CA1084710A - Methode de fabrication du verre a base temperature - Google Patents

Methode de fabrication du verre a base temperature

Info

Publication number: CA1084710A
Authority: CA; Canada
Prior art keywords: glass; solution; hydrosilicate; cations; exchange
Prior art date: 1975-06-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA250,626A

Other languages

English (en)

Inventor

Helmuth E. Meissner

Stanley D. Stookey

Robert D. Shoup

Joseph E. Pierson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Corning Glass Works

Original Assignee

Corning Glass Works

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-06-04

Filing date

1976-04-21

Publication date

1980-09-02

1976-04-21 Application filed by Corning Glass Works filed Critical Corning Glass Works

1980-09-02 Application granted granted Critical

1980-09-02 Publication of CA1084710A publication Critical patent/CA1084710A/fr

Status Expired legal-status Critical Current

Links

239000011521 glass Substances 0.000 title claims abstract description 140
238000004519 manufacturing process Methods 0.000 title claims abstract description 10
239000000243 solution Substances 0.000 claims abstract description 101
238000006243 chemical reaction Methods 0.000 claims abstract description 62
150000001768 cations Chemical class 0.000 claims abstract description 59
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
239000007864 aqueous solution Substances 0.000 claims abstract description 38
238000005342 ion exchange Methods 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 30
239000000203 mixture Substances 0.000 claims abstract description 30
239000011734 sodium Substances 0.000 claims abstract description 27
238000001179 sorption measurement Methods 0.000 claims abstract description 19
229910052751 metal Inorganic materials 0.000 claims abstract description 17
239000002184 metal Substances 0.000 claims abstract description 17
229910001414 potassium ion Inorganic materials 0.000 claims abstract description 17
229910001415 sodium ion Inorganic materials 0.000 claims abstract description 17
229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 13
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 12
239000013626 chemical specie Substances 0.000 claims abstract description 12
229910052708 sodium Inorganic materials 0.000 claims abstract description 11
150000001450 anions Chemical class 0.000 claims abstract description 10
239000011148 porous material Substances 0.000 claims abstract description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 107
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 54
239000000377 silicon dioxide Substances 0.000 claims description 48
238000000576 coating method Methods 0.000 claims description 27
239000011248 coating agent Substances 0.000 claims description 26
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 25
235000012239 silicon dioxide Nutrition 0.000 claims description 23
229910052681 coesite Inorganic materials 0.000 claims description 22
229910052906 cristobalite Inorganic materials 0.000 claims description 22
229910052682 stishovite Inorganic materials 0.000 claims description 22
229910052905 tridymite Inorganic materials 0.000 claims description 22
150000003839 salts Chemical class 0.000 claims description 14
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 11
239000004115 Sodium Silicate Substances 0.000 claims description 11
229910021529 ammonia Inorganic materials 0.000 claims description 11
239000000908 ammonium hydroxide Substances 0.000 claims description 11
150000003863 ammonium salts Chemical class 0.000 claims description 11
150000001735 carboxylic acids Chemical class 0.000 claims description 11
229910052911 sodium silicate Inorganic materials 0.000 claims description 11
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
238000001035 drying Methods 0.000 claims description 10
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims description 10
239000005368 silicate glass Substances 0.000 claims description 10
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 10
-1 AS2O3 Chemical compound 0.000 claims description 8
GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims description 8
ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 8
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
229910019142 PO4 Inorganic materials 0.000 claims description 7
239000004111 Potassium silicate Substances 0.000 claims description 7
235000021317 phosphate Nutrition 0.000 claims description 7
229910052913 potassium silicate Inorganic materials 0.000 claims description 7
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 7
235000019353 potassium silicate Nutrition 0.000 claims description 7
239000012266 salt solution Substances 0.000 claims description 7
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
238000007710 freezing Methods 0.000 claims description 6
230000008014 freezing Effects 0.000 claims description 6
229910044991 metal oxide Inorganic materials 0.000 claims description 6
150000004706 metal oxides Chemical class 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
229910011255 B2O3 Inorganic materials 0.000 claims description 5
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 5
150000004645 aluminates Chemical class 0.000 claims description 5
GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 5
150000001642 boronic acid derivatives Chemical class 0.000 claims description 5
SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 5
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 5
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 5
150000004820 halides Chemical class 0.000 claims description 5
ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 claims description 5
HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 claims description 5
150000002825 nitriles Chemical class 0.000 claims description 5
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 5
125000005402 stannate group Chemical group 0.000 claims description 5
239000000758 substrate Substances 0.000 claims description 5
150000003568 thioethers Chemical class 0.000 claims description 5
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 4
LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
239000011261 inert gas Substances 0.000 claims description 4
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 4
239000011701 zinc Substances 0.000 claims description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 3
239000003086 colorant Substances 0.000 claims description 3
239000011133 lead Substances 0.000 claims description 3
YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
229920000642 polymer Polymers 0.000 claims description 3
IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 3
239000000725 suspension Substances 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
229930040373 Paraformaldehyde Natural products 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 2
229940015043 glyoxal Drugs 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
229910052746 lanthanum Inorganic materials 0.000 claims description 2
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
