CA1099657A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1099657A
Authority: CA; Canada
Prior art keywords: catalyst; cracking; zone; platinum; group metal
Prior art date: 1976-02-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA270,168A

Other languages

English (en)

Inventor

Albert B. Schwartz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-02-19

Filing date

1977-01-21

Publication date

1981-04-21

1976-02-19 Priority claimed from US05/659,308 external-priority patent/US4088568A/en

1977-01-21 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1981-04-21 Application granted granted Critical

1981-04-21 Publication of CA1099657A publication Critical patent/CA1099657A/fr

Status Expired legal-status Critical Current

Links

229930195733 hydrocarbon Natural products 0.000 title claims abstract description 53
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 53
238000004523 catalytic cracking Methods 0.000 title claims abstract description 28
239000003054 catalyst Substances 0.000 claims abstract description 329
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 146
238000005336 cracking Methods 0.000 claims abstract description 123
239000000571 coke Substances 0.000 claims abstract description 47
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 41
238000000034 method Methods 0.000 claims abstract description 41
229910052697 platinum Inorganic materials 0.000 claims abstract description 36
230000008569 process Effects 0.000 claims abstract description 35
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 22
-1 petroleum Chemical class 0.000 claims abstract description 21
150000001875 compounds Chemical class 0.000 claims abstract description 10
229910052763 palladium Inorganic materials 0.000 claims abstract description 10
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 8
239000003208 petroleum Substances 0.000 claims abstract description 6
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 5
229910052751 metal Inorganic materials 0.000 claims description 89
239000002184 metal Substances 0.000 claims description 89
238000011069 regeneration method Methods 0.000 claims description 80
230000008929 regeneration Effects 0.000 claims description 79
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 72
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 72
239000007789 gas Substances 0.000 claims description 62
229910002092 carbon dioxide Inorganic materials 0.000 claims description 51
229910002091 carbon monoxide Inorganic materials 0.000 claims description 33
230000000694 effects Effects 0.000 claims description 30
239000003546 flue gas Substances 0.000 claims description 30
238000004231 fluid catalytic cracking Methods 0.000 claims description 18
239000001257 hydrogen Substances 0.000 claims description 18
229910052739 hydrogen Inorganic materials 0.000 claims description 18
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
229910052760 oxygen Inorganic materials 0.000 claims description 17
239000001301 oxygen Substances 0.000 claims description 17
238000002156 mixing Methods 0.000 claims description 13
239000001569 carbon dioxide Substances 0.000 claims description 11
229910002090 carbon oxide Inorganic materials 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 8
239000007787 solid Substances 0.000 claims description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
239000002253 acid Substances 0.000 claims description 4
238000000151 deposition Methods 0.000 claims description 4
230000006872 improvement Effects 0.000 claims description 4
XZQYTGKSBZGQMO-UHFFFAOYSA-I rhenium pentachloride Chemical compound Cl[Re](Cl)(Cl)(Cl)Cl XZQYTGKSBZGQMO-UHFFFAOYSA-I 0.000 claims description 4
KLFRPGNCEJNEKU-FDGPNNRMSA-L (z)-4-oxopent-2-en-2-olate;platinum(2+) Chemical compound [Pt+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O KLFRPGNCEJNEKU-FDGPNNRMSA-L 0.000 claims description 3
WUHYYTYYHCHUID-UHFFFAOYSA-K iridium(3+);triiodide Chemical compound [I-].[I-].[I-].[Ir+3] WUHYYTYYHCHUID-UHFFFAOYSA-K 0.000 claims description 3
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 claims description 3
MBVAQOHBPXKYMF-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;rhodium Chemical compound [Rh].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MBVAQOHBPXKYMF-LNTINUHCSA-N 0.000 claims description 2
QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 claims description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
239000005977 Ethylene Substances 0.000 claims description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
238000001816 cooling Methods 0.000 claims description 2
125000004989 dicarbonyl group Chemical group 0.000 claims description 2
STJZTTRQAFUKML-UHFFFAOYSA-N ethane-1,2-diamine rhenium Chemical compound C(CN)N.C(CN)N.[Re] STJZTTRQAFUKML-UHFFFAOYSA-N 0.000 claims description 2
