CA1094973A - Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre - Google Patents

Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre

Info

Publication number: CA1094973A
Authority: CA; Canada
Prior art keywords: zinc; copper; electrolyte; cobalt; residue
Prior art date: 1976-03-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA328,544A

Other languages

English (en)

Inventor

George M. Freeman

John E. Dulson

Monica F. Morris

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Texasgulf Canada Ltd

Original Assignee

Texasgulf Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-03-11

Filing date

1979-05-29

Publication date

1981-02-03

1976-03-11 Priority claimed from CA247,665A external-priority patent/CA1063967A/fr

1979-05-29 Application filed by Texasgulf Canada Ltd filed Critical Texasgulf Canada Ltd

1979-05-29 Priority to CA328,544A priority Critical patent/CA1094973A/fr

1981-02-03 Application granted granted Critical

1981-02-03 Publication of CA1094973A publication Critical patent/CA1094973A/fr

Status Expired legal-status Critical Current

Links

HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 95
239000011701 zinc Substances 0.000 title claims abstract description 89
229910052725 zinc Inorganic materials 0.000 title claims abstract description 79
229910017052 cobalt Inorganic materials 0.000 title claims abstract description 55
239000010941 cobalt Substances 0.000 title claims abstract description 55
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 54
239000003792 electrolyte Substances 0.000 title claims abstract description 43
RKYSWCFUYJGIQA-UHFFFAOYSA-H copper(ii) arsenate Chemical compound [Cu+2].[Cu+2].[Cu+2].[O-][As]([O-])([O-])=O.[O-][As]([O-])([O-])=O RKYSWCFUYJGIQA-UHFFFAOYSA-H 0.000 title claims abstract description 26
229940030341 copper arsenate Drugs 0.000 title claims abstract description 23
238000000034 method Methods 0.000 claims abstract description 29
230000008569 process Effects 0.000 claims abstract description 18
238000005868 electrolysis reaction Methods 0.000 claims abstract description 11
239000007787 solid Substances 0.000 claims abstract description 9
239000000356 contaminant Substances 0.000 claims abstract description 7
238000005363 electrowinning Methods 0.000 claims abstract description 6
239000010949 copper Substances 0.000 abstract description 60
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 58
229910052802 copper Inorganic materials 0.000 abstract description 55
229910052785 arsenic Inorganic materials 0.000 abstract description 40
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 36
239000002253 acid Substances 0.000 abstract description 27
238000000746 purification Methods 0.000 abstract description 20
229910052793 cadmium Inorganic materials 0.000 abstract description 19
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 18
239000003518 caustics Substances 0.000 abstract description 18
239000004568 cement Substances 0.000 abstract description 18
239000002002 slurry Substances 0.000 abstract description 15
238000011084 recovery Methods 0.000 abstract description 11
238000000605 extraction Methods 0.000 abstract description 5
239000003513 alkali Substances 0.000 abstract description 2
150000001879 copper Chemical class 0.000 abstract description 2
238000009854 hydrometallurgy Methods 0.000 abstract 1
239000000243 solution Substances 0.000 description 38
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
239000000706 filtrate Substances 0.000 description 17
239000000047 product Substances 0.000 description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
229910000365 copper sulfate Inorganic materials 0.000 description 12
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 12
239000003153 chemical reaction reagent Substances 0.000 description 10
229910052751 metal Inorganic materials 0.000 description 10
239000002184 metal Substances 0.000 description 10
HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 description 9
GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
238000001914 filtration Methods 0.000 description 7
239000011572 manganese Substances 0.000 description 7
229910052759 nickel Inorganic materials 0.000 description 7
238000007792 addition Methods 0.000 description 6
239000011734 sodium Substances 0.000 description 6
238000002386 leaching Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
238000006073 displacement reaction Methods 0.000 description 4
239000011787 zinc oxide Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 3
239000000428 dust Substances 0.000 description 3
239000008151 electrolyte solution Substances 0.000 description 3
239000012535 impurity Substances 0.000 description 3
239000012286 potassium permanganate Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
229910052950 sphalerite Inorganic materials 0.000 description 3
229910052984 zinc sulfide Inorganic materials 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
239000012527 feed solution Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
229910000368 zinc sulfate Inorganic materials 0.000 description 2
229960001763 zinc sulfate Drugs 0.000 description 2
DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
239000005083 Zinc sulfide Substances 0.000 description 1
229940000489 arsenate Drugs 0.000 description 1
150000001495 arsenic compounds Chemical class 0.000 description 1
JEMGLEPMXOIVNS-UHFFFAOYSA-N arsenic copper Chemical compound [Cu].[As] JEMGLEPMXOIVNS-UHFFFAOYSA-N 0.000 description 1
238000011021 bench scale process Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
229940079593 drug Drugs 0.000 description 1
239000003814 drug Substances 0.000 description 1
229940093920 gynecological arsenic compound Drugs 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000004571 lime Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000007747 plating Methods 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
230000000699 topical effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Manufacture And Refinement Of Metals (AREA)

CA328,544A 1976-03-11 1979-05-29 Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre Expired CA1094973A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA328,544A CA1094973A (fr)	1976-03-11	1979-05-29	Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CA247,665A CA1063967A (fr)	1976-03-11	1976-03-11	Traitement hydrometallurgique du zinc
CA328,544A CA1094973A (fr)	1976-03-11	1979-05-29	Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre

