CA1099656A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1099656A
Authority: CA; Canada
Prior art keywords: improved process; product; feed; hydrocarbons; convertible
Prior art date: 1975-07-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA254,838A

Other languages

English (en)

Inventor

Clarence D. Chang

William H. Lang

Anthony J. Silvestri

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-07-02

Filing date

1976-06-15

Publication date

1981-04-21

1975-07-02 Priority claimed from US05/592,434 external-priority patent/US3998898A/en

1976-06-15 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1981-04-21 Application granted granted Critical

1981-04-21 Publication of CA1099656A publication Critical patent/CA1099656A/fr

Status Expired legal-status Critical Current

Links

239000003502 gasoline Substances 0.000 title claims abstract description 28
238000004519 manufacturing process Methods 0.000 title abstract description 6
239000010457 zeolite Substances 0.000 claims abstract description 58
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 34
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 29
239000000203 mixture Substances 0.000 claims abstract description 29
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 15
239000000377 silicon dioxide Substances 0.000 claims abstract description 14
125000001931 aliphatic group Chemical group 0.000 claims abstract description 11
150000001735 carboxylic acids Chemical class 0.000 claims abstract description 9
150000001875 compounds Chemical class 0.000 claims abstract description 8
150000002170 ethers Chemical class 0.000 claims abstract description 7
229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 5
150000001720 carbohydrates Chemical class 0.000 claims abstract description 5
235000014633 carbohydrates Nutrition 0.000 claims abstract description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
150000002430 hydrocarbons Chemical class 0.000 claims description 38
229930195733 hydrocarbon Natural products 0.000 claims description 36
238000000034 method Methods 0.000 claims description 23
239000003054 catalyst Substances 0.000 claims description 22
239000004215 Carbon black (E152) Substances 0.000 claims description 17
230000008569 process Effects 0.000 claims description 17
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
238000009835 boiling Methods 0.000 claims description 12
150000002894 organic compounds Chemical class 0.000 claims description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
229910052799 carbon Inorganic materials 0.000 claims description 9
150000001299 aldehydes Chemical class 0.000 claims description 8
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
150000001298 alcohols Chemical class 0.000 claims description 7
125000003118 aryl group Chemical group 0.000 claims description 7
125000004430 oxygen atom Chemical group O* 0.000 claims description 6
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
125000002843 carboxylic acid group Chemical group 0.000 claims description 4
230000001186 cumulative effect Effects 0.000 claims description 4
150000002576 ketones Chemical class 0.000 claims description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
230000007812 deficiency Effects 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
230000006872 improvement Effects 0.000 claims description 2
239000000463 material Substances 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 1
229940077731 carbohydrate nutrients Drugs 0.000 claims 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
150000005846 sugar alcohols Polymers 0.000 claims 1
-1 aliphatic alcohols Chemical class 0.000 abstract description 6
150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 3
239000007789 gas Substances 0.000 abstract description 3
150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract description 2
150000001241 acetals Chemical class 0.000 abstract 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 21
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
239000013078 crystal Substances 0.000 description 14
239000000376 reactant Substances 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 8
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 8
239000002253 acid Substances 0.000 description 7
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 6
125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 6
239000000126 substance Substances 0.000 description 6
150000001768 cations Chemical class 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
239000010454 slate Substances 0.000 description 5
PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 4
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000011148 porous material Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
238000001354 calcination Methods 0.000 description 3
239000000571 coke Substances 0.000 description 3
239000000470 constituent Substances 0.000 description 3
239000001307 helium Substances 0.000 description 3
229910052734 helium Inorganic materials 0.000 description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
150000002892 organic cations Chemical class 0.000 description 3
239000001294 propane Substances 0.000 description 3
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000004913 activation Effects 0.000 description 2
230000029936 alkylation Effects 0.000 description 2
238000005804 alkylation reaction Methods 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052675 erionite Inorganic materials 0.000 description 2
238000005755 formation reaction Methods 0.000 description 2
235000011187 glycerol Nutrition 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
125000005842 heteroatom Chemical group 0.000 description 2
229910052677 heulandite Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
230000036619 pore blockages Effects 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
239000008096 xylene Substances 0.000 description 2
OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
101150034533 ATIC gene Proteins 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
238000005882 aldol condensation reaction Methods 0.000 description 1
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000001273 butane Substances 0.000 description 1
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
229910052676 chabazite Inorganic materials 0.000 description 1
229910001603 clinoptilolite Inorganic materials 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
229910001657 ferrierite group Inorganic materials 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910001683 gmelinite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000007037 hydroformylation reaction Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000007327 hydrogenolysis reaction Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
229910001711 laumontite Inorganic materials 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
229910052678 stilbite Inorganic materials 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
230000009466 transformation Effects 0.000 description 1
238000000844 transformation Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
239000011800 void material Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA254,838A 1975-07-02 1976-06-15 Traduction non-disponible Expired CA1099656A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US592,434		1975-07-02
US05/592,434 US3998898A (en)	1973-08-09	1975-07-02	Manufacture of gasoline

