CA1083272A - Traitement d'un element aqueux contenant du mercure - Google Patents

Traitement d'un element aqueux contenant du mercure

Info

Publication number: CA1083272A
Authority: CA; Canada
Prior art keywords: mercury; sulfide; polysulfide; effluent; elemental
Prior art date: 1977-01-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA269,686A

Other languages

English (en)

Inventor

David M. Findlay

Ronald A. N. Mclean

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Domtar Inc

Original Assignee

Domtar Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-01-13

Filing date

1977-01-13

Publication date

1980-08-05

1977-01-13 Application filed by Domtar Inc filed Critical Domtar Inc

1977-01-13 Priority to CA269,686A priority Critical patent/CA1083272A/fr

1980-08-05 Application granted granted Critical

1980-08-05 Publication of CA1083272A publication Critical patent/CA1083272A/fr

Status Expired legal-status Critical Current

Links

QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 66
229910052753 mercury Inorganic materials 0.000 title claims abstract description 52
239000012736 aqueous medium Substances 0.000 title abstract description 7
239000005077 polysulfide Substances 0.000 claims abstract description 30
150000008117 polysulfides Polymers 0.000 claims abstract description 30
229920001021 polysulfide Polymers 0.000 claims abstract description 27
QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 claims abstract description 18
238000000034 method Methods 0.000 claims abstract description 17
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 12
239000003513 alkali Substances 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 8
HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 claims description 4
229910052979 sodium sulfide Inorganic materials 0.000 claims description 3
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 3
239000007788 liquid Substances 0.000 abstract description 3
229940041669 mercury Drugs 0.000 description 47
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 21
239000012267 brine Substances 0.000 description 20
239000010802 sludge Substances 0.000 description 14
239000000243 solution Substances 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
238000001914 filtration Methods 0.000 description 6
239000002609 medium Substances 0.000 description 6
239000000523 sample Substances 0.000 description 6
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
230000001419 dependent effect Effects 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
239000006228 supernatant Substances 0.000 description 4
229910000497 Amalgam Inorganic materials 0.000 description 3
229910015400 FeC13 Inorganic materials 0.000 description 3
229910020275 Na2Sx Inorganic materials 0.000 description 3
230000001376 precipitating effect Effects 0.000 description 3
239000011734 sodium Substances 0.000 description 3
-1 sulfide ions Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
239000003456 ion exchange resin Substances 0.000 description 2
229920003303 ion-exchange polymer Polymers 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
235000008645 Chenopodium bonus henricus Nutrition 0.000 description 1
244000138502 Chenopodium bonus henricus Species 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
YHQUYMYYBCNHGN-UHFFFAOYSA-N S=[Hg]=S Chemical compound S=[Hg]=S YHQUYMYYBCNHGN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
KYKQHSMYWLWROM-UHFFFAOYSA-N ac1l4yjn Chemical compound [Hg].[Hg] KYKQHSMYWLWROM-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000000203 mixture Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000005498 polishing Methods 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910000033 sodium borohydride Inorganic materials 0.000 description 1
239000012279 sodium borohydride Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
HLCHESOMJVGDSJ-UHFFFAOYSA-N thiq Chemical compound C1=CC(Cl)=CC=C1CC(C(=O)N1CCC(CN2N=CN=C2)(CC1)C1CCCCC1)NC(=O)C1NCC2=CC=CC=C2C1 HLCHESOMJVGDSJ-UHFFFAOYSA-N 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
239000003643 water by type Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Removal Of Specific Substances (AREA)

CA269,686A 1977-01-13 1977-01-13 Traitement d'un element aqueux contenant du mercure Expired CA1083272A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA269,686A CA1083272A (fr)	1977-01-13	1977-01-13	Traitement d'un element aqueux contenant du mercure

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA269,686A CA1083272A (fr)	1977-01-13	1977-01-13	Traitement d'un element aqueux contenant du mercure

Publications (1)

Publication Number	Publication Date
CA1083272A true CA1083272A (fr)	1980-08-05

Family

ID=4107725

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA269,686A Expired CA1083272A (fr)	1977-01-13	1977-01-13	Traitement d'un element aqueux contenant du mercure

Country Status (1)

Country	Link
CA (1)	CA1083272A (fr)

1977
- 1977-01-13 CA CA269,686A patent/CA1083272A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1997-08-05	MKEX	Expiry

Publication	Publication Date	Title
US4147626A (en)	1979-04-03	Treatment of mercury contaminated aqueous media
US5536416A (en)	1996-07-16	Method for removing metals from a solution
AU639561B2 (en)	1993-07-29	Process for the treatment of water containing sulphur compounds
US4329224A (en)	1982-05-11	Wastewater treatment process
US4422943A (en)	1983-12-27	Method for precipitation of heavy metal sulfides
JP4565838B2 (ja)	2010-10-20	硫化剤を用いた重金属含有排水の処理方法および処理装置
US5698107A (en)	1997-12-16	Treatment for acid mine drainage
US4108769A (en)	1978-08-22	Process for reducing the mercury content of industrial waste waters
US4503017A (en)	1985-03-05	Method of purifying waste aqueous solutions from heavy metals
US3749761A (en)	1973-07-31	Process for the recovery of mercury from aqueous solution
US4087359A (en)	1978-05-02	Process for removing mercury and mercury salts from liquid effluents
US4250030A (en)	1981-02-10	Process for the removal of cyanides from effluent
US4124459A (en)	1978-11-07	Process for removing mercury from brine sludges
US3793174A (en)	1974-02-19	Method of treating waste water containing ligninsulfonate
CA2647965C (fr)	2014-12-02	Procedes de precipitation de sulfure de nickel
US4073706A (en)	1978-02-14	Brine treatment for trace metal removal
CA1083272A (fr)	1980-08-05	Traitement d'un element aqueux contenant du mercure
JP2020032382A (ja)	2020-03-05	重金属含有廃水の処理方法
US4012297A (en)	1977-03-15	Mercury recovery and recycle process
US1886267A (en)	1932-11-01	Treating sewage
JP3921695B2 (ja)	2007-05-30	マンガン含有排水の処理方法
NO154010B (no)	1986-03-24	Fremgangsmaate for aa fjerne kvikksoelv fra surt industrielt avloepsvann.
SU1724595A1 (ru)	1992-04-07	Способ очистки сточных вод от т желых металлов
US20220017390A1 (en)	2022-01-20	Method for the precipitation of arsenic and heavy metals from acidic process water
JPH0122830B2 (fr)	1989-04-27