CA1093641A - Electrode selectrice d'ions - Google Patents

Electrode selectrice d'ions

Info

Publication number: CA1093641A
Authority: CA; Canada
Prior art keywords: electrode; ion; layer; binder; membrane
Prior art date: 1976-05-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA276,918A

Other languages

English (en)

Inventor

Charles J. Battaglia

Jack C. Chang

Daniel S. Daniel

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-05-19

Filing date

1977-04-25

Publication date

1981-01-13

1977-04-25 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1980-05-27 Priority to CA000352785A priority Critical patent/CA1116696A/fr

1981-01-13 Application granted granted Critical

1981-01-13 Publication of CA1093641A publication Critical patent/CA1093641A/fr

Status Expired legal-status Critical Current

Links

239000012528 membrane Substances 0.000 claims abstract description 141
229910052751 metal Inorganic materials 0.000 claims abstract description 59
239000002184 metal Substances 0.000 claims abstract description 59
239000011230 binding agent Substances 0.000 claims abstract description 58
150000003839 salts Chemical class 0.000 claims abstract description 57
239000002904 solvent Substances 0.000 claims abstract description 57
230000002209 hydrophobic effect Effects 0.000 claims abstract description 31
150000002500 ions Chemical class 0.000 claims description 181
-1 poly(ethylene terephthalate) Polymers 0.000 claims description 57
239000000463 material Substances 0.000 claims description 35
229910052709 silver Inorganic materials 0.000 claims description 32
239000004332 silver Substances 0.000 claims description 32
239000003792 electrolyte Substances 0.000 claims description 28
239000004020 conductor Substances 0.000 claims description 26
239000004372 Polyvinyl alcohol Substances 0.000 claims description 23
239000008273 gelatin Substances 0.000 claims description 23
229920000159 gelatin Polymers 0.000 claims description 23
229920002451 polyvinyl alcohol Polymers 0.000 claims description 23
108010010803 Gelatin Proteins 0.000 claims description 22
235000019322 gelatine Nutrition 0.000 claims description 22
235000011852 gelatine desserts Nutrition 0.000 claims description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
FCFNRCROJUBPLU-DNDCDFAISA-N valinomycin Chemical group CC(C)[C@@H]1NC(=O)[C@H](C)OC(=O)[C@@H](C(C)C)NC(=O)[C@@H](C(C)C)OC(=O)[C@H](C(C)C)NC(=O)[C@H](C)OC(=O)[C@@H](C(C)C)NC(=O)[C@@H](C(C)C)OC(=O)[C@H](C(C)C)NC(=O)[C@H](C)OC(=O)[C@@H](C(C)C)NC(=O)[C@@H](C(C)C)OC1=O FCFNRCROJUBPLU-DNDCDFAISA-N 0.000 claims description 20
108010067973 Valinomycin Proteins 0.000 claims description 19
FCFNRCROJUBPLU-UHFFFAOYSA-N compound M126 Natural products CC(C)C1NC(=O)C(C)OC(=O)C(C(C)C)NC(=O)C(C(C)C)OC(=O)C(C(C)C)NC(=O)C(C)OC(=O)C(C(C)C)NC(=O)C(C(C)C)OC(=O)C(C(C)C)NC(=O)C(C)OC(=O)C(C(C)C)NC(=O)C(C(C)C)OC1=O FCFNRCROJUBPLU-UHFFFAOYSA-N 0.000 claims description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
239000007787 solid Substances 0.000 claims description 18
229910052799 carbon Inorganic materials 0.000 claims description 17
238000004458 analytical method Methods 0.000 claims description 16
230000003647 oxidation Effects 0.000 claims description 16
238000007254 oxidation reaction Methods 0.000 claims description 16
229920000642 polymer Polymers 0.000 claims description 15
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
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229920000915 polyvinyl chloride Polymers 0.000 claims description 12
239000000126 substance Substances 0.000 claims description 12
150000001450 anions Chemical class 0.000 claims description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
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229920000515 polycarbonate Polymers 0.000 claims description 6
239000004417 polycarbonate Substances 0.000 claims description 6
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229920000936 Agarose Polymers 0.000 claims description 5
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229910052759 nickel Inorganic materials 0.000 claims description 5
125000005498 phthalate group Chemical class 0.000 claims description 5
229920002401 polyacrylamide Polymers 0.000 claims description 5
239000004584 polyacrylic acid Substances 0.000 claims description 5
229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
229920002379 silicone rubber Polymers 0.000 claims description 5
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 4
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
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239000010931 gold Substances 0.000 claims description 4
229910052697 platinum Inorganic materials 0.000 claims description 4
239000004814 polyurethane Substances 0.000 claims description 4
239000011118 polyvinyl acetate Substances 0.000 claims description 4
229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
238000009736 wetting Methods 0.000 claims description 4
239000004793 Polystyrene Substances 0.000 claims description 3
229920002678 cellulose Polymers 0.000 claims description 3
229920002301 cellulose acetate Polymers 0.000 claims description 3
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 3
239000003120 macrolide antibiotic agent Substances 0.000 claims description 3
229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
229920000570 polyether Polymers 0.000 claims description 3
229920001184 polypeptide Polymers 0.000 claims description 3
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108090000765 processed proteins & peptides Proteins 0.000 claims description 3
102000004196 processed proteins & peptides Human genes 0.000 claims description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
229920001328 Polyvinylidene chloride Polymers 0.000 claims description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 2
229910052796 boron Inorganic materials 0.000 claims description 2
229920002223 polystyrene Polymers 0.000 claims description 2
239000005033 polyvinylidene chloride Substances 0.000 claims description 2
229920002554 vinyl polymer Polymers 0.000 claims description 2
229920001477 hydrophilic polymer Polymers 0.000 claims 4
229910052742 iron Inorganic materials 0.000 claims 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
150000001868 cobalt Chemical class 0.000 claims 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 2
