CA1086293A - Methode de preparation de ferrierite synthetique - Google Patents

Methode de preparation de ferrierite synthetique

Info

Publication number: CA1086293A
Authority: CA; Canada
Prior art keywords: ferrierite; group; reaction mixture; cations; lithium
Prior art date: 1976-06-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA280,653A

Other languages

English (en)

Inventor

David E. W. Vaughan

Grant C. Edwards

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-06-25

Filing date

1977-06-16

Publication date

1980-09-23

1976-06-25 Priority claimed from US05/699,916 external-priority patent/US4088739A/en

1977-06-16 Application filed by WR Grace and Co filed Critical WR Grace and Co

1980-09-23 Application granted granted Critical

1980-09-23 Publication of CA1086293A publication Critical patent/CA1086293A/fr

Status Expired legal-status Critical Current

Links

229910001657 ferrierite group Inorganic materials 0.000 title claims abstract description 88
238000004519 manufacturing process Methods 0.000 title claims abstract description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 73
239000000377 silicon dioxide Substances 0.000 claims abstract description 33
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 23
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 20
229910052681 coesite Inorganic materials 0.000 claims abstract description 19
229910052906 cristobalite Inorganic materials 0.000 claims abstract description 19
229910052682 stishovite Inorganic materials 0.000 claims abstract description 19
229910052905 tridymite Inorganic materials 0.000 claims abstract description 19
FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 18
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims abstract description 18
239000011541 reaction mixture Substances 0.000 claims abstract description 16
150000001768 cations Chemical class 0.000 claims abstract description 10
230000001737 promoting effect Effects 0.000 claims abstract description 6
229910052593 corundum Inorganic materials 0.000 claims abstract description 5
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 5
229910052744 lithium Inorganic materials 0.000 claims description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
229910001868 water Inorganic materials 0.000 claims description 23
238000000034 method Methods 0.000 claims description 19
229910052712 strontium Inorganic materials 0.000 claims description 17
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 17
238000006243 chemical reaction Methods 0.000 claims description 15
239000011734 sodium Substances 0.000 claims description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
229910052708 sodium Inorganic materials 0.000 claims description 11
229910052700 potassium Inorganic materials 0.000 claims description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
239000011591 potassium Substances 0.000 claims description 7
-1 lithium cations Chemical class 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
239000011575 calcium Substances 0.000 claims description 5
150000004679 hydroxides Chemical class 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
239000011777 magnesium Substances 0.000 claims description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
229910052788 barium Inorganic materials 0.000 claims description 4
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
229910052792 caesium Inorganic materials 0.000 claims description 4
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 4
229910052791 calcium Inorganic materials 0.000 claims description 4
229910052701 rubidium Inorganic materials 0.000 claims description 4
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 3
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 6
229910000272 alkali metal oxide Inorganic materials 0.000 abstract description 6
150000003839 salts Chemical class 0.000 abstract description 4
239000010457 zeolite Substances 0.000 abstract description 3
230000003197 catalytic effect Effects 0.000 abstract description 2
230000000737 periodic effect Effects 0.000 abstract description 2
KOPBYBDAPCDYFK-UHFFFAOYSA-N Cs2O Inorganic materials [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 abstract 1
238000010521 absorption reaction Methods 0.000 abstract 1
AKUNKIJLSDQFLS-UHFFFAOYSA-M dicesium;hydroxide Chemical compound [OH-].[Cs+].[Cs+] AKUNKIJLSDQFLS-UHFFFAOYSA-M 0.000 abstract 1
229910003002 lithium salt Inorganic materials 0.000 abstract 1
159000000002 lithium salts Chemical class 0.000 abstract 1
NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 abstract 1
229910001953 rubidium(I) oxide Inorganic materials 0.000 abstract 1
239000002002 slurry Substances 0.000 description 23
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 17
239000000047 product Substances 0.000 description 17
239000000203 mixture Substances 0.000 description 15
238000003786 synthesis reaction Methods 0.000 description 13
239000000843 powder Substances 0.000 description 12
230000015572 biosynthetic process Effects 0.000 description 11
239000000126 substance Substances 0.000 description 10
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
239000000376 reactant Substances 0.000 description 8
238000004458 analytical method Methods 0.000 description 7
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 7
229910000831 Steel Inorganic materials 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000010959 steel Substances 0.000 description 6
239000002253 acid Substances 0.000 description 5
GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 5
238000002156 mixing Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
229960000443 hydrochloric acid Drugs 0.000 description 4
235000011167 hydrochloric acid Nutrition 0.000 description 4
229910013596 LiOH—H2O Inorganic materials 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000000306 component Substances 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 2
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
YSZKOFNTXPLTCU-UHFFFAOYSA-N barium lithium Chemical compound [Li].[Ba] YSZKOFNTXPLTCU-UHFFFAOYSA-N 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 2
229940040692 lithium hydroxide monohydrate Drugs 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000002243 precursor Substances 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
241001111950 Sonora Species 0.000 description 1
229910003514 Sr(OH) Inorganic materials 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
MSJIBCNUPFPONA-UHFFFAOYSA-N [K].[Sr] Chemical compound [K].[Sr] MSJIBCNUPFPONA-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
229910001863 barium hydroxide Inorganic materials 0.000 description 1
ZUDYPQRUOYEARG-UHFFFAOYSA-L barium(2+);dihydroxide;octahydrate Chemical compound O.O.O.O.O.O.O.O.[OH-].[OH-].[Ba+2] ZUDYPQRUOYEARG-UHFFFAOYSA-L 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
229910001570 bauxite Inorganic materials 0.000 description 1
239000000404 calcium aluminium silicate Substances 0.000 description 1
235000012215 calcium aluminium silicate Nutrition 0.000 description 1
229940078583 calcium aluminosilicate Drugs 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000002050 diffraction method Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000010433 feldspar Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
150000002641 lithium Chemical class 0.000 description 1
229940006487 lithium cation Drugs 0.000 description 1
GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
239000008262 pumice Substances 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000012066 reaction slurry Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA280,653A 1976-06-25 1977-06-16 Methode de preparation de ferrierite synthetique Expired CA1086293A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US699,916		1976-06-25
US05/699,916 US4088739A (en)	1974-10-16	1976-06-25	Process for preparing synthetic ferrierite

