CA1092082A - Catalyseur pour procede ameliore de conversion des hydrocarbures - Google Patents

Catalyseur pour procede ameliore de conversion des hydrocarbures

Info

Publication number: CA1092082A
Authority: CA; Canada
Prior art keywords: particles; discrete entities; alumina; weight; catalyst
Prior art date: 1977-10-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA310,858A

Other languages

English (en)

Inventor

John Mooi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Atlantic Richfield Co

Original Assignee

Atlantic Richfield Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-10-27

Filing date

1978-09-07

Publication date

1980-12-23

1978-09-07 Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co

1980-12-23 Application granted granted Critical

1980-12-23 Publication of CA1092082A publication Critical patent/CA1092082A/fr

Status Expired legal-status Critical Current

Links

150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 146
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 145
239000003054 catalyst Substances 0.000 title claims abstract description 141
238000006243 chemical reaction Methods 0.000 title claims abstract description 118
238000000034 method Methods 0.000 title claims abstract description 46
239000002245 particle Substances 0.000 claims abstract description 144
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 131
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 99
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 76
229910052751 metal Inorganic materials 0.000 claims abstract description 71
239000002184 metal Substances 0.000 claims abstract description 71
239000007787 solid Substances 0.000 claims abstract description 67
239000000203 mixture Substances 0.000 claims abstract description 56
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 38
229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 36
230000003647 oxidation Effects 0.000 claims abstract description 35
238000007254 oxidation reaction Methods 0.000 claims abstract description 35
230000001737 promoting effect Effects 0.000 claims abstract description 27
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 24
229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 12
239000001569 carbon dioxide Substances 0.000 claims abstract description 12
238000011069 regeneration method Methods 0.000 claims description 53
230000008929 regeneration Effects 0.000 claims description 49
238000005336 cracking Methods 0.000 claims description 47
239000000463 material Substances 0.000 claims description 40
229910000323 aluminium silicate Inorganic materials 0.000 claims description 34
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 31
239000011593 sulfur Substances 0.000 claims description 31
229910052717 sulfur Inorganic materials 0.000 claims description 31
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 26
229910052697 platinum Inorganic materials 0.000 claims description 20
230000003197 catalytic effect Effects 0.000 claims description 19
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 13
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
239000001301 oxygen Substances 0.000 claims description 11
229910052760 oxygen Inorganic materials 0.000 claims description 11
229910052763 palladium Inorganic materials 0.000 claims description 7
239000003575 carbonaceous material Substances 0.000 claims description 6
238000002485 combustion reaction Methods 0.000 claims description 6
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract description 24
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 23
230000001590 oxidative effect Effects 0.000 abstract description 5
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 36
239000007789 gas Substances 0.000 description 26
-1 platinum group metals Chemical class 0.000 description 17
238000007323 disproportionation reaction Methods 0.000 description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
239000003921 oil Substances 0.000 description 12
239000000047 product Substances 0.000 description 12
239000000126 substance Substances 0.000 description 12
239000000017 hydrogel Substances 0.000 description 11
238000001035 drying Methods 0.000 description 10
238000001354 calcination Methods 0.000 description 9
239000002002 slurry Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
238000009835 boiling Methods 0.000 description 7
239000003546 flue gas Substances 0.000 description 7
239000012530 fluid Substances 0.000 description 7
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
238000004519 manufacturing process Methods 0.000 description 7
239000008096 xylene Substances 0.000 description 7
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
229910052741 iridium Inorganic materials 0.000 description 5
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 5
239000011159 matrix material Substances 0.000 description 5
230000000737 periodic effect Effects 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
239000011148 porous material Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
239000000395 magnesium oxide Substances 0.000 description 4
239000012071 phase Substances 0.000 description 4
238000001694 spray drying Methods 0.000 description 4
150000003738 xylenes Chemical class 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
230000029936 alkylation Effects 0.000 description 3
238000005804 alkylation reaction Methods 0.000 description 3
