CA1087546A - Production de chlore par echange ionique a faible tension de chlor-alcali - Google Patents

Production de chlore par echange ionique a faible tension de chlor-alcali

Info

Publication number: CA1087546A
Authority: CA; Canada
Prior art keywords: anode; cathode; membrane; solution; alkali
Prior art date: 1976-02-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA269,402A

Other languages

English (en)

Inventor

Robert B. Macmullin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Goodrich Corp

Original Assignee

BF Goodrich Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-02-05

Filing date

1977-01-10

Publication date

1980-10-14

1977-01-10 Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp

1980-10-14 Application granted granted Critical

1980-10-14 Publication of CA1087546A publication Critical patent/CA1087546A/fr

Status Expired legal-status Critical Current

Links

239000003513 alkali Substances 0.000 title claims abstract description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title abstract description 12
239000000460 chlorine Substances 0.000 title abstract description 10
229910052801 chlorine Inorganic materials 0.000 title abstract description 10
238000004519 manufacturing process Methods 0.000 title abstract description 4
238000005342 ion exchange Methods 0.000 title abstract description 3
239000012528 membrane Substances 0.000 claims abstract description 66
238000000034 method Methods 0.000 claims abstract description 42
239000003518 caustics Substances 0.000 claims abstract description 22
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 20
239000001257 hydrogen Substances 0.000 claims abstract description 16
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
238000005341 cation exchange Methods 0.000 claims abstract description 13
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 5
UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims abstract description 4
239000000243 solution Substances 0.000 claims description 51
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 28
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
229910052751 metal Inorganic materials 0.000 claims description 21
239000002184 metal Substances 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
239000011780 sodium chloride Substances 0.000 claims description 14
239000007868 Raney catalyst Substances 0.000 claims description 12
229910000564 Raney nickel Inorganic materials 0.000 claims description 12
238000003843 chloralkali process Methods 0.000 claims description 12
229910001514 alkali metal chloride Inorganic materials 0.000 claims description 11
239000000463 material Substances 0.000 claims description 10
229910052759 nickel Inorganic materials 0.000 claims description 7
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
238000009835 boiling Methods 0.000 claims description 4
239000010936 titanium Substances 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
239000011248 coating agent Substances 0.000 claims description 3
238000000576 coating method Methods 0.000 claims description 3
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 3
229910052707 ruthenium Inorganic materials 0.000 claims description 3
239000000203 mixture Substances 0.000 claims description 2
229920000642 polymer Polymers 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims 6
238000005868 electrolysis reaction Methods 0.000 claims 2
125000002091 cationic group Chemical group 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 10
229920000557 Nafion® Polymers 0.000 abstract description 3
229920005597 polymer membrane Polymers 0.000 abstract description 3
210000004027 cell Anatomy 0.000 description 25
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000010439 graphite Substances 0.000 description 5
229910002804 graphite Inorganic materials 0.000 description 5
229910052742 iron Inorganic materials 0.000 description 5
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
229910052753 mercury Inorganic materials 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
-1 hydroxyl ions Chemical class 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
239000010425 asbestos Substances 0.000 description 3
239000012267 brine Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000001103 potassium chloride Substances 0.000 description 3
235000011164 potassium chloride Nutrition 0.000 description 3
229910052895 riebeckite Inorganic materials 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
229910001413 alkali metal ion Inorganic materials 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910001415 sodium ion Inorganic materials 0.000 description 2
241000518994 Conta Species 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
101100412856 Mus musculus Rhod gene Proteins 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
101100242191 Tetraodon nigroviridis rho gene Proteins 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
238000005266 casting Methods 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
210000005056 cell body Anatomy 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000012612 commercial material Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000011109 contamination Methods 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
229940021013 electrolyte solution Drugs 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
239000007769 metal material Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
230000010287 polarization Effects 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical class [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000000523 sample Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
159000000008 strontium salts Chemical class 0.000 description 1
230000003319 supportive effect Effects 0.000 description 1
238000010408 sweeping Methods 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
239000011800 void material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

CA269,402A 1976-02-05 1977-01-10 Production de chlore par echange ionique a faible tension de chlor-alcali Expired CA1087546A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US65542976A	1976-02-05	1976-02-05
US655,429		1976-02-05

Publications (1)

Publication Number	Publication Date
CA1087546A true CA1087546A (fr)	1980-10-14

Family

ID=24628850

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA269,402A Expired CA1087546A (fr)	1976-02-05	1977-01-10	Production de chlore par echange ionique a faible tension de chlor-alcali

Country Status (4)

Country	Link
JP (1)	JPS52113398A (fr)
CA (1)	CA1087546A (fr)
DE (1)	DE2704213A1 (fr)
IT (1)	IT1075262B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4364815A (en)	1979-11-08	1982-12-21	Ppg Industries, Inc.	Solid polymer electrolyte chlor-alkali process and electrolytic cell
US4402809A (en) *	1981-09-03	1983-09-06	Ppg Industries, Inc.	Bipolar electrolyzer

