CA1092085A - Acides polycarboxyliques comme aides a l'extrusion des poudres de type silice-alumine - Google Patents

Acides polycarboxyliques comme aides a l'extrusion des poudres de type silice-alumine

Info

Publication number: CA1092085A
Authority: CA; Canada
Prior art keywords: silica; alumina; polycarboxylic acid; powder; extrusion
Prior art date: 1977-08-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA288,342A

Other languages

English (en)

Inventor

Gerald R. Feistel

Monica E. Choca

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ChampionX LLC

Original Assignee

Nalco Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-31

Filing date

1977-10-07

Publication date

1980-12-23

1977-10-07 Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co

1980-12-23 Application granted granted Critical

1980-12-23 Publication of CA1092085A publication Critical patent/CA1092085A/fr

Status Expired legal-status Critical Current

Links

238000001125 extrusion Methods 0.000 title claims abstract description 29
239000002253 acid Substances 0.000 title claims abstract description 24
150000007513 acids Chemical class 0.000 title abstract description 7
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 57
239000000843 powder Substances 0.000 claims abstract description 35
239000003054 catalyst Substances 0.000 claims abstract description 31
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
239000011148 porous material Substances 0.000 claims description 22
238000000034 method Methods 0.000 claims description 21
239000000463 material Substances 0.000 claims description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
230000008569 process Effects 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
238000001354 calcination Methods 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 8
229910052681 coesite Inorganic materials 0.000 claims description 4
229910052906 cristobalite Inorganic materials 0.000 claims description 4
230000003247 decreasing effect Effects 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
235000012239 silicon dioxide Nutrition 0.000 claims description 4
229910052682 stishovite Inorganic materials 0.000 claims description 4
229910052905 tridymite Inorganic materials 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 2
229940037003 alum Drugs 0.000 claims 1
208000030507 AIDS Diseases 0.000 abstract 1
230000000704 physical effect Effects 0.000 description 8
239000006187 pill Substances 0.000 description 8
230000003197 catalytic effect Effects 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
238000005504 petroleum refining Methods 0.000 description 3
239000000243 solution Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
-1 alpha alumina monohydrates Chemical class 0.000 description 2
238000005336 cracking Methods 0.000 description 2
238000007429 general method Methods 0.000 description 2
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
239000000203 mixture Substances 0.000 description 2
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000007670 refining Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
241000197727 Euscorpius alpha Species 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
CKQGJVKHBSPKST-UHFFFAOYSA-N [Ni].P#[Mo] Chemical compound [Ni].P#[Mo] CKQGJVKHBSPKST-UHFFFAOYSA-N 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229940024546 aluminum hydroxide gel Drugs 0.000 description 1
SMYKVLBUSSNXMV-UHFFFAOYSA-K aluminum;trihydroxide;hydrate Chemical compound O.[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-K 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000007324 demetalation reaction Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
150000007518 monoprotic acids Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
150000007519 polyprotic acids Polymers 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000003330 sebacic acids Chemical class 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
229960004029 silicic acid Drugs 0.000 description 1
229960001866 silicon dioxide Drugs 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/20—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by expressing the material, e.g. through sieves and fragmenting the extruded length
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Compositions Of Oxide Ceramics (AREA)

CA288,342A 1977-08-31 1977-10-07 Acides polycarboxyliques comme aides a l'extrusion des poudres de type silice-alumine Expired CA1092085A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US82954177A	1977-08-31	1977-08-31
US829,541		1977-08-31

Publications (1)

Publication Number	Publication Date
CA1092085A true CA1092085A (fr)	1980-12-23

Family

ID=25254813

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA288,342A Expired CA1092085A (fr)	1977-08-31	1977-10-07	Acides polycarboxyliques comme aides a l'extrusion des poudres de type silice-alumine

Country Status (6)

