CA1087344A - Produits photo-stables a base de polyolefines - Google Patents

Produits photo-stables a base de polyolefines

Info

Publication number: CA1087344A
Authority: CA; Canada
Prior art keywords: hydroxy; light; composition; butyl; benzotriazole
Prior art date: 1977-07-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA304,827A

Other languages

English (en)

Inventor

Joseph A. Stretanski

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Wyeth Holdings LLC

Original Assignee

American Cyanamid Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-18

Filing date

1978-06-06

Publication date

1980-10-07

1978-06-06 Application filed by American Cyanamid Co filed Critical American Cyanamid Co

1980-10-07 Application granted granted Critical

1980-10-07 Publication of CA1087344A publication Critical patent/CA1087344A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 20
229920000098 polyolefin Polymers 0.000 title claims abstract description 19
-1 alkenyl ester Chemical class 0.000 claims abstract description 24
239000012964 benzotriazole Substances 0.000 claims abstract description 8
BJFLSHMHTPAZHO-UHFFFAOYSA-N benzotriazole Chemical compound [CH]1C=CC=C2N=NN=C21 BJFLSHMHTPAZHO-UHFFFAOYSA-N 0.000 claims abstract description 7
125000000217 alkyl group Chemical group 0.000 claims abstract description 6
150000001875 compounds Chemical class 0.000 claims description 19
239000004611 light stabiliser Substances 0.000 claims description 14
239000004743 Polypropylene Substances 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 12
229920001155 polypropylene Polymers 0.000 claims description 7
230000002542 deteriorative effect Effects 0.000 claims description 4
QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 4
TUKWPCXMNZAXLO-UHFFFAOYSA-N ethyl 2-nonylsulfanyl-4-oxo-1h-pyrimidine-6-carboxylate Chemical compound CCCCCCCCCSC1=NC(=O)C=C(C(=O)OCC)N1 TUKWPCXMNZAXLO-UHFFFAOYSA-N 0.000 claims description 3
NZYMWGXNIUZYRC-UHFFFAOYSA-N hexadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NZYMWGXNIUZYRC-UHFFFAOYSA-N 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 2
230000006866 deterioration Effects 0.000 claims description 2
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
239000005977 Ethylene Substances 0.000 claims 1
150000001336 alkenes Chemical class 0.000 claims 1
125000003545 alkoxy group Chemical group 0.000 claims 1
229920005606 polypropylene copolymer Polymers 0.000 claims 1
230000000087 stabilizing effect Effects 0.000 claims 1
229940090248 4-hydroxybenzoic acid Drugs 0.000 abstract description 2
239000000654 additive Substances 0.000 description 9
230000000996 additive effect Effects 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
238000000034 method Methods 0.000 description 4
230000015556 catabolic process Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
XRCGPZWJUXJKJF-UHFFFAOYSA-N (2-hydroxy-4-octoxyphenyl)-(2-hydroxyphenyl)methanone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1O XRCGPZWJUXJKJF-UHFFFAOYSA-N 0.000 description 2
ZOXXRCPXCUJHQQ-UHFFFAOYSA-N (4-butoxy-2-hydroxyphenyl)-(2-hydroxyphenyl)methanone Chemical compound OC1=CC(OCCCC)=CC=C1C(=O)C1=CC=CC=C1O ZOXXRCPXCUJHQQ-UHFFFAOYSA-N 0.000 description 2
IADJBCIKCXGXDN-UHFFFAOYSA-N (4-butoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCC)=CC=C1C(=O)C1=CC=CC=C1 IADJBCIKCXGXDN-UHFFFAOYSA-N 0.000 description 2
ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 2
MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 2
XSDBAAZKJCBPRL-UHFFFAOYSA-N 2-(5-methoxybenzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound OC1=C(C=C(C=C1)C(C)(C)CC(C)(C)C)N1N=C2C(=N1)C=CC(=C2)OC XSDBAAZKJCBPRL-UHFFFAOYSA-N 0.000 description 2
MJFOVRMNLQNDDS-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dimethylphenol Chemical compound CC1=CC(C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MJFOVRMNLQNDDS-UHFFFAOYSA-N 0.000 description 2
WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 2
JDKRKMFUIYZYJP-UHFFFAOYSA-N 2-methylpropyl 4-hydroxy-3,5-bis(2,4,4-trimethylpentan-2-yl)benzoate Chemical compound C(C)(C)(CC(C)(C)C)C=1C=C(C(=O)OCC(C)C)C=C(C=1O)C(C)(C)CC(C)(C)C JDKRKMFUIYZYJP-UHFFFAOYSA-N 0.000 description 2
IEMHIOUNBGZEAG-UHFFFAOYSA-N 4-tert-butyl-2-(5-chlorobenzotriazol-2-yl)phenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=C(Cl)C=CC3=N2)=C1 IEMHIOUNBGZEAG-UHFFFAOYSA-N 0.000 description 2
UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 2
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
239000000835 fiber Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
JQSSXIRDGUMPNP-UHFFFAOYSA-N (4-decoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 JQSSXIRDGUMPNP-UHFFFAOYSA-N 0.000 description 1
RKVRWKDTXOIXNG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RKVRWKDTXOIXNG-UHFFFAOYSA-N 0.000 description 1
SYFIBOFYDHBYCD-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-pentylphenol Chemical compound CCCCCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 SYFIBOFYDHBYCD-UHFFFAOYSA-N 0.000 description 1
YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
REUNLTDKVSLTAY-UHFFFAOYSA-N CCCCC1(C(O)=O)CC=C(O)C=C1 Chemical compound CCCCC1(C(O)=O)CC=C(O)C=C1 REUNLTDKVSLTAY-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
229940024874 benzophenone Drugs 0.000 description 1
SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
RUKUZSIKORUWFQ-UHFFFAOYSA-N cyclohexyl 4-hydroxy-3,5-bis(2-methylbutan-2-yl)benzoate Chemical compound CCC(C)(C)C1=C(O)C(C(C)(C)CC)=CC(C(=O)OC2CCCCC2)=C1 RUKUZSIKORUWFQ-UHFFFAOYSA-N 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
ZFOZSYQWFYGERI-UHFFFAOYSA-N decyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 ZFOZSYQWFYGERI-UHFFFAOYSA-N 0.000 description 1
CARVOQIAEFKWRP-UHFFFAOYSA-N dodecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 CARVOQIAEFKWRP-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
229920001903 high density polyethylene Polymers 0.000 description 1
239000004700 high-density polyethylene Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
229940099514 low-density polyethylene Drugs 0.000 description 1
UBGPHZZYVGSNSW-UHFFFAOYSA-N methyl 4-hydroxy-3-methyl-5-propan-2-ylbenzoate Chemical compound COC(=O)C1=CC(C)=C(O)C(C(C)C)=C1 UBGPHZZYVGSNSW-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
RNVAPPWJCZTWQL-UHFFFAOYSA-N octadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 RNVAPPWJCZTWQL-UHFFFAOYSA-N 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
BRNTYBFVLCEIEJ-UHFFFAOYSA-N octadecyl 4-hydroxy-3,5-di(propan-2-yl)benzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)C)=C(O)C(C(C)C)=C1 BRNTYBFVLCEIEJ-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA304,827A 1977-07-18 1978-06-06 Produits photo-stables a base de polyolefines Expired CA1087344A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US81662277A	1977-07-18	1977-07-18
US816,622		1977-07-18