Publications (1)

Publication Number	Publication Date
CA1094973A true CA1094973A (fr)	1981-02-03

Family

ID=25668233

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA328,544A Expired CA1094973A (fr)	1976-03-11	1979-05-29	Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre

Country Status (1)

Country	Link
CA (1)	CA1094973A (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5002748A (en) *	1988-09-02	1991-03-26	Cominco Ltd.	Method for the preparation of copper arsenate
AP3297A (en) *	2011-10-09	2015-05-31	Mintek	Direct electrowinning of cobalt
CN109778229A (zh) *	2019-03-15	2019-05-21	瑞安市南方电解厂	采用废铜渣回收生产电解锌铜的生产工艺
CN113621993A (zh) *	2021-08-25	2021-11-09	湖南福尔程环保科技有限公司	一种锌电解液的净化方法
CN114774693A (zh) *	2022-05-06	2022-07-22	新疆紫金有色金属有限公司	一种湿法炼锌二净渣的综合利用方法
CN114774692A (zh) *	2022-04-29	2022-07-22	新疆紫金有色金属有限公司	一种湿法炼锌系统的贫镉液除镉和钴方法

1979
- 1979-05-29 CA CA328,544A patent/CA1094973A/fr not_active Expired

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5002748A (en) *	1988-09-02	1991-03-26	Cominco Ltd.	Method for the preparation of copper arsenate
AP3297A (en) *	2011-10-09	2015-05-31	Mintek	Direct electrowinning of cobalt
CN109778229A (zh) *	2019-03-15	2019-05-21	瑞安市南方电解厂	采用废铜渣回收生产电解锌铜的生产工艺
CN113621993A (zh) *	2021-08-25	2021-11-09	湖南福尔程环保科技有限公司	一种锌电解液的净化方法
CN114774692A (zh) *	2022-04-29	2022-07-22	新疆紫金有色金属有限公司	一种湿法炼锌系统的贫镉液除镉和钴方法
CN114774693A (zh) *	2022-05-06	2022-07-22	新疆紫金有色金属有限公司	一种湿法炼锌二净渣的综合利用方法

Legal Events

Date	Code	Title	Description
1998-02-03	MKEX	Expiry

Publication	Publication Date	Title
CA2154560C (fr)	2004-11-02	Procede hydrometallurgique d'extraction de metaux de minerais complexes
CA1155084A (fr)	1983-10-11	Procede de recuperation de metaux precieux a partir de boues anodiques
RU2023728C1 (ru)	1994-11-30	Способ извлечения цинка, меди, свинца и серебра из цинкжелезосодержащего сульфидного сырья
US4440569A (en)	1984-04-03	Recovery of zinc from zinc-containing sulphidic material
CA2202289C (fr)	2002-01-22	Recuperation du zinc de concentres sulfures
NO142995B (no)	1980-08-18	Fremgangsmaate ved behandling av sinkfabrikkresiduum dannet ved utluting av sinkkalsinat med svovelsyre
US4150976A (en)	1979-04-24	Method for the recovery of metallic copper
CA2666229A1 (fr)	2008-05-02	Procede de production de cobalt metallique a partir de produit raffine d'extraction par solvant de nickel
US3691038A (en)	1972-09-12	Process for the recovery of zinc from zinc- and iron-containing materials
AU5406794A (en)	1994-05-09	Antimony separation process
CA1117897A (fr)	1982-02-09	Procede de regeneration continue de l'electrolyte d'une installation de zingage
CA1094973A (fr)	1981-02-03	Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre
US4789446A (en)	1988-12-06	Method of processing residues from the hydrometallurgical production of zinc
US3883345A (en)	1975-05-13	Process for the recovery of antimony
US4049514A (en)	1977-09-20	Zinc hydrometallurgical process
EP0025466B1 (fr)	1984-02-15	Procédé de récupération d'arsenic sous forme d'arséniate de zinc à partir d'un gâteau de cuivre de cémentation et procédé de purification d'un électrolyte de zinc impur au moyen de l'arséniate de zinc ainsi obtenu
CA2304064A1 (fr)	1999-04-15	Recuperation du plomb contenu dans les poussieres de carneau
CA1156048A (fr)	1983-11-01	Methode de recuperation de plomb et d'argent a partir de mineraux et de residus de procede
CN109913647B (zh)	2020-10-27	一种回收铋中矿中铜、锌的湿法处理方法
AU2010217184A1 (en)	2011-08-25	Zinc oxide purification
GB2114966A (en)	1983-09-01	Recovery of zinc from sulphidic material
RU2079561C1 (ru)	1997-05-20	Способ переработки окисленных полиметаллических материалов
US2473962A (en)	1949-06-21	Process for recovering cadmium
CA1066658A (fr)	1979-11-20	Recuperation du zinc
CN114058856A (zh)	2022-02-18	一种含锑废渣综合回收处理系统

CA1094973A - Extraction du cobalt dans une solution d'electrolyte de zinc, au moyen de zinc en poussiere et d'arsenate de cuivre - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (2)

Publications (1)

Family

ID=25668233

Family Applications (1)

Country Status (1)

Cited By (6)

Cited By (6)

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