CA1094489A - Desulfuration et demetallisation de charges lourdes - Google Patents

Desulfuration et demetallisation de charges lourdes

Info

Publication number: CA1094489A
Authority: CA; Canada
Prior art keywords: hydrogen; water; reaction zone; sulfur; nickel
Prior art date: 1976-03-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA272,087A

Other languages

English (en)

Inventor

Louis D. Rollmann

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-03-29

Filing date

1977-02-18

Publication date

1981-01-27

1977-02-18 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1981-01-27 Application granted granted Critical

1981-01-27 Publication of CA1094489A publication Critical patent/CA1094489A/fr

Status Expired legal-status Critical Current

Links

238000006477 desulfuration reaction Methods 0.000 title claims abstract description 25
230000023556 desulfurization Effects 0.000 title claims abstract description 24
238000007324 demetalation reaction Methods 0.000 title abstract description 9
229910001868 water Inorganic materials 0.000 claims abstract description 55
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 38
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
238000000034 method Methods 0.000 claims abstract description 28
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
239000001257 hydrogen Substances 0.000 claims abstract description 23
239000003054 catalyst Substances 0.000 claims abstract description 22
238000006243 chemical reaction Methods 0.000 claims abstract description 22
229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 21
229910052717 sulfur Inorganic materials 0.000 claims abstract description 21
239000011593 sulfur Substances 0.000 claims abstract description 21
229910052759 nickel Inorganic materials 0.000 claims abstract description 19
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 14
238000004064 recycling Methods 0.000 claims abstract description 5
229910052751 metal Inorganic materials 0.000 claims description 15
239000002184 metal Substances 0.000 claims description 15
239000007789 gas Substances 0.000 claims description 14
239000007924 injection Substances 0.000 claims description 7
238000002347 injection Methods 0.000 claims description 7
150000002739 metals Chemical class 0.000 claims description 7
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
238000005336 cracking Methods 0.000 claims description 3
229910052809 inorganic oxide Inorganic materials 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
238000000926 separation method Methods 0.000 claims 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
230000005494 condensation Effects 0.000 claims 1
238000009833 condensation Methods 0.000 claims 1
229910052750 molybdenum Inorganic materials 0.000 claims 1
239000011733 molybdenum Substances 0.000 claims 1
125000000101 thioether group Chemical group 0.000 claims 1
230000000694 effects Effects 0.000 description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
239000000047 product Substances 0.000 description 6
229910052720 vanadium Inorganic materials 0.000 description 6
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
238000009835 boiling Methods 0.000 description 4
239000000306 component Substances 0.000 description 4
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
230000032683 aging Effects 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000010779 crude oil Substances 0.000 description 3
238000004821 distillation Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000003921 oil Substances 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
238000004523 catalytic cracking Methods 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
238000010791 quenching Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
241000518994 Conta Species 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
241000588731 Hafnia Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000004939 coking Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
-1 hydrogen- Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
150000002898 organic sulfur compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA272,087A 1976-03-29 1977-02-18 Desulfuration et demetallisation de charges lourdes Expired CA1094489A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US67190676A	1976-03-29	1976-03-29
US671,906		1976-03-29

Publications (1)

Publication Number	Publication Date
CA1094489A true CA1094489A (fr)	1981-01-27

Family

ID=24696365

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA272,087A Expired CA1094489A (fr)	1976-03-29	1977-02-18	Desulfuration et demetallisation de charges lourdes

Country Status (8)

Country	Link
JP (1)	JPS52117905A (fr)
AU (1)	AU510360B2 (fr)
CA (1)	CA1094489A (fr)
DE (1)	DE2713343A1 (fr)
FR (1)	FR2346436A1 (fr)
GB (1)	GB1535477A (fr)
IT (1)	IT1075588B (fr)
ZA (1)	ZA771371B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20020056664A1 (en) *	2000-09-07	2002-05-16	Julie Chabot	Extension of catalyst cycle length in residuum desulfurization processes

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1528414A (fr) *	1966-06-24	1968-06-07	Universal Oil Prod Co	Procédé de désulfuration de l'huile de pétrole brute
US3501396A (en) *	1969-04-14	1970-03-17	Universal Oil Prod Co	Hydrodesulfurization of asphaltene-containing black oil
US3753894A (en) *	1971-02-26	1973-08-21	Exxon Research Engineering Co	Water injection between catalyst beds in hydrodesulfurization of residuum feed
US3720602A (en) *	1971-02-26	1973-03-13	Exxon Research Engineering Co	Water injection in a hydrodesulfurization process
DE2207611A1 (de) *	1972-02-18	1973-08-30	Exxon Research Engineering Co	Hydroraffinationsverfahren
DE2332834A1 (de) *	1973-06-28	1975-01-23	Exxon Research Engineering Co	Hydrodesulfurierung von rueckstandsoelen
NL188659C (nl) *	1975-02-21	1992-08-17	Shell Int Research	Werkwijze voor het ontzwavelen van koolwaterstofolien.

