CA1100477A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1100477A
Authority: CA; Canada
Prior art keywords: particles; catalyst; water; hydrogel particles; hydrogel
Prior art date: 1976-04-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA276,092A

Other languages

English (en)

Inventor

Cornelis W.J. De Goederen

Theo G. Spek

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-04-30

Filing date

1977-04-13

Publication date

1981-05-05

1977-04-13 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1981-05-05 Application granted granted Critical

1981-05-05 Publication of CA1100477A publication Critical patent/CA1100477A/fr

Status Expired legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 68
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims abstract description 42
239000003054 catalyst Substances 0.000 title claims abstract description 41
229910000147 aluminium phosphate Inorganic materials 0.000 title claims abstract description 21
239000000741 silica gel Substances 0.000 title claims abstract description 19
229910002027 silica gel Inorganic materials 0.000 title claims abstract description 19
238000002360 preparation method Methods 0.000 title claims description 9
239000002245 particle Substances 0.000 claims abstract description 78
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
239000000017 hydrogel Substances 0.000 claims abstract description 43
239000011148 porous material Substances 0.000 claims abstract description 21
239000007864 aqueous solution Substances 0.000 claims abstract description 15
239000000377 silicon dioxide Substances 0.000 claims abstract description 14
150000001336 alkenes Chemical class 0.000 claims abstract description 12
239000002253 acid Substances 0.000 claims abstract description 11
238000002156 mixing Methods 0.000 claims abstract description 10
238000001704 evaporation Methods 0.000 claims abstract description 9
230000008020 evaporation Effects 0.000 claims abstract description 9
239000007788 liquid Substances 0.000 claims abstract description 9
238000001035 drying Methods 0.000 claims abstract description 7
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 6
150000001340 alkali metals Chemical class 0.000 claims abstract description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 6
238000001354 calcination Methods 0.000 claims abstract description 5
239000000499 gel Substances 0.000 claims abstract description 5
150000001339 alkali metal compounds Chemical class 0.000 claims abstract description 4
239000012736 aqueous medium Substances 0.000 claims abstract description 4
230000003247 decreasing effect Effects 0.000 claims abstract description 4
239000000463 material Substances 0.000 claims abstract description 4
238000000034 method Methods 0.000 claims description 20
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
239000005977 Ethylene Substances 0.000 claims description 11
238000011282 treatment Methods 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 4
239000000203 mixture Substances 0.000 claims description 4
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
238000007654 immersion Methods 0.000 claims description 2
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
208000036366 Sensation of pressure Diseases 0.000 claims 1
230000036571 hydration Effects 0.000 abstract description 8
238000006703 hydration reaction Methods 0.000 abstract description 8
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
235000011007 phosphoric acid Nutrition 0.000 description 15
229960004838 phosphoric acid Drugs 0.000 description 15
239000000945 filler Substances 0.000 description 14
238000010438 heat treatment Methods 0.000 description 9
239000000243 solution Substances 0.000 description 8
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
239000003921 oil Substances 0.000 description 5
-1 "Davison Grade 57"* Chemical compound 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
238000001879 gelation Methods 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
238000001914 filtration Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
238000012360 testing method Methods 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
241000765083 Ondina Species 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
230000004075 alteration Effects 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009529 body temperature measurement Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000013467 fragmentation Methods 0.000 description 1
238000006062 fragmentation reaction Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000007863 gel particle Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000010335 hydrothermal treatment Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000010690 paraffinic oil Substances 0.000 description 1
238000005325 percolation Methods 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
238000004448 titration Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Dispersion Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA276,092A 1976-04-30 1977-04-13 Traduction non-disponible Expired CA1100477A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB17723/76		1976-04-30
GB1772376A GB1564223A (en)	1976-04-30	1976-04-30	Catalyst comprising phosphoric acid on silica gel its preparation and use

Publications (1)

Publication Number	Publication Date
CA1100477A true CA1100477A (fr)	1981-05-05

Family

ID=10100100

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA276,092A Expired CA1100477A (fr)	1976-04-30	1977-04-13	Traduction non-disponible

Country Status (11)

Country	Link
JP (1)	JPS52133095A (fr)
AU (1)	AU509571B2 (fr)
BE (1)	BE853785A (fr)
BR (1)	BR7702712A (fr)
CA (1)	CA1100477A (fr)
DE (1)	DE2719055A1 (fr)
ES (1)	ES458266A1 (fr)
FR (1)	FR2349359A1 (fr)
GB (1)	GB1564223A (fr)
IT (1)	IT1075516B (fr)
NL (1)	NL7704657A (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2908491A1 (de)	1979-03-05	1980-09-18	Huels Chemische Werke Ag	Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen
DE2929919A1 (de)	1979-07-24	1981-02-19	Huels Chemische Werke Ag	Verfahren zur herstellung eines katalysators aus tonmineralien fuer die hydratation von olefinen
CA1177811A (fr) *	1981-04-13	1984-11-13	Theo G. Spek	Methode de preparation de particules de silice; particules de silice a pores de diametre relativement uniforme; catalyseurs obtenus a l'aide de ces particules, et applications
GB9214688D0 (en) *	1992-07-10	1992-08-19	Bp Chem Int Ltd	Olfin hydration catalysts
TW321634B (fr)	1994-07-05	1997-12-01	Mitsui Toatsu Chemicals
GB9805107D0 (en) *	1998-03-10	1998-05-06	Bp Chem Int Ltd	Catalyst and use therof
KR101110800B1 (ko)	2003-05-28	2012-07-06	도꾸리쯔교세이호진 상교기쥬쯔 소고겡뀨죠	히드록실기 함유 화합물의 제조 방법
US8558036B2 (en)	2010-11-15	2013-10-15	Saudi Arabian Oil Company	Dual phase catalysts system for mixed olefin hydrations