229920002866 paraformaldehyde Polymers 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
230000000379 polymerizing effect Effects 0.000 claims description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims 2
229910052593 corundum Inorganic materials 0.000 claims 2
239000011368 organic material Substances 0.000 claims 2
229910001845 yogo sapphire Inorganic materials 0.000 claims 2
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 1
229910001868 water Inorganic materials 0.000 abstract description 46
150000002500 ions Chemical class 0.000 abstract description 39
239000000126 substance Substances 0.000 abstract description 14
239000003513 alkali Substances 0.000 abstract description 13
230000007935 neutral effect Effects 0.000 abstract description 7
230000008569 process Effects 0.000 abstract description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
229910000272 alkali metal oxide Inorganic materials 0.000 abstract description 2
230000004075 alteration Effects 0.000 abstract description 2
150000001412 amines Chemical class 0.000 abstract description 2
229910052700 potassium Inorganic materials 0.000 abstract description 2
239000011591 potassium Substances 0.000 abstract description 2
230000003292 diminished effect Effects 0.000 abstract 1
239000005373 porous glass Substances 0.000 abstract 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 13
241000894007 species Species 0.000 description 12
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
239000010949 copper Substances 0.000 description 9
230000018044 dehydration Effects 0.000 description 9
238000006297 dehydration reaction Methods 0.000 description 9
239000000047 product Substances 0.000 description 9
229910001413 alkali metal ion Inorganic materials 0.000 description 8
239000000463 material Substances 0.000 description 8
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
238000004458 analytical method Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
238000004090 dissolution Methods 0.000 description 6
238000007654 immersion Methods 0.000 description 6
239000012467 final product Substances 0.000 description 5
230000000717 retained effect Effects 0.000 description 5
229910017974 NH40H Inorganic materials 0.000 description 4
239000012298 atmosphere Substances 0.000 description 4
239000008187 granular material Substances 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
239000007858 starting material Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000003637 basic solution Substances 0.000 description 3
239000011575 calcium Substances 0.000 description 3
238000005341 cation exchange Methods 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000000835 fiber Substances 0.000 description 3
238000010304 firing Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000002386 leaching Methods 0.000 description 3
238000000465 moulding Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
229960005419 nitrogen Drugs 0.000 description 3
230000036961 partial effect Effects 0.000 description 3
239000002245 particle Substances 0.000 description 3
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
229920000178 Acrylic resin Polymers 0.000 description 2
239000004925 Acrylic resin Substances 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
229910003849 O-Si Inorganic materials 0.000 description 2
229910003872 O—Si Inorganic materials 0.000 description 2
229910020175 SiOH Inorganic materials 0.000 description 2
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
239000004809 Teflon Substances 0.000 description 2
229920006362 Teflon® Polymers 0.000 description 2
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
150000001242 acetic acid derivatives Chemical class 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003929 acidic solution Substances 0.000 description 2
238000007792 addition Methods 0.000 description 2
238000007605 air drying Methods 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
235000012501 ammonium carbonate Nutrition 0.000 description 2
235000019270 ammonium chloride Nutrition 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
238000007596 consolidation process Methods 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
239000004744 fabric Substances 0.000 description 2
230000002427 irreversible effect Effects 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
239000002609 medium Substances 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
239000004033 plastic Substances 0.000 description 2
238000002459 porosimetry Methods 0.000 description 2
239000010453 quartz Substances 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
229910001369 Brass Inorganic materials 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241001269524 Dura Species 0.000 description 1
101100400378 Mus musculus Marveld2 gene Proteins 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
229910010066 TiC14 Inorganic materials 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000010951 brass Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
229910001634 calcium fluoride Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000005350 fused silica glass Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
230000000887 hydrating effect Effects 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
JCYWCSGERIELPG-UHFFFAOYSA-N imes Chemical class CC1=CC(C)=CC(C)=C1N1C=CN(C=2C(=CC(C)=CC=2C)C)[C]1 JCYWCSGERIELPG-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000012500 ion exchange media Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000010410 layer Substances 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
125000005372 silanol group Chemical group 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000010959 steel Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
229960001124 trientine Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/06—Glass compositions containing silica with more than 90% silica by weight, e.g. quartz
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/006—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform an exchange of the type Xn+ ----> nH+
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C03C2201/20—Doped silica-based glasses containing non-metals other than boron or halide
- C03C2201/23—Doped silica-based glasses containing non-metals other than boron or halide containing hydroxyl groups
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C03C2201/30—Doped silica-based glasses containing metals
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C03C2201/30—Doped silica-based glasses containing metals
- C03C2201/32—Doped silica-based glasses containing metals containing aluminium
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C03C2201/30—Doped silica-based glasses containing metals
- C03C2201/50—Doped silica-based glasses containing metals containing alkali metals
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
- C03C2201/06—Doped silica-based glasses
- C03C2201/30—Doped silica-based glasses containing metals
- C03C2201/54—Doped silica-based glasses containing metals containing beryllium, magnesium or alkaline earth metals
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2203/00—Production processes
- C03C2203/50—After-treatment