Publications (1)

Publication Number	Publication Date
CA1087344A true CA1087344A (fr)	1980-10-07

Family

ID=25221162

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA304,827A Expired CA1087344A (fr)	1977-07-18	1978-06-06	Produits photo-stables a base de polyolefines

Country Status (11)

Country	Link
JP (1)	JPS5421450A (fr)
AU (1)	AU3642678A (fr)
BE (1)	BE869003A (fr)
BR (1)	BR7804592A (fr)
CA (1)	CA1087344A (fr)
DE (1)	DE2828363A1 (fr)
FR (1)	FR2398089A1 (fr)
NL (1)	NL7806493A (fr)
PL (1)	PL208485A1 (fr)
SE (1)	SE7807906L (fr)
ZA (1)	ZA782930B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1161241A (fr) *	1980-09-18	1984-01-31	Paula A. Paolino	Antioxydant phenolique et stabilisateur combines pour l'emploi avec des matieres
JPS5959473U (ja) *	1982-10-13	1984-04-18	本田技研工業株式会社	車載用バツテリ装置
CA2038179A1 (fr) *	1990-03-26	1991-09-27	Donald Frederick Anderson	Stabilisation de microbiocides a base de phenoxarsine
JP3987632B2 (ja) *	1998-04-27	2007-10-10	株式会社Ａｄｅｋａ	自動車内外装材

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3681431A (en) *	1970-02-06	1972-08-01	Ciba Geigy Corp	N-OCTADECYL 3,5-DI-t-BUTYL-4-HYDROXYBENZOATE
US3658910A (en) *	1970-02-11	1972-04-25	Carlisle Chemical Works	Liquid 2-hydroxy-4-alkoxybenzophenones
CH527873A (de) *	1970-08-26	1972-09-15	Ciba Geigy Ag	Verwendung von 4-Hydroxy-benzoesäurearylestern als Lichtschutzmittel