Country	Link
JP (1)	JPS5438289A (fr)
BE (1)	BE860947A (fr)
CA (1)	CA1092085A (fr)
DE (1)	DE2751269C3 (fr)
GB (1)	GB1549548A (fr)
NL (1)	NL7712703A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2935914A1 (de) *	1979-09-06	1981-04-02	Kali-Chemie Ag, 3000 Hannover	Verfahren zur herstellung von kugelfoermigen formkoerpern auf basis al(pfeil abwaerts)2(pfeil abwaerts)o(pfeil abwaerts)3(pfeil abwaerts) und/oder sio(pfeil abwaerts)2(pfeil abwaerts)
JP5690634B2 (ja) *	2011-03-31	2015-03-25	独立行政法人石油天然ガス・金属鉱物資源機構	水素化精製触媒及び炭化水素油の製造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3917808A (en) *	1972-10-16	1975-11-04	Continental Oil Co	Method for extruding alumina

1977
- 1977-10-07 CA CA288,342A patent/CA1092085A/fr not_active Expired
- 1977-10-31 GB GB4526777A patent/GB1549548A/en not_active Expired
- 1977-11-14 DE DE19772751269 patent/DE2751269C3/de not_active Expired
- 1977-11-17 NL NL7712703A patent/NL7712703A/xx not_active Application Discontinuation
- 1977-11-18 BE BE1008524A patent/BE860947A/fr not_active IP Right Cessation
- 1977-11-22 JP JP13953777A patent/JPS5438289A/ja active Granted

Also Published As

Publication number	Publication date
DE2751269C3 (de)	1981-09-03
DE2751269A1 (de)	1979-03-08
BE860947A (fr)	1978-05-18
GB1549548A (en)	1979-08-08
DE2751269B2 (de)	1980-07-10
JPS5723539B2 (fr)	1982-05-19
NL7712703A (nl)	1979-03-02
JPS5438289A (en)	1979-03-22

Legal Events

Date	Code	Title	Description
1997-12-23	MKEX	Expiry

Publication	Publication Date	Title
US4081406A (en)	1978-03-28	Preparation of catalysts of predetermined pore size distribution and pore volume
US4196102A (en)	1980-04-01	Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite
US6043187A (en)	2000-03-28	Catalyst for hydrotreating hydrocarbon feeds in a fixed bed reactor
US4172809A (en)	1979-10-30	Alumina, a method for its preparation and said alumina as carrier containing catalysts
US4341625A (en)	1982-07-27	Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst
US4568657A (en)	1986-02-04	Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same
US4107087A (en)	1978-08-15	Use of citric acid to make catalyst from catalyst fines
US4289653A (en)	1981-09-15	Comulled silica-alumina base denitrification catalyst
US4174301A (en)	1979-11-13	Polycarboxylic acids as extrusion aids for silica-aluminas
WO2001094012A1 (fr)	2001-12-13	Catalyseur et procede d'hydrodesulfuration
US4613427A (en)	1986-09-23	Process for the demetallization and hydroconversion of heavy crudes and residues using a natural clay catalyst
US4016108A (en)	1977-04-05	Preparation of catalysts of predetermined pore size distribution and pore volume
SA06270479B1 (ar)	2009-12-22	حفاز مدعم غير كروي وغير منتظم، وعملية للتحول المائي للأجزاء الزيتية الثقيلة
US4083808A (en)	1978-04-11	Desulfurization of residual petroleum oils and catalysts therefor
US3840477A (en)	1974-10-08	Hydrotreating catalyst
US4364857A (en)	1982-12-21	Fibrous clay mixtures
US4394302A (en)	1983-07-19	Hydrodesulfurization catalyst on lithium-containing support and method for its preparation
CA1183121A (fr)	1985-02-26	Catalyseur ultrastable d'hydrotraitement
US4132669A (en)	1979-01-02	Process for preparing phosphorous-alumina catalysts using polycarboxylic acids as extrusion aids
JP2001520567A (ja)	2001-10-30	低マクロ細孔率の残油転化触媒
US2984630A (en)	1961-05-16	Method for preparing an alumina catalyst base
US4145316A (en)	1979-03-20	Preparation of catalysts of predetermined pore size distribution and pore volume
US4179410A (en)	1979-12-18	Cobalt-molybdenum-alumina desulfurization catalyst
US4081405A (en)	1978-03-28	Preparation of catalysts of predetermined pore size distribution and pore volume
CA1092085A (fr)	1980-12-23	Acides polycarboxyliques comme aides a l'extrusion des poudres de type silice-alumine