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Glass Compositions (AREA)
Surface Treatment Of Glass (AREA)
Glass Melting And Manufacturing (AREA)

CA250,626A 1975-06-04 1976-04-21 Methode de fabrication du verre a base temperature Expired CA1084710A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US58360675A	1975-06-04	1975-06-04
US583,606		1990-09-17

Publications (1)

Publication Number	Publication Date
CA1084710A true CA1084710A (fr)	1980-09-02

Family

ID=24333806

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA250,626A Expired CA1084710A (fr)	1975-06-04	1976-04-21	Methode de fabrication du verre a base temperature

Country Status (6)

Country	Link
JP (1)	JPS51148715A (fr)
CA (1)	CA1084710A (fr)
DE (1)	DE2624447A1 (fr)
FR (1)	FR2330656A1 (fr)
GB (1)	GB1525873A (fr)
NL (1)	NL7606016A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5722127A (en) *	1980-07-15	1982-02-05	Hitachi Ltd	Production of optical glass
WO2016085905A1 (fr) *	2014-11-26	2016-06-02	Corning Incorporated	Verre renforcé, articles en vitrocéramique et céramique et leurs procédés de fabrication par échange d'ions sous pression
CN116715436B (zh) *	2023-08-07	2023-11-24	山东天旭特种玻璃有限公司	一种太阳能用超白玻璃及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3498802A (en)	1967-04-13	1970-03-03	Corning Glass Works	Steam treatment process to produce thermoplastic materials and hydraulic cements
US3498803A (en)	1967-04-13	1970-03-03	Corning Glass Works	Glass or glass-ceramic steam treatment method and article
US3653864A (en) *	1969-03-17	1972-04-04	Corning Glass Works	Dealkalization of glass surfaces
US3827893A (en)	1970-06-12	1974-08-06	Corning Glass Works	Silicate bodies
US3782982A (en)	1970-06-12	1974-01-01	Corning Glass Works	Products prepared from soluble silicate solutions
US3912481A (en) *	1974-02-25	1975-10-14	Corning Glass Works	Method for making alkali metal silicate thermoplastic materials

