CA1079663A - Procede pour l'hydrodesulfurisation de matieres carbonees a l'aide d'un catalyseur en suspension - Google Patents

Procede pour l'hydrodesulfurisation de matieres carbonees a l'aide d'un catalyseur en suspension

Info

Publication number: CA1079663A
Authority: CA; Canada
Prior art keywords: catalyst; hydrogen; suspension; liquid; coal
Prior art date: 1976-08-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA275,992A

Other languages

English (en)

Inventor

Maurice M. Mitchell (Jr.)

Louis C. Doelp

Lee Friedman

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Air Products and Chemicals Inc

Original Assignee

Air Products and Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-08-13

Filing date

1977-04-12

Publication date

1980-06-17

1976-08-13 Priority claimed from US05/714,035 external-priority patent/US4075082A/en

1977-04-12 Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc

1980-06-17 Application granted granted Critical

1980-06-17 Publication of CA1079663A publication Critical patent/CA1079663A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 80
238000000034 method Methods 0.000 title claims abstract description 36
239000000725 suspension Substances 0.000 claims abstract description 51
239000003245 coal Substances 0.000 claims abstract description 45
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 36
239000001257 hydrogen Substances 0.000 claims abstract description 36
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 31
239000007787 solid Substances 0.000 claims abstract description 28
239000007788 liquid Substances 0.000 claims abstract description 20
239000002245 particle Substances 0.000 claims abstract description 17
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
239000011593 sulfur Substances 0.000 claims abstract description 13
229910052717 sulfur Inorganic materials 0.000 claims abstract description 13
239000000463 material Substances 0.000 claims abstract description 11
229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
238000006243 chemical reaction Methods 0.000 claims description 11
239000003208 petroleum Substances 0.000 claims description 10
238000009835 boiling Methods 0.000 claims description 9
229910052751 metal Inorganic materials 0.000 claims description 9
239000002184 metal Substances 0.000 claims description 9
150000002739 metals Chemical class 0.000 claims description 9
239000003575 carbonaceous material Substances 0.000 claims description 8
150000002431 hydrogen Chemical class 0.000 claims description 5
239000011344 liquid material Substances 0.000 claims description 3
150000003568 thioethers Chemical class 0.000 claims description 2
230000003009 desulfurizing effect Effects 0.000 claims 1
239000000047 product Substances 0.000 abstract description 13
239000007789 gas Substances 0.000 abstract description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
229910052799 carbon Inorganic materials 0.000 abstract description 2
239000012263 liquid product Substances 0.000 abstract description 2
239000003921 oil Substances 0.000 description 28
229960002126 creosote Drugs 0.000 description 11
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 10
235000006173 Larrea tridentata Nutrition 0.000 description 10
244000073231 Larrea tridentata Species 0.000 description 10
230000000694 effects Effects 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
238000006477 desulfuration reaction Methods 0.000 description 4
230000023556 desulfurization Effects 0.000 description 4
230000008929 regeneration Effects 0.000 description 4
238000011069 regeneration method Methods 0.000 description 4
238000000926 separation method Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000012071 phase Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
241000282326 Felis catus Species 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910000428 cobalt oxide Inorganic materials 0.000 description 2
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
230000009849 deactivation Effects 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000000446 fuel Substances 0.000 description 2
238000007689 inspection Methods 0.000 description 2
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
239000011148 porous material Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
241000286904 Leptothecata Species 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
IXWIAFSBWGYQOE-UHFFFAOYSA-M aluminum;magnesium;oxygen(2-);silicon(4+);hydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] IXWIAFSBWGYQOE-UHFFFAOYSA-M 0.000 description 1
238000013459 approach Methods 0.000 description 1
-1 boria Chemical compound 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
238000004939 coking Methods 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000284 extract Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
238000000227 grinding Methods 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000010742 number 1 fuel oil Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
238000010298 pulverizing process Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/083—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts in the presence of a solvent
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/086—Characterised by the catalyst used