239000011959 amorphous silica alumina Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000001419 dependent effect Effects 0.000 description 3
238000006317 isomerization reaction Methods 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
150000005172 methylbenzenes Chemical class 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
238000012545 processing Methods 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000011734 sodium Substances 0.000 description 3
150000004684 trihydrates Chemical class 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
229910001593 boehmite Inorganic materials 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000004523 catalytic cracking Methods 0.000 description 2
239000003245 coal Substances 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
230000020335 dealkylation Effects 0.000 description 2
238000006900 dealkylation reaction Methods 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
239000008187 granular material Substances 0.000 description 2
230000005484 gravity Effects 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
150000002484 inorganic compounds Chemical class 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
150000004682 monohydrates Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 2
239000006187 pill Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical class CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
239000003079 shale oil Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000007921 spray Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
229910052815 sulfur oxide Inorganic materials 0.000 description 2
239000011275 tar sand Substances 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
KLFRPGNCEJNEKU-FDGPNNRMSA-L (z)-4-oxopent-2-en-2-olate;platinum(2+) Chemical compound [Pt+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O KLFRPGNCEJNEKU-FDGPNNRMSA-L 0.000 description 1
QUBBAXISAHIDNM-UHFFFAOYSA-N 1-ethyl-2,3-dimethylbenzene Chemical class CCC1=CC=CC(C)=C1C QUBBAXISAHIDNM-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
IXKUIJYACQJMBG-UHFFFAOYSA-P C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Rh](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Rh](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 IXKUIJYACQJMBG-UHFFFAOYSA-P 0.000 description 1
WAAOIKBSUAOJEH-UHFFFAOYSA-O C=1C=CC=CC=1P(C=1C=CC=CC=1)([Ru])C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)([Ru])C1=CC=CC=C1 WAAOIKBSUAOJEH-UHFFFAOYSA-O 0.000 description 1
NAUGROHREIQBKM-UHFFFAOYSA-M C[Pt](C)(C)Cl Chemical compound C[Pt](C)(C)Cl NAUGROHREIQBKM-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
JNJVARQLPFPYNT-UHFFFAOYSA-H Cl[Pt](Cl)(Cl)(Cl)(Cl)Cl.N Chemical compound Cl[Pt](Cl)(Cl)(Cl)(Cl)Cl.N JNJVARQLPFPYNT-UHFFFAOYSA-H 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
230000010718 Oxidation Activity Effects 0.000 description 1
229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
AQBOUNVXZQRXNP-UHFFFAOYSA-L azane;dichloropalladium Chemical compound N.N.N.N.Cl[Pd]Cl AQBOUNVXZQRXNP-UHFFFAOYSA-L 0.000 description 1
WIEZTXFTOIBIOC-UHFFFAOYSA-L azane;dichloropalladium Chemical compound N.N.Cl[Pd]Cl WIEZTXFTOIBIOC-UHFFFAOYSA-L 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
LDKSTCHEYCNPDS-UHFFFAOYSA-L carbon monoxide;dichloroplatinum Chemical compound O=C=[Pt](Cl)(Cl)=C=O LDKSTCHEYCNPDS-UHFFFAOYSA-L 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
239000007809 chemical reaction catalyst Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
239000011280 coal tar Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000000571 coke Substances 0.000 description 1
238000004891 communication Methods 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
239000000539 dimer Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
239000000499 gel Substances 0.000 description 1
229910001679 gibbsite Inorganic materials 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
239000004005 microsphere Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
238000005457 optimization Methods 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
239000012285 osmium tetroxide Substances 0.000 description 1
229910000489 osmium tetroxide Inorganic materials 0.000 description 1
YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
238000005325 percolation Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000001294 propane Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000010453 quartz Substances 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
GTCKPGDAPXUISX-UHFFFAOYSA-N ruthenium(3+);trinitrate Chemical compound [Ru+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GTCKPGDAPXUISX-UHFFFAOYSA-N 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
FZHCFNGSGGGXEH-UHFFFAOYSA-N ruthenocene Chemical compound [Ru+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 FZHCFNGSGGGXEH-UHFFFAOYSA-N 0.000 description 1
238000012216 screening Methods 0.000 description 1
238000005204 segregation Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
238000010555 transalkylation reaction Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
150000005199 trimethylbenzenes Chemical class 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA310,858A 1977-10-27 1978-09-07 Catalyseur pour procede ameliore de conversion des hydrocarbures Expired CA1092082A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US84604677A	1977-10-27	1977-10-27
US846,046		1977-10-27