Publications (1)

Publication Number	Publication Date
CA1099656A true CA1099656A (fr)	1981-04-21

Family

ID=24370634

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA254,838A Expired CA1099656A (fr)	1975-07-02	1976-06-15	Traduction non-disponible

Country Status (2)

Country	Link
CA (1)	CA1099656A (fr)
ZA (1)	ZA763551B (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7560607B2 (en)	2004-04-16	2009-07-14	Marathon Gtf Technology, Ltd.	Process for converting gaseous alkanes to liquid hydrocarbons
US7579510B2 (en)	2006-02-03	2009-08-25	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US7674941B2 (en)	2004-04-16	2010-03-09	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
US7838708B2 (en)	2001-06-20	2010-11-23	Grt, Inc.	Hydrocarbon conversion process improvements
US7847139B2 (en)	2003-07-15	2010-12-07	Grt, Inc.	Hydrocarbon synthesis
US7883568B2 (en)	2006-02-03	2011-02-08	Grt, Inc.	Separation of light gases from halogens
US7964764B2 (en)	2003-07-15	2011-06-21	Grt, Inc.	Hydrocarbon synthesis
US7998438B2 (en)	2007-05-24	2011-08-16	Grt, Inc.	Zone reactor incorporating reversible hydrogen halide capture and release
US8008535B2 (en)	2004-04-16	2011-08-30	Marathon Gtf Technology, Ltd.	Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8173851B2 (en)	2004-04-16	2012-05-08	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
US8198495B2 (en)	2010-03-02	2012-06-12	Marathon Gtf Technology, Ltd.	Processes and systems for the staged synthesis of alkyl bromides
US8273929B2 (en)	2008-07-18	2012-09-25	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US8282810B2 (en)	2008-06-13	2012-10-09	Marathon Gtf Technology, Ltd.	Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8436220B2 (en)	2011-06-10	2013-05-07	Marathon Gtf Technology, Ltd.	Processes and systems for demethanization of brominated hydrocarbons
US8802908B2 (en)	2011-10-21	2014-08-12	Marathon Gtf Technology, Ltd.	Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en)	2011-12-16	2015-11-24	Gtc Technology Us, Llc	Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US9206093B2 (en)	2004-04-16	2015-12-08	Gtc Technology Us, Llc	Process for converting gaseous alkanes to liquid hydrocarbons

1976
- 1976-06-15 ZA ZA00763551A patent/ZA763551B/xx unknown
- 1976-06-15 CA CA254,838A patent/CA1099656A/fr not_active Expired