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA275,992A 1976-08-13 1977-04-12 Procede pour l'hydrodesulfurisation de matieres carbonees a l'aide d'un catalyseur en suspension Expired CA1079663A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/714,035 US4075082A (en)	1975-07-10	1976-08-13	Process for hydrodesulfurization and liquefaction of carbonaceous stocks using suspended catalyst

Publications (1)

Publication Number	Publication Date
CA1079663A true CA1079663A (fr)	1980-06-17

Family

ID=24868532

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA275,992A Expired CA1079663A (fr)	1976-08-13	1977-04-12	Procede pour l'hydrodesulfurisation de matieres carbonees a l'aide d'un catalyseur en suspension

Country Status (5)

Country	Link
JP (1)	JPS5330607A (fr)
CA (1)	CA1079663A (fr)
DE (1)	DE2720289C2 (fr)
FR (1)	FR2361460A1 (fr)
GB (1)	GB1553454A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3634275A1 (de) *	1986-10-08	1988-04-28	Veba Oel Entwicklungs Gmbh	Verfahren zur hydrierenden konversion von schwer- und rueckstandsoelen
DE3710021A1 (de) *	1987-03-30	1988-10-20	Veba Oel Entwicklungs Gmbh	Verfahren zur hydrierenden konversion von schwer- und rueckstandsoelen

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3183180A (en) *	1964-02-18	1965-05-11	Hydrocarbon Research Inc	Hydrogenation of oils
US3635814A (en) *	1970-11-25	1972-01-18	Atlantic Richfield Co	Catalytic coal conversion process
US3975259A (en) *	1975-07-10	1976-08-17	Air Products And Chemicals, Inc.	Hydrodesulfurization of liquid hydrocarbon utilizing a suspended catalyst particle of less than 10 microns

1977
- 1977-04-12 CA CA275,992A patent/CA1079663A/fr not_active Expired
- 1977-04-28 GB GB1787877A patent/GB1553454A/en not_active Expired
- 1977-05-05 DE DE19772720289 patent/DE2720289C2/de not_active Expired
- 1977-07-14 JP JP8460377A patent/JPS5330607A/ja active Pending
- 1977-08-03 FR FR7723871A patent/FR2361460A1/fr active Granted

Also Published As

Publication number	Publication date
FR2361460B1 (fr)	1984-06-08
GB1553454A (en)	1979-09-26
JPS5330607A (en)	1978-03-23
DE2720289A1 (de)	1978-02-16
FR2361460A1 (fr)	1978-03-10
DE2720289C2 (de)	1982-12-02

Legal Events

Date	Code	Title	Description
1997-06-17	MKEX	Expiry

Publication	Publication Date	Title
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GB2127843A (en)	1984-04-18	Solvent refining of coal
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CA1164380A (fr)	1984-03-27	Methode de liquefaction de la houille
US4330389A (en)	1982-05-18	Coal liquefaction process
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US8226821B2 (en)	2012-07-24	Direct coal liquefaction with integrated product hydrotreating and catalyst cascading
WO2008027868A2 (fr)	2008-03-06	Système et procédé d'hydrotraitement par réacteur à lit expansé d'une cire obtenue par réaction de fischer-tropsch et contaminée par des solides
US4391699A (en)	1983-07-05	Coal liquefaction process
US3594305A (en)	1971-07-20	Process for hydrogenation of coal
CA1236417A (fr)	1988-05-10	Procede d'hydrogenation catalytique du charbon par alimentation directe du reacteur en bouillie de charbon
US3997426A (en)	1976-12-14	Process for the conversion of carbonaceous materials
US4325800A (en)	1982-04-20	Two-stage coal liquefaction process with interstage guard bed
GB2211200A (en)	1989-06-28	Two-stage catalytic coal hydrogenation process
CA1079663A (fr)	1980-06-17	Procede pour l'hydrodesulfurisation de matieres carbonees a l'aide d'un catalyseur en suspension