CA1079350A - Cellules a combustible utilisant des electrolytes a chlorure - Google Patents

Cellules a combustible utilisant des electrolytes a chlorure

Info

Publication number: CA1079350A
Authority: CA; Canada
Prior art keywords: anolyte; catholyte; energy conversion; conversion apparatus; accordance
Prior art date: 1977-11-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA291,579A

Other languages

English (en)

Inventor

Raiph Zito (Jr.)

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Gel Inc

Original Assignee

Gel Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-23

Filing date

1977-11-23

Publication date

1980-06-10

1977-11-23 Application filed by Gel Inc filed Critical Gel Inc

1977-11-23 Priority to CA291,579A priority Critical patent/CA1079350A/fr

1980-06-10 Application granted granted Critical

1980-06-10 Publication of CA1079350A publication Critical patent/CA1079350A/fr

Status Expired legal-status Critical Current

Links

239000003792 electrolyte Substances 0.000 title claims description 50
239000000446 fuel Substances 0.000 title abstract description 14
FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 title description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 135
238000006243 chemical reaction Methods 0.000 claims abstract description 46
229910052742 iron Inorganic materials 0.000 claims abstract description 40
230000004888 barrier function Effects 0.000 claims abstract description 19
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
239000011701 zinc Substances 0.000 claims abstract description 13
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 11
238000009792 diffusion process Methods 0.000 claims abstract description 11
239000007788 liquid Substances 0.000 claims abstract description 11
229910052725 zinc Inorganic materials 0.000 claims abstract description 10
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 6
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims abstract 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 32
239000012530 fluid Substances 0.000 claims description 32
238000007747 plating Methods 0.000 claims description 25
229910052751 metal Inorganic materials 0.000 claims description 17
239000002184 metal Substances 0.000 claims description 17
229910052799 carbon Inorganic materials 0.000 claims description 14
230000003647 oxidation Effects 0.000 claims description 13
238000007254 oxidation reaction Methods 0.000 claims description 13
230000010287 polarization Effects 0.000 claims description 13
230000003134 recirculating effect Effects 0.000 claims description 13
239000004033 plastic Substances 0.000 claims description 9
239000000126 substance Substances 0.000 claims description 8
229920003023 plastic Polymers 0.000 claims description 7
230000008859 change Effects 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
239000002131 composite material Substances 0.000 claims description 4
230000001351 cycling effect Effects 0.000 claims description 4
239000002738 chelating agent Substances 0.000 claims description 3
230000003247 decreasing effect Effects 0.000 claims description 3
238000010248 power generation Methods 0.000 claims description 3
150000001768 cations Chemical class 0.000 claims description 2
230000002708 enhancing effect Effects 0.000 claims description 2
239000003125 aqueous solvent Substances 0.000 claims 2
239000000956 alloy Substances 0.000 claims 1
229910045601 alloy Inorganic materials 0.000 claims 1
230000000740 bleeding effect Effects 0.000 claims 1
239000007800 oxidant agent Substances 0.000 abstract description 16
-1 Fe+++ ion Chemical class 0.000 abstract description 15
239000007787 solid Substances 0.000 abstract description 15
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 6
230000002441 reversible effect Effects 0.000 abstract description 6
238000007599 discharging Methods 0.000 abstract description 5
239000004449 solid propellant Substances 0.000 abstract description 3
238000009825 accumulation Methods 0.000 abstract description 2
229920000136 polysorbate Polymers 0.000 abstract description 2
239000000356 contaminant Substances 0.000 abstract 1
230000000630 rising effect Effects 0.000 abstract 1
210000004027 cell Anatomy 0.000 description 100
239000000243 solution Substances 0.000 description 26
150000002500 ions Chemical class 0.000 description 23
238000000034 method Methods 0.000 description 18
229910015400 FeC13 Inorganic materials 0.000 description 15
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 14
229940037395 electrolytes Drugs 0.000 description 13
229910002804 graphite Inorganic materials 0.000 description 13
239000010439 graphite Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 13