UPYKZYDFVXGMOF-UHFFFAOYSA-J ethane-1,2-diamine tetrachloroplatinum Chemical compound NCCN.NCCN.NCCN.Cl[Pt](Cl)(Cl)Cl UPYKZYDFVXGMOF-UHFFFAOYSA-J 0.000 claims description 2
IHUHXSNGMLUYES-UHFFFAOYSA-J osmium(iv) chloride Chemical compound Cl[Os](Cl)(Cl)Cl IHUHXSNGMLUYES-UHFFFAOYSA-J 0.000 claims description 2
MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 claims description 2
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 2
YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 claims description 2
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
FZHCFNGSGGGXEH-UHFFFAOYSA-N ruthenocene Chemical compound [Ru+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 FZHCFNGSGGGXEH-UHFFFAOYSA-N 0.000 claims description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
XCNONSRQKLQCTI-UHFFFAOYSA-N [Ir+].ClP(C(=O)P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [Ir+].ClP(C(=O)P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 XCNONSRQKLQCTI-UHFFFAOYSA-N 0.000 claims 1
AYLLMOCGNIKXAC-UHFFFAOYSA-L azanide;dichloroplatinum Chemical compound [NH2-].[NH2-].[NH2-].[Cl-].[Cl-].[Pt+2] AYLLMOCGNIKXAC-UHFFFAOYSA-L 0.000 claims 1
125000005997 bromomethyl group Chemical group 0.000 claims 1
238000007084 catalytic combustion reaction Methods 0.000 claims 1
125000003963 dichloro group Chemical group Cl* 0.000 claims 1
GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 claims 1
DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 claims 1
229910052702 rhenium Inorganic materials 0.000 abstract description 9
229910052741 iridium Inorganic materials 0.000 abstract description 7
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract description 6
238000012546 transfer Methods 0.000 abstract description 6
239000010948 rhodium Substances 0.000 abstract description 5
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract description 4
229910052762 osmium Inorganic materials 0.000 abstract description 4
229910052703 rhodium Inorganic materials 0.000 abstract description 4
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract description 3
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract description 3
238000006243 chemical reaction Methods 0.000 description 35
239000000306 component Substances 0.000 description 34
239000002245 particle Substances 0.000 description 30
239000003921 oil Substances 0.000 description 27
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 25
229910052799 carbon Inorganic materials 0.000 description 25
239000000047 product Substances 0.000 description 25
239000000203 mixture Substances 0.000 description 23
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
239000000243 solution Substances 0.000 description 19
229910021536 Zeolite Inorganic materials 0.000 description 18
239000010457 zeolite Substances 0.000 description 18
150000002739 metals Chemical class 0.000 description 16
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
239000003502 gasoline Substances 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
230000010718 Oxidation Activity Effects 0.000 description 14
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
238000002485 combustion reaction Methods 0.000 description 12
239000011159 matrix material Substances 0.000 description 12
230000003647 oxidation Effects 0.000 description 12
238000007254 oxidation reaction Methods 0.000 description 12
230000003197 catalytic effect Effects 0.000 description 11
239000004927 clay Substances 0.000 description 11
239000008367 deionised water Substances 0.000 description 10
229910021641 deionized water Inorganic materials 0.000 description 10
229910052761 rare earth metal Inorganic materials 0.000 description 10
238000000926 separation method Methods 0.000 description 10
238000012360 testing method Methods 0.000 description 10
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
239000012530 fluid Substances 0.000 description 9
239000000463 material Substances 0.000 description 9
150000002736 metal compounds Chemical class 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 9
239000002002 slurry Substances 0.000 description 9
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
238000004517 catalytic hydrocracking Methods 0.000 description 8
239000007921 spray Substances 0.000 description 8
230000008901 benefit Effects 0.000 description 7
239000011651 chromium Substances 0.000 description 7
229910052759 nickel Inorganic materials 0.000 description 7
239000011734 sodium Substances 0.000 description 7
239000000725 suspension Substances 0.000 description 7
229910001868 water Inorganic materials 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000004115 Sodium Silicate Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
239000002585 base Substances 0.000 description 6
230000004087 circulation Effects 0.000 description 6
229910052681 coesite Inorganic materials 0.000 description 6
239000002131 composite material Substances 0.000 description 6
