CA1094531A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1094531A
Authority: CA; Canada
Prior art keywords: polyol; unsaturation; prepared; containing added; polyols
Prior art date: 1977-07-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA307,256A

Other languages

English (en)

Inventor

Randall C. Rains

Larry T. Blankenship

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-13

Filing date

1978-07-12

Publication date

1981-01-27

1978-07-12 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1981-01-27 Application granted granted Critical

1981-01-27 Publication of CA1094531A publication Critical patent/CA1094531A/fr

Status Expired legal-status Critical Current

Links

229920005862 polyol Polymers 0.000 title claims abstract description 106
150000003077 polyols Chemical class 0.000 title claims abstract description 105
239000006185 dispersion Substances 0.000 title claims abstract description 27
229920000642 polymer Polymers 0.000 title abstract description 20
239000000203 mixture Substances 0.000 claims abstract description 39
239000000178 monomer Substances 0.000 claims abstract description 24
238000000034 method Methods 0.000 claims abstract description 15
238000006116 polymerization reaction Methods 0.000 claims abstract description 10
230000004048 modification Effects 0.000 claims abstract description 7
238000012986 modification Methods 0.000 claims abstract description 7
239000003444 phase transfer catalyst Substances 0.000 claims abstract description 6
239000011953 free-radical catalyst Substances 0.000 claims abstract description 5
238000011065 in-situ storage Methods 0.000 claims abstract description 5
238000006959 Williamson synthesis reaction Methods 0.000 claims abstract description 4
238000006243 chemical reaction Methods 0.000 claims description 14
239000004815 dispersion polymer Substances 0.000 claims description 9
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 claims description 5
SLBOQBILGNEPEB-UHFFFAOYSA-N 1-chloroprop-2-enylbenzene Chemical compound C=CC(Cl)C1=CC=CC=C1 SLBOQBILGNEPEB-UHFFFAOYSA-N 0.000 claims description 4
-1 for example Substances 0.000 abstract description 19
238000002360 preparation method Methods 0.000 abstract description 7
239000004814 polyurethane Substances 0.000 abstract description 6
229920002635 polyurethane Polymers 0.000 abstract description 6
229920001577 copolymer Polymers 0.000 abstract description 2
239000000806 elastomer Substances 0.000 abstract description 2
229920001971 elastomer Polymers 0.000 abstract 1
239000006260 foam Substances 0.000 abstract 1
239000007788 liquid Substances 0.000 abstract 1
239000000047 product Substances 0.000 description 19
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
229960005419 nitrogen Drugs 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
125000002947 alkylene group Chemical group 0.000 description 11
239000003054 catalyst Substances 0.000 description 11
229910001873 dinitrogen Inorganic materials 0.000 description 9
238000010438 heat treatment Methods 0.000 description 9
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
239000007787 solid Substances 0.000 description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
229910052753 mercury Inorganic materials 0.000 description 6
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
239000004721 Polyphenylene oxide Substances 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000003513 alkali Substances 0.000 description 3
229910001854 alkali hydroxide Inorganic materials 0.000 description 3
150000008044 alkali metal hydroxides Chemical class 0.000 description 3
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
229960005150 glycerol Drugs 0.000 description 3
235000011187 glycerol Nutrition 0.000 description 3
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
239000000391 magnesium silicate Substances 0.000 description 3
229960002366 magnesium silicate Drugs 0.000 description 3
229910052919 magnesium silicate Inorganic materials 0.000 description 3
235000019792 magnesium silicate Nutrition 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000003018 phosphorus compounds Chemical class 0.000 description 3
238000010926 purge Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000005587 bubbling Effects 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
229920001281 polyalkylene Polymers 0.000 description 2
229920006324 polyoxymethylene Polymers 0.000 description 2
229960004063 propylene glycol Drugs 0.000 description 2
235000013772 propylene glycol Nutrition 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
239000012047 saturated solution Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
FVXAIIVXIJVXRH-OWOJBTEDSA-N (e)-but-2-ene-1,4-dithiol Chemical compound SC\C=C\CS FVXAIIVXIJVXRH-OWOJBTEDSA-N 0.000 description 1
VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical group SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 description 1
YGKHJWTVMIMEPQ-UHFFFAOYSA-N 1,2-propanedithiol Chemical group CC(S)CS YGKHJWTVMIMEPQ-UHFFFAOYSA-N 0.000 description 1
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
SRZXCOWFGPICGA-UHFFFAOYSA-N 1,6-Hexanedithiol Chemical group SCCCCCCS SRZXCOWFGPICGA-UHFFFAOYSA-N 0.000 description 1
HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
FXLJHFCTYDFUER-UHFFFAOYSA-N 1-bromoprop-2-enylbenzene Chemical compound C=CC(Br)C1=CC=CC=C1 FXLJHFCTYDFUER-UHFFFAOYSA-N 0.000 description 1
LCLUKOYPZSDZAP-UHFFFAOYSA-N 1-fluoroprop-2-enylbenzene Chemical compound C=CC(F)C1=CC=CC=C1 LCLUKOYPZSDZAP-UHFFFAOYSA-N 0.000 description 1
YAUZKNDNVSEDKE-UHFFFAOYSA-N 1-iodoprop-2-enylbenzene Chemical compound C=CC(I)C1=CC=CC=C1 YAUZKNDNVSEDKE-UHFFFAOYSA-N 0.000 description 1
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical compound NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
QCMKXHXKNIOBBC-UHFFFAOYSA-N 3-fluoroprop-1-ene Chemical compound FCC=C QCMKXHXKNIOBBC-UHFFFAOYSA-N 0.000 description 1
YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920005830 Polyurethane Foam Polymers 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
HFEHLDPGIKPNKL-UHFFFAOYSA-N allyl iodide Chemical compound ICC=C HFEHLDPGIKPNKL-UHFFFAOYSA-N 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001414 amino alcohols Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
229910001863 barium hydroxide Inorganic materials 0.000 description 1
239000002585 base Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
RGTXVXDNHPWPHH-UHFFFAOYSA-N butane-1,3-diamine Chemical compound CC(N)CCN RGTXVXDNHPWPHH-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000012043 crude product Substances 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
230000029087 digestion Effects 0.000 description 1
LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
229940043276 diisopropanolamine Drugs 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
229940012017 ethylenediamine Drugs 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
YYLZFVAZIBYRMJ-UHFFFAOYSA-N hex-3-yne-1,6-dithiol Chemical compound SCCC#CCCS YYLZFVAZIBYRMJ-UHFFFAOYSA-N 0.000 description 1
125000001145 hydrido group Chemical group *[H] 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229940102253 isopropanolamine Drugs 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
238000003408 phase transfer catalysis Methods 0.000 description 1
150000004714 phosphonium salts Chemical class 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920001228 polyisocyanate Polymers 0.000 description 1
239000005056 polyisocyanate Substances 0.000 description 1
229920006295 polythiol Polymers 0.000 description 1
239000011496 polyurethane foam Substances 0.000 description 1
229940093932 potassium hydroxide Drugs 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
239000001294 propane Substances 0.000 description 1
238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
125000005207 tetraalkylammonium group Chemical group 0.000 description 1
DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical class CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
229950006389 thiodiglycol Drugs 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/06—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules
- C08F291/08—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules on to macromolecules containing hydroxy radicals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/14—Polymers provided for in subclass C08G
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/337—Polymers modified by chemical after-treatment with organic compounds containing other elements