239000000758 substrate Substances 0.000 description 13
230000008569 process Effects 0.000 description 12
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 11
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 8
229940090045 cartridge Drugs 0.000 description 8
239000000460 chlorine Substances 0.000 description 8
238000005755 formation reaction Methods 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
239000002033 PVDF binder Substances 0.000 description 7
239000000306 component Substances 0.000 description 7
239000007789 gas Substances 0.000 description 7
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 7
RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
229920001577 copolymer Polymers 0.000 description 6
230000000694 effects Effects 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000002585 base Substances 0.000 description 5
239000003610 charcoal Substances 0.000 description 5
239000003153 chemical reaction reagent Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
230000000875 corresponding effect Effects 0.000 description 5
229960002089 ferrous chloride Drugs 0.000 description 5
150000002506 iron compounds Chemical class 0.000 description 5
235000013980 iron oxide Nutrition 0.000 description 5
239000000463 material Substances 0.000 description 5
239000012528 membrane Substances 0.000 description 5
210000004379 membrane Anatomy 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
239000011780 sodium chloride Substances 0.000 description 5
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
229920006370 Kynar Polymers 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
150000001805 chlorine compounds Chemical class 0.000 description 4
238000000576 coating method Methods 0.000 description 4
238000010276 construction Methods 0.000 description 4
238000004146 energy storage Methods 0.000 description 4
229910001448 ferrous ion Inorganic materials 0.000 description 4
230000007062 hydrolysis Effects 0.000 description 4
238000006460 hydrolysis reaction Methods 0.000 description 4
239000004800 polyvinyl chloride Substances 0.000 description 4
229920000915 polyvinyl chloride Polymers 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
QHGVXILFMXYDRS-UHFFFAOYSA-N pyraclofos Chemical compound C1=C(OP(=O)(OCC)SCCC)C=NN1C1=CC=C(Cl)C=C1 QHGVXILFMXYDRS-UHFFFAOYSA-N 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
241000894007 species Species 0.000 description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
239000000853 adhesive Substances 0.000 description 3
230000001070 adhesive effect Effects 0.000 description 3
230000008901 benefit Effects 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000010949 copper Substances 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
238000013461 design Methods 0.000 description 3
238000010586 diagram Methods 0.000 description 3
229910003460 diamond Inorganic materials 0.000 description 3
239000010432 diamond Substances 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
238000011010 flushing procedure Methods 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 3
238000002156 mixing Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
230000003381 solubilizing effect Effects 0.000 description 3
239000002904 solvent Substances 0.000 description 3
125000006850 spacer group Chemical group 0.000 description 3
238000012546 transfer Methods 0.000 description 3
229940123150 Chelating agent Drugs 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
229910021577 Iron(II) chloride Inorganic materials 0.000 description 2
230000009102 absorption Effects 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000004364 calculation method Methods 0.000 description 2
230000009920 chelation Effects 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
239000004020 conductor Substances 0.000 description 2
230000002844 continuous effect Effects 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000005684 electric field Effects 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
235000014413 iron hydroxide Nutrition 0.000 description 2
235000010213 iron oxides and hydroxides Nutrition 0.000 description 2
239000004407 iron oxides and hydroxides Substances 0.000 description 2
NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical class [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
238000005259 measurement Methods 0.000 description 2
230000036961 partial effect Effects 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
230000036647 reaction Effects 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000006722 reduction reaction Methods 0.000 description 2
238000012827 research and development Methods 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000000565 sealant Substances 0.000 description 2