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8415512B2 (en)	2001-06-20	2013-04-09	Grt, Inc.	Hydrocarbon conversion process improvements
US7838708B2 (en)	2001-06-20	2010-11-23	Grt, Inc.	Hydrocarbon conversion process improvements
US7847139B2 (en)	2003-07-15	2010-12-07	Grt, Inc.	Hydrocarbon synthesis
US7964764B2 (en)	2003-07-15	2011-06-21	Grt, Inc.	Hydrocarbon synthesis
US7880041B2 (en)	2004-04-16	2011-02-01	Marathon Gtf Technology, Ltd.	Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en)	2004-04-16	2010-03-09	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
US8008535B2 (en)	2004-04-16	2011-08-30	Marathon Gtf Technology, Ltd.	Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8173851B2 (en)	2004-04-16	2012-05-08	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
US9206093B2 (en)	2004-04-16	2015-12-08	Gtc Technology Us, Llc	Process for converting gaseous alkanes to liquid hydrocarbons
US7560607B2 (en)	2004-04-16	2009-07-14	Marathon Gtf Technology, Ltd.	Process for converting gaseous alkanes to liquid hydrocarbons
US7883568B2 (en)	2006-02-03	2011-02-08	Grt, Inc.	Separation of light gases from halogens
US8053616B2 (en)	2006-02-03	2011-11-08	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US7579510B2 (en)	2006-02-03	2009-08-25	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US8921625B2 (en)	2007-02-05	2014-12-30	Reaction35, LLC	Continuous process for converting natural gas to liquid hydrocarbons
US7998438B2 (en)	2007-05-24	2011-08-16	Grt, Inc.	Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en)	2008-06-13	2012-10-09	Marathon Gtf Technology, Ltd.	Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8273929B2 (en)	2008-07-18	2012-09-25	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US8415517B2 (en)	2008-07-18	2013-04-09	Grt, Inc.	Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en)	2010-03-02	2012-06-12	Marathon Gtf Technology, Ltd.	Processes and systems for the staged synthesis of alkyl bromides
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Also Published As

Publication number	Publication date
ZA763551B (en)	1978-01-25

Legal Events

Date	Code	Title	Description
1998-04-21	MKEX	Expiry

Publication	Publication Date	Title
US3998898A (en)	1976-12-21	Manufacture of gasoline
CA1099656A (fr)	1981-04-21	Traduction non-disponible
US3979472A (en)	1976-09-07	Process for manufacturing hydrocarbons
US4211640A (en)	1980-07-08	Process for the treatment of olefinic gasoline
US4025576A (en)	1977-05-24	Process for manufacturing olefins
EP0026041B1 (fr)	1983-01-26	Procédé pour la production d'oléfines et/ou d'éthers à indice d'octane élevé
US4048250A (en)	1977-09-13	Conversion of natural gas to gasoline and LPG
US4150062A (en)	1979-04-17	Light olefin processing
US4311865A (en)	1982-01-19	Manufacture of hydrocarbons from oxygenates
US4025575A (en)	1977-05-24	Process for manufacturing olefins
US3965205A (en)	1976-06-22	Conversion of low octane hydrocarbons to high octane gasoline
US4096163A (en)	1978-06-20	Conversion of synthesis gas to hydrocarbon mixtures
US4227992A (en)	1980-10-14	Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4025571A (en)	1977-05-24	Manufacture of hydrocarbons
Le Van Mao et al.	1987	Ethylene from ethanol over zeolite catalysts
US4180516A (en)	1979-12-25	Conversion of synthesis gas to aromatic hydrocarbons
US4039600A (en)	1977-08-02	Conversion of synthesis gas to aromatic hydrocarbons
US4088706A (en)	1978-05-09	Methanol conversion to para-xylene using a zeolite catalyst containing an oxide of boron, magnesium, phosphorus, or mixtures
US4698452A (en)	1987-10-06	Ethylene light olefins from ethanol
US4720602A (en)	1988-01-19	Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite
US5609654A (en)	1997-03-11	Process for hydroisomerization and etherification of isoalkenes
US5191142A (en)	1993-03-02	Process for converting methanol to olefins or gasoline
US4148835A (en)	1979-04-10	Hydrocarbon manufacture from alcohols
US4083888A (en)	1978-04-11	Process for manufacturing ethylene
US4547601A (en)	1985-10-15	Conversion of Fischer-Tropsch oxygenates to middle distillate