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Graft Or Block Polymers (AREA)
Macromonomer-Based Addition Polymer (AREA)
Polymerisation Methods In General (AREA)

CA307,256A 1977-07-13 1978-07-12 Traduction non-disponible Expired CA1094531A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US81512577A	1977-07-13	1977-07-13
US815,125		1977-07-13

Publications (1)

Publication Number	Publication Date
CA1094531A true CA1094531A (fr)	1981-01-27

Family

ID=25216943

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA307,256A Expired CA1094531A (fr)	1977-07-13	1978-07-12	Traduction non-disponible

Country Status (7)

Country	Link
EP (1)	EP0000503A1 (fr)
JP (1)	JPS5440887A (fr)
AR (1)	AR219761A1 (fr)
AU (1)	AU3794778A (fr)
BR (1)	BR7804510A (fr)
CA (1)	CA1094531A (fr)
IT (1)	IT1156857B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4690956A (en) *	1982-04-01	1987-09-01	Basf Corporation	Process for the preparation of graft polymer dispersions and flame-retardant polyurethane foams
USRE33291E (en) *	1982-04-01	1990-08-07	Basf Corporation	Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams
US4463107A (en) *	1982-05-18	1984-07-31	Union Carbide Corporation	Polymer/polyol compositions having improved combustion resistance
USRE32733E (en) *	1982-05-18	1988-08-16	Union Carbide Corporation	Polymer/polyol compositions having improved combustion resistance
US4623674A (en)	1985-06-21	1986-11-18	Union Carbide Corporation	Polymer/polyols of substituted styrenes and polyurethanes made therefrom