239000013049 sediment Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
238000005303 weighing Methods 0.000 description 2
239000000080 wetting agent Substances 0.000 description 2
QOLHIVSOGUUQQS-UHFFFAOYSA-N 1,10-phenanthrolin-2-yl nitrate Chemical compound [N+](=O)([O-])OC1=NC2=C3N=CC=CC3=CC=C2C=C1 QOLHIVSOGUUQQS-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
241000905957 Channa melasoma Species 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
102100026933 Myelin-associated neurite-outgrowth inhibitor Human genes 0.000 description 1
JQGGAELIYHNDQS-UHFFFAOYSA-N Nic 12 Natural products CC(C=CC(=O)C)c1ccc2C3C4OC4C5(O)CC=CC(=O)C5(C)C3CCc2c1 JQGGAELIYHNDQS-UHFFFAOYSA-N 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
229910052774 Proactinium Inorganic materials 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Inorganic materials [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
ICGLOTCMOYCOTB-UHFFFAOYSA-N [Cl].[Zn] Chemical compound [Cl].[Zn] ICGLOTCMOYCOTB-UHFFFAOYSA-N 0.000 description 1
BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 1
230000035508 accumulation Effects 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
238000005275 alloying Methods 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000003491 array Methods 0.000 description 1
230000000712 assembly Effects 0.000 description 1
238000000429 assembly Methods 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
238000009529 body temperature measurement Methods 0.000 description 1
239000006172 buffering agent Substances 0.000 description 1
BBBFJLBPOGFECG-VJVYQDLKSA-N calcitonin Chemical compound N([C@H](C(=O)N[C@@H](CC(C)C)C(=O)NCC(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CO)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC=1NC=NC=1)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CC=1C=CC(O)=CC=1)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H]([C@@H](C)O)C(=O)NCC(=O)N[C@@H](CO)C(=O)NCC(=O)N[C@@H]([C@@H](C)O)C(=O)N1[C@@H](CCC1)C(N)=O)C(C)C)C(=O)[C@@H]1CSSC[C@H](N)C(=O)N[C@@H](CO)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CO)C(=O)N[C@@H]([C@@H](C)O)C(=O)N1 BBBFJLBPOGFECG-VJVYQDLKSA-N 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000013522 chelant Substances 0.000 description 1
238000003889 chemical engineering Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000004737 colorimetric analysis Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
230000002596 correlated effect Effects 0.000 description 1
230000005574 cross-species transmission Effects 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
210000001787 dendrite Anatomy 0.000 description 1
230000000881 depressing effect Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
239000004700 high-density polyethylene Substances 0.000 description 1
229940063583 high-density polyethylene Drugs 0.000 description 1
235000003642 hunger Nutrition 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000007689 inspection Methods 0.000 description 1
239000011810 insulating material Substances 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000007733 ion plating Methods 0.000 description 1
159000000014 iron salts Chemical class 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
210000003127 knee Anatomy 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
230000013011 mating Effects 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
239000002609 medium Substances 0.000 description 1
230000008384 membrane barrier Effects 0.000 description 1
239000012982 microporous membrane Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
150000002815 nickel Chemical class 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
230000009965 odorless effect Effects 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
230000033116 oxidation-reduction process Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
CFCQBWWQMZWALG-UHFFFAOYSA-N oxonickel;zinc Chemical compound [Zn].[Ni]=O CFCQBWWQMZWALG-UHFFFAOYSA-N 0.000 description 1
150000002927 oxygen compounds Chemical class 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000011946 reduction process Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000004044 response Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
230000009919 sequestration Effects 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
230000037351 starvation Effects 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000001629 suppression Effects 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
150000003567 thiocyanates Chemical class 0.000 description 1
230000007723 transport mechanism Effects 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Hybrid Cells (AREA)