229910052906 cristobalite Inorganic materials 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
229910001404 rare earth metal oxide Inorganic materials 0.000 description 6
150000002910 rare earth metals Chemical group 0.000 description 6
230000002829 reductive effect Effects 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
229910052911 sodium silicate Inorganic materials 0.000 description 6
229910052682 stishovite Inorganic materials 0.000 description 6
229910052905 tridymite Inorganic materials 0.000 description 6
229910052720 vanadium Inorganic materials 0.000 description 6
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 6
239000011324 bead Substances 0.000 description 5
230000007423 decrease Effects 0.000 description 5
238000010348 incorporation Methods 0.000 description 5
230000009467 reduction Effects 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000005995 Aluminium silicate Substances 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
235000012211 aluminium silicate Nutrition 0.000 description 4
229910052804 chromium Inorganic materials 0.000 description 4
230000003247 decreasing effect Effects 0.000 description 4
239000012065 filter cake Substances 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
230000000717 retained effect Effects 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
229910000323 aluminium silicate Inorganic materials 0.000 description 3
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
239000011959 amorphous silica alumina Substances 0.000 description 3
238000013461 design Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
239000000017 hydrogel Substances 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
230000014759 maintenance of location Effects 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000036961 partial effect Effects 0.000 description 3
239000002574 poison Substances 0.000 description 3
231100000614 poison Toxicity 0.000 description 3
239000011148 porous material Substances 0.000 description 3
241000894007 species Species 0.000 description 3
238000003756 stirring Methods 0.000 description 3
241000905957 Channa melasoma Species 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
230000002411 adverse Effects 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000004364 calculation method Methods 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
230000008859 change Effects 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
230000001351 cycling effect Effects 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011572 manganese Substances 0.000 description 2
239000004005 microsphere Substances 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
150000003058 platinum compounds Chemical class 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
230000000630 rising effect Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
238000013022 venting Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
OTOBABIFUHCBCF-UHFFFAOYSA-P C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ir](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ir](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 OTOBABIFUHCBCF-UHFFFAOYSA-P 0.000 description 1
PLZNEAAEBKBGCC-UHFFFAOYSA-O C=1C=CC=CC=1P(C=1C=CC=CC=1)([Pt])C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)([Pt])C1=CC=CC=C1 PLZNEAAEBKBGCC-UHFFFAOYSA-O 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
206010027439 Metal poisoning Diseases 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
206010037660 Pyrexia Diseases 0.000 description 1
238000010793 Steam injection (oil industry) Methods 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
NYAWADGYOWCCLK-UHFFFAOYSA-N [Na].[Zr] Chemical compound [Na].[Zr] NYAWADGYOWCCLK-UHFFFAOYSA-N 0.000 description 1
RJYZHZIMHNKPKM-UHFFFAOYSA-N [Rh].C=C Chemical compound [Rh].C=C RJYZHZIMHNKPKM-UHFFFAOYSA-N 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
239000003570 air Substances 0.000 description 1
239000000809 air pollutant Substances 0.000 description 1
231100001243 air pollutant Toxicity 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
229940045985 antineoplastic platinum compound Drugs 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000000567 combustion gas Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000003795 desorption Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
238000005272 metallurgy Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000010454 slate Substances 0.000 description 1
JRQGFDPXVPTSJU-UHFFFAOYSA-L sodium zirconium(4+) sulfate Chemical compound [Na+].[Zr+4].[O-]S([O-])(=O)=O JRQGFDPXVPTSJU-UHFFFAOYSA-L 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000009466 transformation Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/16—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "moving bed" method
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/36—Rhenium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Catalysts (AREA)