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 2
239000004721 Polyphenylene oxide Substances 0.000 claims 2
229910019142 PO4 Inorganic materials 0.000 claims 1
229920001311 Poly(hydroxyethyl acrylate) Polymers 0.000 claims 1
150000003863 ammonium salts Chemical class 0.000 claims 1
150000008378 aryl ethers Chemical class 0.000 claims 1
239000005466 carboxylated polyvinylchloride Substances 0.000 claims 1
229910001429 cobalt ion Inorganic materials 0.000 claims 1
150000004292 cyclic ethers Chemical class 0.000 claims 1
235000021317 phosphate Nutrition 0.000 claims 1
150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
229920002338 polyhydroxyethylmethacrylate Polymers 0.000 claims 1
229920000973 polyvinylchloride carboxylated Polymers 0.000 claims 1
239000002365 multiple layer Substances 0.000 abstract description 2
239000010410 layer Substances 0.000 description 179
239000000243 solution Substances 0.000 description 59
238000000034 method Methods 0.000 description 34
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 33
239000000203 mixture Substances 0.000 description 33
239000011248 coating agent Substances 0.000 description 32
238000000576 coating method Methods 0.000 description 32
230000004044 response Effects 0.000 description 27
238000005259 measurement Methods 0.000 description 23
239000000523 sample Substances 0.000 description 23
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 22
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 21
230000000694 effects Effects 0.000 description 17
238000004519 manufacturing process Methods 0.000 description 16
235000019422 polyvinyl alcohol Nutrition 0.000 description 16
239000001103 potassium chloride Substances 0.000 description 16
238000003860 storage Methods 0.000 description 16
229910021607 Silver chloride Inorganic materials 0.000 description 15
239000012085 test solution Substances 0.000 description 15
235000011164 potassium chloride Nutrition 0.000 description 14
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 14
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 13
229910001414 potassium ion Inorganic materials 0.000 description 13
239000011521 glass Substances 0.000 description 12
239000010408 film Substances 0.000 description 11
238000002360 preparation method Methods 0.000 description 11
238000012360 testing method Methods 0.000 description 11
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
238000007598 dipping method Methods 0.000 description 10
239000002555 ionophore Substances 0.000 description 10
230000000236 ionophoric effect Effects 0.000 description 10
238000001035 drying Methods 0.000 description 9
239000012088 reference solution Substances 0.000 description 9
SGSRWJWKEQYEGG-UHFFFAOYSA-N 1-bromo-3-(3-bromo-2-phenylphenoxy)-2-phenylbenzene Chemical compound C=1C=CC=CC=1C=1C(Br)=CC=CC=1OC1=CC=CC(Br)=C1C1=CC=CC=C1 SGSRWJWKEQYEGG-UHFFFAOYSA-N 0.000 description 8
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 8
229940021013 electrolyte solution Drugs 0.000 description 8
239000011734 sodium Substances 0.000 description 8
150000001768 cations Chemical class 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
239000004094 surface-active agent Substances 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 6
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
239000000839 emulsion Substances 0.000 description 6
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VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
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238000011156 evaluation Methods 0.000 description 5
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NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 4
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 4
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PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 3
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150000001340 alkali metals Chemical class 0.000 description 3
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PUFGCEQWYLJYNJ-UHFFFAOYSA-N didodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCC PUFGCEQWYLJYNJ-UHFFFAOYSA-N 0.000 description 3
229960001826 dimethylphthalate Drugs 0.000 description 3
HAKMAMKAFTZXOZ-UHFFFAOYSA-N dioctoxyphosphorylbenzene Chemical compound CCCCCCCCOP(=O)(OCCCCCCCC)C1=CC=CC=C1 HAKMAMKAFTZXOZ-UHFFFAOYSA-N 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
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ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 3
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KAMCBFNNGGVPPW-UHFFFAOYSA-N 1-(ethenylsulfonylmethoxymethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)COCS(=O)(=O)C=C KAMCBFNNGGVPPW-UHFFFAOYSA-N 0.000 description 2
CBVXNDCIOLXDFD-UHFFFAOYSA-N 1-methoxy-3-phenoxybenzene Chemical compound COC1=CC=CC(OC=2C=CC=CC=2)=C1 CBVXNDCIOLXDFD-UHFFFAOYSA-N 0.000 description 2
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QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
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QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
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229910001447 ferric ion Inorganic materials 0.000 description 2
229910001448 ferrous ion Inorganic materials 0.000 description 2
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UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 2
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IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
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BDJXVNRFAQSMAA-UHFFFAOYSA-N quinhydrone Chemical compound OC1=CC=C(O)C=C1.O=C1C=CC(=O)C=C1 BDJXVNRFAQSMAA-UHFFFAOYSA-N 0.000 description 2
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XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 2
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VOQUBBXWPSCCHR-UHFFFAOYSA-N 2,2,2-trifluoro-1-(2-octan-4-ylphenyl)ethanone Chemical compound CCCCC(CCC)C1=CC=CC=C1C(=O)C(F)(F)F VOQUBBXWPSCCHR-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
102000007469 Actins Human genes 0.000 description 1
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229920001817 Agar Polymers 0.000 description 1
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Inert Electrodes (AREA)