CA291,579A 1977-11-23 1977-11-23 Cellules a combustible utilisant des electrolytes a chlorure Expired CA1079350A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA291,579A CA1079350A (fr)	1977-11-23	1977-11-23	Cellules a combustible utilisant des electrolytes a chlorure

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA291,579A CA1079350A (fr)	1977-11-23	1977-11-23	Cellules a combustible utilisant des electrolytes a chlorure

Publications (1)

Publication Number	Publication Date
CA1079350A true CA1079350A (fr)	1980-06-10

Family

ID=4110116

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA291,579A Expired CA1079350A (fr)	1977-11-23	1977-11-23	Cellules a combustible utilisant des electrolytes a chlorure

Country Status (1)

Country	Link
CA (1)	CA1079350A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN106414809A (zh) *	2013-12-16	2017-02-15	阿海珐	大容量的电能储存装置
CN116079166A (zh) *	2023-02-20	2023-05-09	西北工业大学	一种用于非晶合金材料电化学成形的电解液及制备方法

1977
- 1977-11-23 CA CA291,579A patent/CA1079350A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN106414809A (zh) *	2013-12-16	2017-02-15	阿海珐	大容量的电能储存装置
CN116079166A (zh) *	2023-02-20	2023-05-09	西北工业大学	一种用于非晶合金材料电化学成形的电解液及制备方法

Legal Events

Date	Code	Title	Description
1997-06-10	MKEX	Expiry

Publication	Publication Date	Title
US4069371A (en)	1978-01-17	Energy conversion
Vincent et al.	1997	Modern batteries
US8158277B1 (en)	2012-04-17	Cross-flow electrochemical batteries
DE69220030T2 (de)	1997-12-11	Mechanisch wiederaufladbare Batterien und darin verwendbare Anoden
CA1207832A (fr)	1986-07-15	Accumulateur zinc et brome a stabilite de longue duree
DE202011051993U1 (de)	2012-03-07	Mehrmodusladen von hierarchischer Anode
KR102149159B1 (ko)	2020-08-28	높은 개방 회로 전위를 특징으로 하는 전기화학적 시스템
BG61627B1 (bg)	1998-01-30	Метод и система за електрохимично акумулиране на енергияи/или генериране на мощност
GB1569398A (en)	1980-06-11	Metal halogen batteries and method of operating same
JPH08502386A (ja)	1996-03-12	空気電極を用いた電力配給用電気化学的装置
US3909298A (en)	1975-09-30	Batteries comprising vented electrodes and method of using same
EP1371067B1 (fr)	2005-06-01	Compose de haute conductivite pour electrons ; electrode de pile electrochimique comprenant ce compose ; procede de preparation d'une electrode et d'une pile electrochimique
Lu et al.	2022	Introduction to zinc–air batteries
MU¨ LLER et al.	1998	Development of a 100 W rechargeable bipolar zinc/oxygen battery
JP3315508B2 (ja)	2002-08-19	電解液再調整装置付電解液流通型電池
CA1079350A (fr)	1980-06-10	Cellules a combustible utilisant des electrolytes a chlorure
GB1587748A (en)	1981-04-08	Energy conversion apparatus
Munshi et al.	1985	The dissolution of iron from the negative material in pocket plate nickel-cadmium batteries
KR20210147005A (ko)	2021-12-06	고전압 및 확장가능한 에너지 저장을 위한 전해 배터리
KR101015698B1 (ko)	2011-02-22	분말형 연료 전지
JPH0821415B2 (ja)	1996-03-04	二次電池用リバランス装置の燃料電池
EP3565048A1 (fr)	2019-11-06	Batterie redox
Kazacos	1989	Electrolyte optimization and electrode material evaluation for the vanadium redox battery
DE2129045C3 (de)	1975-11-13	Elektrochemische Zelle zur Energiespeicherung, in der die Elektrode einer Polarität eine Akkumulatorelektrode, die der anderen Polarität eine Gaselektrode ist
DE2444147B2 (de)	1978-06-15	Elektrochemische Sekundärzelle mit einer negativen Zinkelektrode

CA1079350A - Cellules a combustible utilisant des electrolytes a chlorure - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (1)

Family

ID=4110116

Family Applications (1)

Country Status (1)

Cited By (2)

Cited By (2)

Similar Documents

Legal Events