Publications (1)

Publication Number	Publication Date
CA1092082A true CA1092082A (fr)	1980-12-23

Family

ID=25296793

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA310,858A Expired CA1092082A (fr)	1977-10-27	1978-09-07	Catalyseur pour procede ameliore de conversion des hydrocarbures

Country Status (5)

Country	Link
JP (1)	JPS5471093A (fr)
BR (1)	BR7807019A (fr)
CA (1)	CA1092082A (fr)
FR (1)	FR2407254A1 (fr)
GB (1)	GB2023639B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SE438449B (sv) *	1980-06-30	1985-04-22	Katalistiks International Bv	Krackningskatalysator for krackning av kolveten i en med fluidiserad katalysatorbedd arbetande reaktor
AU547232B2 (en) *	1980-07-29	1985-10-10	W.R. Grace & Co.-Conn.	Regeneration of cracking catalysts to effect a reduction the emission of sulphur oxides
DE3123521A1 (de) *	1981-06-13	1983-01-13	EC Erdölchemie GmbH, 5000 Köln	Rieselfaehige, katalytische mischungen
US4412914A (en) *	1981-08-10	1983-11-01	Ashland Oil, Inc.	Endothermic removal of coke deposited on sorbent materials during carbo-metallic oil conversion

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1593119B2 (de) *	1960-01-15	1973-04-05		Verfahren zur vergroesserung des co tief 2/co-verhaeltnisses des beim abbrennen kohlenstoffhaltiger ablagerungen auf katalysatoren entstehenden co tief 2/co-gemisches
CA1093050A (fr) *	1975-12-19	1981-01-06	Iacovos A. Vasalos	Craquage catalytique avec emission reduite de gaz nocifs
US4153534A (en) *	1975-12-19	1979-05-08	Standard Oil Company (Indiana)	Catalytic cracking with reduced emission of noxious gases
US4071436A (en) *	1976-03-11	1978-01-31	Chevron Research Company	Process for removing sulphur from a gas
CA1046484A (fr) *	1976-04-12	1979-01-16	Elroy M. Gladrow	Catalyseur de la conversion d'hydrocarbures, contenant un activeur de l'oxydation du co

1978
- 1978-09-07 CA CA310,858A patent/CA1092082A/fr not_active Expired
- 1978-09-18 GB GB7837200A patent/GB2023639B/en not_active Expired
- 1978-10-19 JP JP12905178A patent/JPS5471093A/ja active Pending
- 1978-10-25 BR BR7807019A patent/BR7807019A/pt unknown
- 1978-10-25 FR FR7830331A patent/FR2407254A1/fr active Pending

Also Published As

Publication number	Publication date
GB2023639B (en)	1982-07-28
BR7807019A (pt)	1979-05-15
GB2023639A (en)	1980-01-03
FR2407254A1 (fr)	1979-05-25
JPS5471093A (en)	1979-06-07

Legal Events

Date	Code	Title	Description
1997-12-23	MKEX	Expiry
2023-05-26	MKEX	Expiry	Effective date: 19971223

Publication	Publication Date	Title
US4472267A (en)	1984-09-18	Catalyst and process for conversion of hydrocarbons
US4469589A (en)	1984-09-04	Catalyst and process for conversion of hydrocarbons
US4758418A (en)	1988-07-19	Process for combusting solid sulfur-containing material
US4252636A (en)	1981-02-24	Catalyst and process for conversion of hydrocarbons
US4957892A (en)	1990-09-18	Process for combusting solid sulfur containing material
US4495305A (en)	1985-01-22	Catalyst for conversion of hydrocarbons
US4495304A (en)	1985-01-22	Catalyst for conversion of hydrocarbons
US4137151A (en)	1979-01-30	Hydrocarbon conversion with cracking catalyst having co-combustion promoters lanthanum and iron
US4735705A (en)	1988-04-05	Composition of matter and process useful for conversion of hydrocarbons
US4642178A (en)	1987-02-10	Process for conversion of hydrocarbons
EP0045170B1 (fr)	1988-02-03	Procédé de combustion de matière contenant du soufre; procédé de conversion d'hydrocarbures et une composition catalytique convenant dans ces procédés
JPH06210177A (ja)	1994-08-02	炭化水素転換用触媒組成物
MXPA02000373A (es)	2002-08-12	Produccion catalitica de olefinas ligeras a partir de alimentacion de nafta.
US4613428A (en)	1986-09-23	Hydrocarbon cracking process
US4919787A (en)	1990-04-24	Metal passivating agents
NO327150B1 (no)	2009-05-04	Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate.
CA1051411A (fr)	1979-03-27	Catalyseur de craquage et methode de craquage qui y fait appel
JPS6312115B2 (fr)	1988-03-17
US4316795A (en)	1982-02-23	Hydrocarbon conversion process with reduced sulfur oxide emissions
EP0263170A1 (fr)	1988-04-13	Composition de spinelle contenant des metaux de terre rare et du vanadium, et procede d'utilisation
US4883783A (en)	1989-11-28	Composition of matter for conversion of hydrocarbons
US4839026A (en)	1989-06-13	Catalytic cracking with reduced emissions of sulfur oxides
US4297244A (en)	1981-10-27	Catalyst and process for conversion of hydrocarbons
US4285806A (en)	1981-08-25	Catalyst and process for conversion of hydrocarbons
CA2179945C (fr)	2000-12-05	Procede de craquage catalytique