06	1979-03-15	Heinz Hoelter	2-stufen-gaswaescher
JPS5484876A (en) *	1977-12-19	1979-07-06	Nippon Steel Corp	Apparatus for withdrawing desulfurizing liquid in oxidation-reduction desulfurization method
EP0011517A3 (fr) *	1978-10-06	1980-07-23	Rhone-Poulenc Industries	Procédé et appareillage pour l'élimination de l'hydrogène sulfuré des courants gazeux
FR2463637A1 (fr) *	1979-08-17	1981-02-27	Rhone Poulenc Ind	Procede et appareillage pour l'elimination de l'hydrogene sulfure des courants gazeux
FR2437863A1 (fr) *	1978-10-06	1980-04-30	Rhone Poulenc Ind	Procede et appareillage pour l'elimination de l'hydrogene sulfure des courants gazeux
AT379759B (de) *	1984-04-05	1986-02-25	Kimura Kakoki Co Ltd	Verfahren zur entfernung von schwefelwasserstoff aus gasen
CN102397744B (zh) *	2011-04-28	2013-10-16	中国石油天然气股份有限公司	一种络合铁脱硫溶液的复配型硫磺分散剂
CN109663484A (zh) *	2017-10-17	2019-04-23	中国石油化工股份有限公司	高效硫化氢气体吸消液及用途
CN110551543A (zh) *	2019-09-12	2019-12-10	欧润吉生态环保(浙江)有限公司	一种沼气深度脱硫的装置
CN115738599B (zh) *	2022-11-23	2024-06-04	攀钢集团攀枝花钢铁研究院有限公司	同时吸收NOx及CO的络合脱硝液的制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3097925A (en) *	1958-04-17	1963-07-16	Atlantic Refining Co	Method of recovering sulphur
DE1253858B (de) *	1962-10-05	1967-11-09	Koppers Gmbh Heinrich	Verfahren zum Entfernen von organischen Schwefelverbindungen, die keine oder nur eine sehr geringe Wasserloeslichkeit aufweisen, aus Gasen

1976
- 1976-01-26 CA CA244,202A patent/CA1071613A/fr not_active Expired
- 1976-01-30 GB GB385976A patent/GB1538925A/en not_active Expired
- 1976-02-13 JP JP51014100A patent/JPS6010773B2/ja not_active Expired
- 1976-02-17 DE DE19762606277 patent/DE2606277C2/de not_active Expired

Also Published As

Publication number	Publication date
DE2606277C2 (de)	1985-05-23
GB1538925A (en)	1979-01-24
JPS6010773B2 (ja)	1985-03-20
JPS51107273A (ja)	1976-09-22
DE2606277A1 (de)	1976-09-09

Legal Events

Date	Code	Title	Description
1997-02-12	MKEX	Expiry

Publication	Publication Date	Title
US4189462A (en)	1980-02-19	Catalytic removal of hydrogen sulfide from gases
CA1159434A (fr)	1983-12-27	Compose et methode pour eliminer le sulfure d'hydrogene des courants gazeux
US4076621A (en)	1978-02-28	Chelate oxidation of hydrogen sulfide in sour water
JP2506596B2 (ja)	1996-06-12	Ｈ２ｓを分離したアブゾ―バ―及びオキシダイザ―及びそれらの間の反応チャンバ―により取り除く方法及び装置
US4889701A (en)	1989-12-26	Process for oxidizing multivalent metals
EP0097303B1 (fr)	1987-01-07	Elimination d'hydrogène sulfuré de courants fluides avec production minimum de solides
US4649032A (en)	1987-03-10	Process for the selective removal of hydrogen sulfide from gaseous streams
US4774071A (en)	1988-09-27	Process and composition for the removal of hydrogen sulfide from gaseous streams
EP0279667A2 (fr)	1988-08-24	Procédé pour la séparation d'acide sulfhydrique et éventuellement de dioxyde de carbone de courants gazeux
GB2202840A (en)	1988-10-05	Removing hydrogen sulphide from sour water
EP0086919B1 (fr)	1987-09-16	Procédé pour l'élimination sélective d'hydrogène sulfuré de courants gazeux
US4283379A (en)	1981-08-11	Method for removing hydrogen sulfide from gas streams
CA1071613A (fr)	1980-02-12	Recuperation de l'hydrogene sulfure en presence dans les gaz
US4525338A (en)	1985-06-25	Method for removal of hydrogen sulfide
US4218342A (en)	1980-08-19	Composition for catalytic removal of hydrogen sulfide from gases
CN206940821U (zh)	2018-01-30	络合铁脱硫装置
US4919914A (en)	1990-04-24	Removal of hydrogen sulphide from gaseous streams
JPH0712411B2 (ja)	1995-02-15	サワ−ガスの流れからの硫化水素の除去
US5139753A (en)	1992-08-18	Continuous process for mass transfer of a liquid reagent with two different gases
US4367212A (en)	1983-01-04	Control of thiosulfate in wet desulfurization process solutions
DeBerry	1997	Chemical evolution of liquid redox processes
US4781901A (en)	1988-11-01	Method and composition for the removal of hydrogen sulfide and carbon dioxide from gaseous streams
US4432962A (en)	1984-02-21	Method for removing hydrogen sulfide from gas streams
US5026503A (en)	1991-06-25	Composition and method for removing hydrogen sulfide from gas streams
CA1042183A (fr)	1978-11-14	Suppression et enlevement des depots de soufre dans le materiel d'absorption du h2s