CA276,918A 1976-05-19 1977-04-25 Electrode selectrice d'ions Expired CA1093641A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000352785A CA1116696A (fr)	1976-05-19	1980-05-27	Electrode a selection ionique

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US68796676A	1976-05-19	1976-05-19
US687,966		1976-05-19

Publications (1)

Publication Number	Publication Date
CA1093641A true CA1093641A (fr)	1981-01-13

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CA276,918A Expired CA1093641A (fr)	1976-05-19	1977-04-25	Electrode selectrice d'ions

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4734375A (en) *	1980-05-27	1988-03-29	Miles Laboratories, Inc.	Ion specific test method
CN113924481A (zh) *	2019-06-14	2022-01-11	罗伯特·博世有限公司	金属亚铁氰化物掺杂的碳作为离子选择性电极的转换器

1977
- 1977-04-25 CA CA276,918A patent/CA1093641A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4734375A (en) *	1980-05-27	1988-03-29	Miles Laboratories, Inc.	Ion specific test method
CN113924481A (zh) *	2019-06-14	2022-01-11	罗伯特·博世有限公司	金属亚铁氰化物掺杂的碳作为离子选择性电极的转换器

Legal Events

Date	Code	Title	Description
1998-01-20	MKEX	Expiry

Publication	Publication Date	Title
US4214968A (en)	1980-07-29	Ion-selective electrode
EP0024191B1 (fr)	1984-04-04	Eléments de référence, électrodes sensibles aux ions comprenant lesdits éléments et procédé pour préparer lesdits éléments
US4966671A (en)	1990-10-30	Method and apparatus for electrochemical analysis
GB1584788A (en)	1981-02-18	Ion-selective electrode
US3856649A (en)	1974-12-24	Solid state electrode
US5286365A (en)	1994-02-15	Graphite-based solid state polymeric membrane ion-selective electrodes
US20050006237A1 (en)	2005-01-13	Ion-selective solid-state polymeric membrane electrondes
JPS6135510B2 (fr)	1986-08-13
EP0512070A1 (fr)	1992-11-11	Cellule electrolytique de detection d'analytes multiples
US4171246A (en)	1979-10-16	Method for determining ionic activity of components of liquid drops
US5840168A (en)	1998-11-24	Solid contact ion-selective electrode
CA2150017C (fr)	1999-08-10	Electrode de reference
JP3135956B2 (ja)	2001-02-19	ソリッドコンタクトとこれを用いた電位差センサ装置およびセンサ装置による方法
US5312537A (en)	1994-05-17	Electrochemical cell, reference electrode and electrochemical method
US4259164A (en)	1981-03-31	Silver/silver halide electrodes comprising chromium or nickel
US4867860A (en)	1989-09-19	Method of manufacturing ion-selective electrodes for analyzing selected ions in solution
CA1093641A (fr)	1981-01-13	Electrode selectrice d'ions
CA1116696A (fr)	1982-01-19	Electrode a selection ionique
EP0288724B1 (fr)	1993-07-21	Electrode sélective aux ions pour mesurer la concentration de carbonate
EP0230573A1 (fr)	1987-08-05	Electrodes sèches sélectivement perméables aux ions pour analyser certains ions dans des solutions aqueuses
JPH03195963A (ja)	1991-08-27	電気化学式ガスセンサ素子
GB2332278A (en)	1999-06-16	Electrochemical sensor

CA1093641A - Electrode selectrice d'ions - Google Patents

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