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1541982A (fr) *	1966-10-26	1968-10-11	Ici Ltd	Nouveaux composés surfactifs à non-saturation éthylénique et leurs procédés defabrication
DE2220723A1 (de) *	1972-04-27	1973-11-08	Basf Ag	Verfahren zur herstellung von reinen polyalkylenaethern mit modifizierten endgruppen
IT988286B (it) *	1972-06-29	1975-04-10	Dow Chemical Co	Composti vinil benzilici e compo sizioni di ricoprimento preparate da essi
US3953393A (en) *	1974-01-07	1976-04-27	Basf Wyandotte Corporation	Low temperature process for the preparation of graft copolymer dispersions

1978
- 1978-07-12 IT IT50257/78A patent/IT1156857B/it active
- 1978-07-12 CA CA307,256A patent/CA1094531A/fr not_active Expired
- 1978-07-12 BR BR7804510A patent/BR7804510A/pt unknown
- 1978-07-12 EP EP78100371A patent/EP0000503A1/fr not_active Withdrawn
- 1978-07-12 AU AU37947/78A patent/AU3794778A/en active Pending
- 1978-07-13 JP JP8565478A patent/JPS5440887A/ja active Pending
- 1978-07-13 AR AR272943A patent/AR219761A1/es active

Also Published As

Publication number	Publication date
IT7850257A0 (it)	1978-07-12
EP0000503A1 (fr)	1979-02-07
IT1156857B (it)	1987-02-04
AU3794778A (en)	1980-01-17
AR219761A1 (es)	1980-09-15
BR7804510A (pt)	1979-04-03
JPS5440887A (en)	1979-03-31

Legal Events

Date	Code	Title	Description
1998-01-27	MKEX	Expiry

Publication	Publication Date	Title
CA1162669A (fr)	1984-02-21	Enduits sechant a temperature ambiante ou basse
AU621916B2 (en)	1992-03-26	Polymerizable surfactant
US4102942A (en)	1978-07-25	Compositions of high solids content comprising carboxylic polymer and aliphatic diepoxide
US4640935A (en)	1987-02-03	Addition polymerizable adducts for nonaqueous dispersions
US4226753A (en)	1980-10-07	Novel methacrylic polymers having condensation-crosslinkable functionality
EP0217481B1 (fr)	1989-11-02	Compositions polymères absorbant l'eau
SU695563A3 (ru)	1979-10-30	Способ получени сополимеров
US3813365A (en)	1974-05-28	High molecular weight cyclic nitrile adduct compositions
US4276432A (en)	1981-06-30	Low molecular weight acrylates or methacrylates and methods for their preparation
US5254651A (en)	1993-10-19	Room temperature curing, alternating isopropenyl-dimethylbenzylisocyanate copolymers having high isocyanate functionality
CA1094531A (fr)	1981-01-27	Traduction non-disponible
US4103093A (en)	1978-07-25	Novel methacrylic polymers having condensation-crosslinkable functionality
AU616886B2 (en)	1991-11-14	Hardenable composition on the basis of a michael addition product, process for the manufacture thereof and use thereof
EP0719796A1 (fr)	1996-07-03	Composition réticulable comprenant de monobenzaldimine comme agent de réticulation
US5206286A (en)	1993-04-27	Aqueous emulsion polymers prepared with crosslinkable non-ionic surfactants
CA1140939A (fr)	1983-02-08	Polymeres reactifs liquides
CA1106989A (fr)	1981-08-11	Polymerisation en emulsion de monomeres a insaturation ethylenique dans des composes organiques termines par une fonction hydroxy
EP0000601B1 (fr)	1981-08-26	Procédé de préparation d'un copolymère de bas poids moléculaire à base d'acrylate et une composition liquide de revêtement ayant une concentration élevée en matières solides, à base du copolymère d'acrylate ainsi obtenu
US3652476A (en)	1972-03-28	Thermoset molding powders employing glycidyl methacrylate and aromatic amines
JP3041856B2 (ja)	2000-05-15	水性エマルジョンおよびその製造方法
US2824858A (en)	1958-02-25	Polymerizable poly-ethylenically unsaturated compounds, polymers thereof, and their preparation
EP0450451B1 (fr)	1996-05-01	Polymères en émulsion aqueuse préparés avec des émulsifiants non toniques réticulables
AU2006302124B2 (en)	2011-08-18	High temperature polymerization process for making branched acrylic polymers, caprolactone-modified branched acrylic polymers, and uses thereof
CA1261531A (fr)	1989-09-26	Preparation de polymeres a teneur d'hydroxyle, et leur emploi pour la production de polyurethanes
IL50491A (en)	1977-05-31	Polymers and copolymers of esters of methacrylic acid and compositions containing them