1976
- 1976-04-30 GB GB1772376A patent/GB1564223A/en not_active Expired
1977
- 1977-04-13 CA CA276,092A patent/CA1100477A/fr not_active Expired
- 1977-04-21 BE BE1008090A patent/BE853785A/xx unknown
- 1977-04-28 JP JP4859077A patent/JPS52133095A/ja active Pending
- 1977-04-28 BR BR7702712A patent/BR7702712A/pt unknown
- 1977-04-28 DE DE19772719055 patent/DE2719055A1/de not_active Withdrawn
- 1977-04-28 ES ES458266A patent/ES458266A1/es not_active Expired
- 1977-04-28 IT IT2294477A patent/IT1075516B/it active
- 1977-04-28 AU AU24668/77A patent/AU509571B2/en not_active Expired
- 1977-04-28 NL NL7704657A patent/NL7704657A/xx not_active Application Discontinuation
- 1977-04-29 FR FR7713012A patent/FR2349359A1/fr not_active Withdrawn

Also Published As

Publication number	Publication date
NL7704657A (nl)	1977-11-01
FR2349359A1 (fr)	1977-11-25
BR7702712A (pt)	1978-03-21
AU509571B2 (en)	1980-05-15
GB1564223A (en)	1980-04-02
DE2719055A1 (de)	1977-11-10
ES458266A1 (es)	1978-07-01
IT1075516B (it)	1985-04-22
BE853785A (nl)	1977-10-21
AU2466877A (en)	1978-11-02
JPS52133095A (en)	1977-11-08

Legal Events

Date	Code	Title	Description
1998-05-05	MKEX	Expiry

Publication	Publication Date	Title
CA1177811A (fr)	1984-11-13	Methode de preparation de particules de silice; particules de silice a pores de diametre relativement uniforme; catalyseurs obtenus a l'aide de ces particules, et applications
RU1837958C (ru)	1993-08-30	Катализатор дл димеризации олефинов, представл ющий собой аморфный гель двуокиси кремни и окиси алюмини , и способ его получени
US3140249A (en)	1964-07-07	Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite
EP0170334B1 (fr)	1989-01-25	Procédé de préparation de sphères de silice
US4542118A (en)	1985-09-17	Catalyst manufacture
Moreno et al.	1999	Al-, Al, Zr-, and Zr-pillared montmorillonites and saponites: Preparation, characterization, and catalytic activity in heptane hydroconversion
GB2166970A (en)	1986-05-21	Silica-alumina-rare earth cogels
US3340012A (en)	1967-09-05	Hydrogen production in a fluidized bed of attrition resistant catalyst
US3437604A (en)	1969-04-08	Hydrocarbon conversion catalyst preparation
US2938874A (en)	1960-05-31	Preparation of phosphate-containing alumina gels
CA2265056A1 (fr)	1999-09-10	Catalyseur et son utilisation
CA1151134A (fr)	1983-08-02	Methode et catalyseur d'hydratation des olefines
CA2044735C (fr)	2001-06-05	Procede d'oligomerisation d'olefines legeres
EP0649396B1 (fr)	1996-03-20	Procede de conversion de butadiene en styrene ou en ethylbenzene ou en ces deux composes, par l'utilisation de catalyseurs contenant du molybdene
US2496265A (en)	1950-02-07	Hydrocarbon synthesis process
CA1064008A (fr)	1979-10-09	Mode de preparation de particules silicieuses globulaires
GB1564223A (en)	1980-04-02	Catalyst comprising phosphoric acid on silica gel its preparation and use
JPH0639287A (ja)	1994-02-15	オレフィンをアルコールに水和化する為の触媒の製造方法
US4472531A (en)	1984-09-18	Polymerization catalyst and method of preparing the same
Lopez et al.	2000	Heterogeneous catalysis of aldolisations on activated hydrotalcites
CA2084929C (fr)	2000-01-25	Catalyseur et procede de craquage d'hydrocarbures au moyen de catalyseurs pour craquage catalytique mesoporeux a haute resistance a l'attrition
Ishihara et al.	2011	Novel Method for Generating Large Mesopores in an Amorphous Silica–Alumina by Controlling the Pore Size with the Gel Skeletal Reinforcement and Its Catalytic Cracking Properties as a Catalyst Matrix
US2773842A (en)	1956-12-11	Hydroforming catalysts and method
US3238147A (en)	1966-03-01	Crystalline aluminosilicate hydrocarbon conversion catalyst composite and method of preparation thereof
CA2336316C (fr)	2009-12-08	Support de catalyseur desaluminise, procede de fabrication du support et procede d'hydratation d'olefines c2 ou c3 avec de l'eau en presence d'un catalyseur constitue dudit supportde catalyseur preimpregne d'acide