1977
- 1977-02-18 CA CA272,087A patent/CA1094489A/fr not_active Expired
- 1977-03-08 ZA ZA00771371A patent/ZA771371B/xx unknown
- 1977-03-09 GB GB9901/77A patent/GB1535477A/en not_active Expired
- 1977-03-14 JP JP2713877A patent/JPS52117905A/ja active Pending
- 1977-03-25 DE DE19772713343 patent/DE2713343A1/de not_active Withdrawn
- 1977-03-25 FR FR7708957A patent/FR2346436A1/fr active Granted
- 1977-03-28 IT IT21755/77A patent/IT1075588B/it active
- 1977-03-28 AU AU23694/77A patent/AU510360B2/en not_active Expired

Also Published As

Publication number	Publication date
ZA771371B (en)	1978-10-25
AU510360B2 (en)	1980-06-19
FR2346436B1 (fr)	1982-06-04
AU2369477A (en)	1978-10-05
IT1075588B (it)	1985-04-22
FR2346436A1 (fr)	1977-10-28
GB1535477A (en)	1978-12-13
DE2713343A1 (de)	1977-10-06
JPS52117905A (en)	1977-10-03

Legal Events

Date	Code	Title	Description
1998-01-27	MKEX	Expiry

Publication	Publication Date	Title
US4016067A (en)	1977-04-05	Process for demetalation and desulfurization of petroleum oils
US4306964A (en)	1981-12-22	Multi-stage process for demetalation and desulfurization of petroleum oils
US4191636A (en)	1980-03-04	Process for hydrotreating heavy hydrocarbon oil
US3287254A (en)	1966-11-22	Residual oil conversion process
US4054508A (en)	1977-10-18	Demetalation and desulfurization of residual oil utilizing hydrogen and trickle beds of catalysts in three zones
US3720602A (en)	1973-03-13	Water injection in a hydrodesulfurization process
US4695369A (en)	1987-09-22	Catalytic hydroconversion of heavy oil using two metal catalyst
US4062762A (en)	1977-12-13	Process for desulfurizing and blending naphtha
US3617481A (en)	1971-11-02	Combination deasphalting-coking-hydrotreating process
US4272357A (en)	1981-06-09	Desulfurization and demetalation of heavy charge stocks
US5024750A (en)	1991-06-18	Process for converting heavy hydrocarbon oil
RU2663896C2 (ru)	2018-08-13	Переработка гидрокрекингом кубового остатка
GB1602639A (en)	1981-11-11	Process for hydrodesulphurization of heavy hydrocarbon oils
US4176048A (en)	1979-11-27	Process for conversion of heavy hydrocarbons
EP1794265A2 (fr)	2007-06-13	Processus de recyclage de composition de catalyseur a suspension dans une valorisation d'huiles lourdes
US3306845A (en)	1967-02-28	Multistage hydrofining process
US3155608A (en)	1964-11-03	Process for reducing metals content of catalytic cracking feedstock
CA1169841A (fr)	1984-06-26	Methode d'enrichissement des produits residuaires du petrole, et catalyseur connexe
US3983030A (en)	1976-09-28	Combination process for residua demetalation, desulfurization and resulting coke gasification
US4992163A (en)	1991-02-12	Cat cracking feed preparation
US3905893A (en)	1975-09-16	Plural stage residue hydrodesulfurization process
US4988434A (en)	1991-01-29	Removal of metallic contaminants from a hydrocarbonaceous liquid
KR100362299B1 (ko)	2003-03-15	접촉분해 가솔린의 탈황방법
GB2167430A (en)	1986-05-29	Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content
US3985643A (en)	1976-10-12	Demetalation and desulfurization of oil in separate catalytic zones