CA1074290A - Catalyseur pour polymerisation - Google Patents

Catalyseur pour polymerisation

Info

Publication number: CA1074290A
Authority: CA; Canada
Prior art keywords: titanium; support material; alcohol; compound; phenol
Prior art date: 1972-07-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA259,512A

Other languages

English (en)

Inventor

Brian P.F. Goldie

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BP PLC

Original Assignee

BP PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-07-25

Filing date

1976-08-20

Publication date

1980-03-25

1972-07-25 Priority claimed from GB3475972A external-priority patent/GB1402777A/en

1976-08-20 Application filed by BP PLC filed Critical BP PLC

1980-03-25 Application granted granted Critical

1980-03-25 Publication of CA1074290A publication Critical patent/CA1074290A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 33
239000000463 material Substances 0.000 claims abstract description 37
238000000034 method Methods 0.000 claims abstract description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
150000003609 titanium compounds Chemical class 0.000 claims abstract description 18
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 17
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 8
239000011777 magnesium Substances 0.000 claims abstract description 8
229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 7
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 6
239000000377 silicon dioxide Substances 0.000 claims abstract description 5
238000010438 heat treatment Methods 0.000 claims abstract description 4
229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 4
239000000395 magnesium oxide Substances 0.000 claims abstract description 4
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 4
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 4
229910052736 halogen Inorganic materials 0.000 claims abstract description 3
238000004519 manufacturing process Methods 0.000 claims abstract description 3
239000010936 titanium Substances 0.000 claims description 26
229910052719 titanium Inorganic materials 0.000 claims description 24
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 22
150000001875 compounds Chemical class 0.000 claims description 8
239000012442 inert solvent Substances 0.000 claims description 7
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 5
125000004429 atom Chemical group 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
239000007789 gas Substances 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims description 3
238000005243 fluidization Methods 0.000 claims description 2
239000007921 spray Substances 0.000 claims description 2
239000011261 inert gas Substances 0.000 claims 1
239000012190 activator Substances 0.000 abstract description 7
239000004411 aluminium Substances 0.000 abstract description 2
229910052782 aluminium Inorganic materials 0.000 abstract description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
150000002367 halogens Chemical class 0.000 abstract description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
238000005406 washing Methods 0.000 description 7
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
-1 zinc halide Chemical class 0.000 description 6
239000007788 liquid Substances 0.000 description 5
239000000178 monomer Substances 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
239000001282 iso-butane Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
229910010066 TiC14 Inorganic materials 0.000 description 2
235000010210 aluminium Nutrition 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000012159 carrier gas Substances 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
239000002612 dispersion medium Substances 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
239000000155 melt Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000000243 solution Substances 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
HNUALPPJLMYHDK-UHFFFAOYSA-N C[CH]C Chemical compound C[CH]C HNUALPPJLMYHDK-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
RTQCAYKHUMWCEM-UHFFFAOYSA-N [Mg].ClO Chemical compound [Mg].ClO RTQCAYKHUMWCEM-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
125000001145 hydrido group Chemical group *[H] 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
150000003509 tertiary alcohols Chemical class 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CA259,512A 1972-07-25 1976-08-20 Catalyseur pour polymerisation Expired CA1074290A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB3475972A GB1402777A (en)	1971-08-13	1972-07-25	Contact adhesive dispersions

Publications (1)

Publication Number	Publication Date
CA1074290A true CA1074290A (fr)	1980-03-25

Family

ID=10369617

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA259,512A Expired CA1074290A (fr)	1972-07-25	1976-08-20	Catalyseur pour polymerisation

Country Status (1)

Country	Link
CA (1)	CA1074290A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2018011156A1 (fr) *	2016-07-12	2018-01-18	Total Raffinage Chimie	Procédé catalytique pour la dimérisation des diènes

1976
- 1976-08-20 CA CA259,512A patent/CA1074290A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2018011156A1 (fr) *	2016-07-12	2018-01-18	Total Raffinage Chimie	Procédé catalytique pour la dimérisation des diènes

Legal Events

Date	Code	Title	Description
1997-03-25	MKEX	Expiry

Publication	Publication Date	Title
US4082692A (en)	1978-04-04	Polymerization catalyst
CA1141365A (fr)	1983-02-15	Catalyseur et methode de polymerisation
CA1145318A (fr)	1983-04-26	Catalyseur de polymerisation olefinique, methode de preparation et polyolefine obtenue
CA1177050A (fr)	1984-10-30	Catalyseur et methode de polymerisation
US4748221A (en)	1988-05-31	Polymerization of olefins using a ziegler-natta catalyst and two organometallic compounds
US4617360A (en)	1986-10-14	Process for the polymerization of α-olefins
CA1265646A (fr)	1990-02-06	METHODE D'AMORCAGE DE LA POLYMERISATION OU DE LA COPOLYMERISATION DE L'OLEFINE .alpha. EN PHASE GAZEUSE EN PRESENCE D'UN SYSTEME CATALYSEUR ZIEGLER-MATTA
US4354009A (en)	1982-10-12	Catalyst composition for copolymerizing ethylene
CA1074285A (fr)	1980-03-25	Catalyseur de polymerisation
US3993588A (en)	1976-11-23	Polymerization catalyst
US4097409A (en)	1978-06-27	Preparation of titanium containing catalyst on magnesium support material
NZ212569A (en)	1987-11-27	Polymerisation of alpha-olefins in a fluidised bed using ziegler-natta type catalyst and cocatalyst therefor
CA1090773A (fr)	1980-12-02	Catalyseur de la polymerisation
CA1107270A (fr)	1981-08-18	CATALYSEUR DE LA POLYMERISATION DES .alpha.-OLEFINES
US4396533A (en)	1983-08-02	Polymerization catalyst
US4478988A (en)	1984-10-23	Polymerization method
US4397762A (en)	1983-08-09	Polymerization catalyst
US4027088A (en)	1977-05-31	Process of preparing polyolefins
US4170568A (en)	1979-10-09	Polymerization catalyst
GB2053939A (en)	1981-02-11	Oxide supported vanadium halide catalyst components
GB2073761A (en)	1981-10-21	Olefin polymerisation catalyst
CA1207499A (fr)	1986-07-08	Methode et catalyseur de preparation de polyolefine
GB1559172A (en)	1980-01-16	Supported ziegler catalyst component
US5484754A (en)	1996-01-16	Process for treating a catalytic component, resultant component, and polymerization of ethylene using such component
US4145312A (en)	1979-03-20	Polymerization catalyst

CA1074290A - Catalyseur pour polymerisation - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=10369617

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

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