CA270,168A 1976-02-19 1977-01-21 Traduction non-disponible Expired CA1099657A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/659,308 US4088568A (en)	1976-01-15	1976-02-19	Catalytic cracking of hydrocarbons
US659,308		1976-02-19

Publications (1)

Publication Number	Publication Date
CA1099657A true CA1099657A (fr)	1981-04-21

Family

ID=24644903

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA270,168A Expired CA1099657A (fr)	1976-02-19	1977-01-21	Traduction non-disponible

Country Status (3)

Country	Link
BE (1)	BE851625A (fr)
CA (1)	CA1099657A (fr)
ZA (1)	ZA77775B (fr)

1977
- 1977-01-21 CA CA270,168A patent/CA1099657A/fr not_active Expired
- 1977-02-10 ZA ZA00770775A patent/ZA77775B/xx unknown
- 1977-02-18 BE BE175099A patent/BE851625A/fr not_active IP Right Cessation

Also Published As

Publication number	Publication date
ZA77775B (en)	1978-09-27
BE851625A (fr)	1977-08-18

Legal Events

Date	Code	Title	Description
1998-04-21	MKEX	Expiry

Publication	Publication Date	Title
US4072600A (en)	1978-02-07	Catalytic cracking process
US4093535A (en)	1978-06-06	Catalytic cracking process
US4159239A (en)	1979-06-26	Catalytic cracking process
US4153535A (en)	1979-05-08	Catalytic cracking with reduced emission of noxious gases
CA1048991A (fr)	1979-02-20	Fractionnement catalytique a emission reduite de gaz nocifs
US4238317A (en)	1980-12-09	Catalytic cracking with reduced emission of noxious gases
EP0072653B1 (fr)	1986-03-05	Enlèvement endothermique de coke déposé sur des matériaux sorbantes lors de la conversion d'huiles contenant des précurseurs de coke et des métaux lourds
CA1048009A (fr)	1979-02-06	Fractionnement catalytique avec regeneration du catalyseur et repression des emanations de co
US4221677A (en)	1980-09-09	Catalytic cracking with reduced emission of noxious gases
EP0074501B1 (fr)	1986-04-16	Procédé et catalyseur pour la conversion d'huiles contenant des précurseurs de coke et des métaux lourds
US4457833A (en)	1984-07-03	Process and catalyst for the conversion of carbo-metallic containing oils
EP2334759B1 (fr)	2019-12-11	Utilisation d'un catalyseur dans un procédé de production d'oléfines légères dans une unité de craquage catalytique de fluide à une déficience en énergie afin de maximiser la production de éthylène et de propylène et de minimiser la déficience en énergie
CA1051411A (fr)	1979-03-27	Catalyseur de craquage et methode de craquage qui y fait appel
US4282084A (en)	1981-08-04	Catalytic cracking process
US4350614A (en)	1982-09-21	Catalytic cracking catalyst
US7959792B2 (en)	2011-06-14	CO oxidation promoters for use in FCC processes
US4267072A (en)	1981-05-12	Catalytic cracking catalyst with reduced emission of noxious gases
JPS5949275B2 (ja)	1984-12-01	抜頭原油の加工に際して触媒材料に沈着したバナジアの不動化
GB1575018A (en)	1980-09-17	Catalytic cracking with reduced emission of noxious gases
US4174272A (en)	1979-11-13	Catalytic cracking of hydrocarbons
US4218344A (en)	1980-08-19	Catalytic cracking with reduced emission of noxious gases
AU2004248145A1 (en)	2004-12-23	Catalyst additives for the removal of NH3 and HCN from a gas flue of a regeneration zone in a catalytic cracking process
CA1099657A (fr)	1981-04-21	Traduction non-disponible
US4265787A (en)	1981-05-05	Cracking catalyst
US4325814A (en)	1982-04-20	Catalytic cracking process utilizing a copper chromite oxidation catalyst