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6015712B2 (ja) *	1977-11-11	1985-04-20	昭和電工株式会社	苛性ソ−ダ製造用陰極及びその製造法
DE2844496C2 (de) *	1977-12-09	1982-12-30	General Electric Co., Schenectady, N.Y.	Verfahren zum Herstellen von Halogen und Alkalimetallhydroxiden
US4240895A (en) *	1979-03-29	1980-12-23	Olin Corporation	Raney alloy coated cathode for chlor-alkali cells
USRE31410E (en) *	1979-03-29	1983-10-11	Olin Corporation	Raney alloy coated cathode for chlor-alkali cells
JPS55158283A (en) *	1979-05-24	1980-12-09	Asahi Glass Co Ltd	Manufacture of alkali hydroxide
JPS55161081A (en)	1979-06-01	1980-12-15	Asahi Glass Co Ltd	Electrolytic cell
JPS5723076A (en) *	1980-07-18	1982-02-06	Asahi Glass Co Ltd	Preparation of alkali hydroxide and chlorine
JPS5940231B2 (ja) *	1979-11-27	1984-09-28	旭硝子株式会社	水酸化アルカリの製造方法
JPS5693883A (en) *	1979-12-27	1981-07-29	Permelec Electrode Ltd	Electrolytic apparatus using solid polymer electrolyte diaphragm and preparation thereof
IN154740B (fr) *	1980-04-15	1984-12-15	Asahi Chemical Ind
JPS6016518B2 (ja) *	1980-07-31	1985-04-25	旭硝子株式会社	イオン交換膜電解槽
JPS605056Y2 (ja) *	1981-04-27	1985-02-15	株式会社新潟鐵工所	タイン装置
US4459188A (en) *	1982-09-13	1984-07-10	Texas Brine Corporation	Brine systems for chlor-alkali membrane cells
JP4582784B2 (ja) *	2004-06-22	2010-11-17	クロリンエンジニアズ株式会社	イオン交換膜電解方法

1977
- 1977-01-10 CA CA269,402A patent/CA1087546A/fr not_active Expired
- 1977-01-27 IT IT19704/77A patent/IT1075262B/it active
- 1977-02-02 DE DE19772704213 patent/DE2704213A1/de active Pending
- 1977-02-04 JP JP1086277A patent/JPS52113398A/ja active Pending

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4364815A (en)	1979-11-08	1982-12-21	Ppg Industries, Inc.	Solid polymer electrolyte chlor-alkali process and electrolytic cell
US4402809A (en) *	1981-09-03	1983-09-06	Ppg Industries, Inc.	Bipolar electrolyzer

Also Published As

Publication number	Publication date
IT1075262B (it)	1985-04-22
JPS52113398A (en)	1977-09-22
DE2704213A1 (de)	1977-08-11

Legal Events

Date	Code	Title	Description
1997-10-14	MKEX	Expiry

Publication	Publication Date	Title
US3976549A (en)	1976-08-24	Electrolysis method
US4025405A (en)	1977-05-24	Electrolytic production of high purity alkali metal hydroxide
RU2107752C1 (ru)	1998-03-27	Электролизер, способ получения раствора основания и раствора, содержащего кислоту, и способ получения раствора основания и раствора чистой кислоты
US4224121A (en)	1980-09-23	Production of halogens by electrolysis of alkali metal halides in an electrolysis cell having catalytic electrodes bonded to the surface of a solid polymer electrolyte membrane
CN110616438B (zh)	2021-09-28	一种电化学制备高纯电池级氢氧化锂的装置及其方法
US5084149A (en)	1992-01-28	Electrolytic process for producing chlorine dioxide
CA1153982A (fr)	1983-09-20	Production electrolytique d'hydrohalite de metal alcalin, et appareil utilise
RU97100560A (ru)	1999-02-10	Способ электролиза водных растворов хлористоводородной кислоты
US4451338A (en)	1984-05-29	Process for making a calcium/sodium ferrate adduct by the electrochemical formation of sodium ferrate
SE453602B (sv)	1988-02-15	Forfarande for framstellning av klor och alkalimetallhydroxid
US4248680A (en)	1981-02-03	Electrolytic process and apparatus
US4364815A (en)	1982-12-21	Solid polymer electrolyte chlor-alkali process and electrolytic cell
US4578159A (en)	1986-03-25	Electrolysis of alkali metal chloride brine in catholyteless membrane cells employing an oxygen consuming cathode
DE2704213A1 (de)	1977-08-11	Chloralkali-elektrolyseverfahren
US4297194A (en)	1981-10-27	Electrolytic production of high purity alkali metal hydroxide
US4956061A (en)	1990-09-11	Production of halogens by electrolysis of alkali metal halides in an electrolysis cell having catalytic electrodes bonded to the surface of a solid polymer electrolyte membrane
US4772364A (en)	1988-09-20	Production of halogens by electrolysis of alkali metal halides in an electrolysis cell having catalytic electrodes bonded to the surface of a solid polymer electrolyte membrane
US4115218A (en)	1978-09-19	Method of electrolyzing brine
US4384937A (en)	1983-05-24	Production of chromic acid in a three-compartment cell
US3043757A (en)	1962-07-10	Electrolytic production of sodium chlorate
EP0267704A1 (fr)	1988-05-18	Elimination électrochimique de chrome de solutions de chlorate
CA1257560A (fr)	1989-07-18	Elimination electrochimique des hypochlorites dans les solutions de chlorate de cellules
US3785943A (en)	1974-01-15	Electrolysis of magnesium chloride
US4360412A (en)	1982-11-23	Treatment of permionic membrane
US4609443A (en)	1986-09-02	Procedure for the cathodic electrowinning of metals, with the corresponding acid generation, from its salt solution

CA1087546A - Production de chlore par echange ionique a faible tension de chlor-alcali - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=24628850

Family Applications (1)

Country Status (4)

Cited By (2)

Families Citing this family (14)

Cited By (2)

Also Published As

Similar Documents

Legal Events