1978
- 1978-05-22 ZA ZA00782930A patent/ZA782930B/xx unknown
- 1978-05-24 AU AU36426/78A patent/AU3642678A/en active Pending
- 1978-06-06 CA CA304,827A patent/CA1087344A/fr not_active Expired
- 1978-06-15 NL NL7806493A patent/NL7806493A/xx not_active Application Discontinuation
- 1978-06-28 DE DE19782828363 patent/DE2828363A1/de not_active Withdrawn
- 1978-07-14 BE BE189289A patent/BE869003A/fr unknown
- 1978-07-17 BR BR7804592A patent/BR7804592A/pt unknown
- 1978-07-17 JP JP8621678A patent/JPS5421450A/ja active Pending
- 1978-07-17 SE SE787807906A patent/SE7807906L/xx unknown
- 1978-07-17 PL PL20848578A patent/PL208485A1/xx unknown
- 1978-07-18 FR FR7821307A patent/FR2398089A1/fr not_active Withdrawn

Also Published As

Publication number	Publication date
ZA782930B (en)	1979-05-30
SE7807906L (sv)	1979-01-19
PL208485A1 (pl)	1979-03-26
NL7806493A (nl)	1979-01-22
AU3642678A (en)	1979-11-29
FR2398089A1 (fr)	1979-02-16
JPS5421450A (en)	1979-02-17
DE2828363A1 (de)	1979-02-08
BE869003A (fr)	1979-01-15
BR7804592A (pt)	1979-04-10

Legal Events

Date	Code	Title	Description
1997-10-07	MKEX	Expiry

Publication	Publication Date	Title
KR102459525B1 (ko)	2022-10-27	안정화제 조성물 및 uv 광 및 열적 열화로부터의 중합체 유기 물질의 보호를 위한 그의 사용 방법
US3230194A (en)	1966-01-18	2-(2'-hydroxy-5'-tertiary-octylphenyl)-benzotriazole and polyolefins stabilized therewith
US20020086924A1 (en)	2002-07-04	Stabilized gamma irradiated polyolefins
US4403053A (en)	1983-09-06	Stabilized olefin polymers
JPH07119318B2 (ja)	1995-12-20	安定剤組成物
CN105102511A (zh)	2015-11-25	树脂添加剂母料和配混有该树脂添加剂母料的聚烯烃树脂组合物
US3574156A (en)	1971-04-06	Antistatic resinous compositions
US4218511A (en)	1980-08-19	Self-extinguishing, expandable styrene polymers
CA1087344A (fr)	1980-10-07	Produits photo-stables a base de polyolefines
EP0538509B1 (fr)	1996-04-03	Composition de résine fortement antioxidante
EP0754722B1 (fr)	2000-05-03	Compositions pour la stabilisation de polymères synthétiques
US3900442A (en)	1975-08-19	Titanium dioxide pigmented polymer compositions with improved visible and ultraviolet light stability
US3639518A (en)	1972-02-01	Anti-static polymer compositions with discoloration suppressors
US3103501A (en)	1963-09-10	- olefins containing alkylidene-
US3431233A (en)	1969-03-04	Novel piperidine n-oxide polyolefin stabilizers
KR0163474B1 (ko)	1999-01-15	합성 중합체 안정화용 조성물
US3657114A (en)	1972-04-18	Ethylene polymers of improved glass, transparency & heat-sealability containing a zinc salt of a fatty acid
PT96290B (pt)	1998-06-30	Processo para a preparacao de composicoes termoplasticas com resistencia ao fogo melhorada contendo polimeros alcenilaromaticos
CA1124677A (fr)	1982-06-01	Polymeres de propylene traites par des rayonnements
US4240954A (en)	1980-12-23	Polymers stabilized against degradation by ultraviolet radiation
US3781242A (en)	1973-12-25	Light stabilized polypropylene containing a hindered phenol,a phosphite and a benzotriazole
US4370430A (en)	1983-01-25	Hindered amine light stabilizers for polymers
EP1652881B1 (fr)	2011-11-23	Composition de stabilisateur thermique pour polymères vinyliques halogénés
EP0165005B1 (fr)	1995-02-01	Procédé phytosanitaire par des pellicules à base de polymères stabilisés
US3359234A (en)	1967-12-19	Stabilized polyolefins containing a nickel alkanoate and a thio-bisphenol