Publications (1)

Publication Number	Publication Date
CA1086293A true CA1086293A (fr)	1980-09-23

Family

ID=24811469

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA280,653A Expired CA1086293A (fr)	1976-06-25	1977-06-16	Methode de preparation de ferrierite synthetique

Country Status (1)

Country	Link
CA (1)	CA1086293A (fr)

1977
- 1977-06-16 CA CA280,653A patent/CA1086293A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1997-09-23	MKEX	Expiry

Publication	Publication Date	Title
US4088739A (en)	1978-05-09	Process for preparing synthetic ferrierite
US3314752A (en)	1967-04-18	Synthetic zeolite
Shigemoto et al.	1995	Characterization of Na-X, Na-A, and coal fly ash zeolites and their amorphous precursors by IR, MAS NMR and XPS
US4900528A (en)	1990-02-13	Zeolite synthesis
CA2081698C (fr)	1999-12-21	Synthese de la zeolite beta utilisant la diethanolamine dans le melange reactionnel
US4705674A (en)	1987-11-10	Synthesis of zeolite EU-13 from a reaction mixture containing tetramethylammonium compound
GB961215A (en)	1964-06-17	Process for making crystalline zeolites
CA1269088A (fr)	1990-05-15	Zeolite ayant une structure de type paulingite (ecr-18) et methode de preparation
Selbin et al.	1961	Preparation of gallium-containing molecular sieves
US4581212A (en)	1986-04-08	Zeolite EU-7
GB1580918A (en)	1980-12-10	Method of producing zeolitic aluminium silicates having a low iron content
JPH0153206B2 (fr)	1989-11-13
US4581211A (en)	1986-04-08	Zeolite EU-12
US3720753A (en)	1973-03-13	Method for preparing a small pore synthetic zeolite
US5192520A (en)	1993-03-09	Synthesis of aluminosilicate zeolites of faujasite structure
CA1336330C (fr)	1995-07-18	L'ecr-18, methode pour sa preparation et ses utilisations pour la sorption et la separation
GB902150A (en)	1962-07-25	Catalytic production of ethylene glycol
CA1086293A (fr)	1980-09-23	Methode de preparation de ferrierite synthetique
JPH0228523B2 (fr)	1990-06-25
GB905194A (en)	1962-09-05	Crystalline zeolite
CA1196902A (fr)	1985-11-19	Zeolite lz-133
US4960578A (en)	1990-10-02	Zeolite ECR-10
US3674425A (en)	1972-07-04	Process for preparing a synthetic crystalline zeolite
US5455020A (en)	1995-10-03	Gallium silicate having 12-ring pores (ECR-34) and a method for its preparation
JP4123546B2 (ja)	2008-07-23	ゼオライトｏｕ−１およびその合成方法