1976
- 1976-04-21 CA CA250,626A patent/CA1084710A/fr not_active Expired
- 1976-06-01 DE DE19762624447 patent/DE2624447A1/de not_active Withdrawn
- 1976-06-02 JP JP6445576A patent/JPS51148715A/ja active Pending
- 1976-06-03 GB GB2294976A patent/GB1525873A/en not_active Expired
- 1976-06-03 NL NL7606016A patent/NL7606016A/xx not_active Application Discontinuation
- 1976-06-03 FR FR7616803A patent/FR2330656A1/fr active Granted

Also Published As

Publication number	Publication date
JPS51148715A (en)	1976-12-21
NL7606016A (nl)	1976-12-07
FR2330656B1 (fr)	1980-12-12
GB1525873A (en)	1978-09-20
FR2330656A1 (fr)	1977-06-03
DE2624447A1 (de)	1976-12-16

Legal Events

Date	Code	Title	Description
1997-09-02	MKEX	Expiry

Publication	Publication Date	Title
CA1057955A (fr)	1979-07-10	Hydratation de verres de silice dans des solutions aqueuses
JP2871440B2 (ja)	1999-03-17	化学強化ガラスの製造方法
US3843341A (en)	1974-10-22	Method of making thermally stable and crush resistant microporous glass catalyst supports
US3653864A (en)	1972-04-04	Dealkalization of glass surfaces
US3811853A (en)	1974-05-21	Degradable glass suitable for containers
DE3607404C2 (fr)	1988-07-07
US4846868A (en)	1989-07-11	Chemically strengthened glass article and method of producing same
US3607172A (en)	1971-09-21	Tripotassium phosphate treatment for strengthening glass
US3912481A (en)	1975-10-14	Method for making alkali metal silicate thermoplastic materials
US2461841A (en)	1949-02-15	Method of making fibrous glass articles
JPH08511232A (ja)	1996-11-26	多孔質の炭素含有材料の酸化防止方法及びそれによって得られる材料
US4379111A (en)	1983-04-05	Method for producing chromium oxide coated refractory fibers
US3498803A (en)	1970-03-03	Glass or glass-ceramic steam treatment method and article
CN101428962B (zh)	2011-07-20	一种超薄锂铝硅酸盐玻璃的增强方法
Bartholomew	1982	Water in glass
US3485702A (en)	1969-12-23	Mechanical strengthening of glass by ion exchange
US3232782A (en)	1966-02-01	High temperature resistant vitreous material and method of producing same
US3773489A (en)	1973-11-20	Chemically strengthened glass
CA1257299A (fr)	1989-07-11	Verre poreux durable au contact avec les agents chimiques et sa fabrication
US20070212534A1 (en)	2007-09-13	Article With Silica-Based Film and Process for Producing the Same
JPH10158037A (ja)	1998-06-16	抗菌性ガラス及びその製造方法
US3560177A (en)	1971-02-02	Manufacture of glass fibers
US2455719A (en)	1948-12-07	Glass manufacture
US4273832A (en)	1981-06-16	Glass article strengthened by ion exchange substitution
US4312911A (en)	1982-01-26	Chromium oxide coated refractory fibers