CA1102465A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1102465A
Authority: CA; Canada
Prior art keywords: acrylate; stage; methacrylate; group; latex
Prior art date: 1976-08-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA283,467A

Other languages

English (en)

Inventor

Andreas Lindert

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Whittaker Corp

Original Assignee

Whittaker Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-08-26

Filing date

1977-07-25

Publication date

1981-06-02

1977-07-25 Application filed by Whittaker Corp filed Critical Whittaker Corp

1981-06-02 Application granted granted Critical

1981-06-02 Publication of CA1102465A publication Critical patent/CA1102465A/fr

Status Expired legal-status Critical Current

Links

239000002184 metal Substances 0.000 title claims 3
239000011253 protective coating Substances 0.000 title 1
239000000178 monomer Substances 0.000 claims abstract description 62
238000000576 coating method Methods 0.000 claims abstract description 43
239000004816 latex Substances 0.000 claims abstract description 30
229920000126 latex Polymers 0.000 claims abstract description 30
239000011248 coating agent Substances 0.000 claims abstract description 27
229920000642 polymer Polymers 0.000 claims abstract description 21
238000000034 method Methods 0.000 claims abstract description 20
239000000203 mixture Substances 0.000 claims abstract description 20
230000008569 process Effects 0.000 claims abstract description 12
239000003999 initiator Substances 0.000 claims abstract description 10
150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 8
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 32
229940063557 methacrylate Drugs 0.000 claims description 32
-1 acrylate ester Chemical class 0.000 claims description 30
238000006243 chemical reaction Methods 0.000 claims description 22
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 15
238000006116 polymerization reaction Methods 0.000 claims description 14
229920002554 vinyl polymer Polymers 0.000 claims description 14
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 11
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 10
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 10
150000002148 esters Chemical class 0.000 claims description 9
239000003960 organic solvent Substances 0.000 claims description 9
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
150000003254 radicals Chemical class 0.000 claims description 8
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 7
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
239000008367 deionised water Substances 0.000 claims description 6
229910021641 deionized water Inorganic materials 0.000 claims description 6
239000000839 emulsion Substances 0.000 claims description 6
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 6
230000000379 polymerizing effect Effects 0.000 claims description 6
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 5
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 5
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 5
239000006172 buffering agent Substances 0.000 claims description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 5
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
239000001530 fumaric acid Substances 0.000 claims description 4
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
150000002576 ketones Chemical class 0.000 claims description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
239000011976 maleic acid Substances 0.000 claims description 4
239000000376 reactant Substances 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
239000004094 surface-active agent Substances 0.000 claims description 4
229930195733 hydrocarbon Natural products 0.000 claims description 3
150000002430 hydrocarbons Chemical class 0.000 claims description 3
239000012429 reaction media Substances 0.000 claims description 3
SFUUDZYXHNYCTM-UHFFFAOYSA-N 2-methylprop-2-enamide;prop-2-enamide Chemical compound NC(=O)C=C.CC(=C)C(N)=O SFUUDZYXHNYCTM-UHFFFAOYSA-N 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims description 2
230000009477 glass transition Effects 0.000 claims description 2
150000002432 hydroperoxides Chemical class 0.000 claims description 2
230000003472 neutralizing effect Effects 0.000 claims description 2
150000002978 peroxides Chemical class 0.000 claims description 2
238000005979 thermal decomposition reaction Methods 0.000 claims description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 2
239000012874 anionic emulsifier Substances 0.000 claims 1
239000012875 nonionic emulsifier Substances 0.000 claims 1
238000002360 preparation method Methods 0.000 claims 1
235000013405 beer Nutrition 0.000 abstract description 9
235000013361 beverage Nutrition 0.000 abstract description 4
238000007720 emulsion polymerization reaction Methods 0.000 abstract description 4
235000013305 food Nutrition 0.000 abstract description 2
238000000518 rheometry Methods 0.000 abstract 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 7
238000012360 testing method Methods 0.000 description 7
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
239000002585 base Substances 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
XSCRXCDDATUDLB-UHFFFAOYSA-N 2-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCC(=C)C(N)=O XSCRXCDDATUDLB-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000000796 flavoring agent Substances 0.000 description 4
235000019634 flavors Nutrition 0.000 description 4
239000011888 foil Substances 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
238000003915 air pollution Methods 0.000 description 3
235000010323 ascorbic acid Nutrition 0.000 description 3
229960005070 ascorbic acid Drugs 0.000 description 3
239000011668 ascorbic acid Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
239000000463 material Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000007921 spray Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
229910001870 ammonium persulfate Inorganic materials 0.000 description 2
230000033228 biological regulation Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
150000007530 organic bases Chemical class 0.000 description 2
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
229930091371 Fructose Natural products 0.000 description 1
239000005715 Fructose Substances 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
241001163743 Perlodes Species 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
125000005011 alkyl ether group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
229940125904 compound 1 Drugs 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
229960002887 deanol Drugs 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
229940120503 dihydroxyacetone Drugs 0.000 description 1
239000012972 dimethylethanolamine Substances 0.000 description 1
235000010350 erythorbic acid Nutrition 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
229960002737 fructose Drugs 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
239000008103 glucose Substances 0.000 description 1
229960001031 glucose Drugs 0.000 description 1
235000001727 glucose Nutrition 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
229940026239 isoascorbic acid Drugs 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
238000009928 pasteurization Methods 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000036314 physical performance Effects 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000009467 reduction Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000012086 standard solution Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
239000005029 tin-free steel Substances 0.000 description 1
239000005028 tinplate Substances 0.000 description 1
229910001428 transition metal ion Inorganic materials 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Paints Or Removers (AREA)

CA283,467A 1976-08-26 1977-07-25 Traduction non-disponible Expired CA1102465A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US71760276A	1976-08-26	1976-08-26
US717,602		1976-08-26

Publications (1)

Publication Number	Publication Date
CA1102465A true CA1102465A (fr)	1981-06-02

Family

ID=24882705

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA283,467A Expired CA1102465A (fr)	1976-08-26	1977-07-25	Traduction non-disponible

Country Status (3)

Country	Link
JP (1)	JPS5328687A (fr)
CA (1)	CA1102465A (fr)
GB (1)	GB1555868A (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5531729A (en) *	1978-08-23	1980-03-06	Hitachi Ltd	Elevator installation method
US4469825A (en) *	1983-03-09	1984-09-04	Rohm And Haas Company	Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as an opacifying agent
AU557547B2 (en) *	1984-08-29	1986-12-24	National Starch & Chemical Corporation	Aqueous coating for meatllised paper
JPS61252203A (ja) *	1985-05-02	1986-11-10	Asahi Chem Ind Co Ltd	高濃度ラテツクス乳化重合方法
DE3543361A1 (de) *	1985-12-07	1987-06-11	Basf Ag	Verfahren zur herstellung waessriger polymerdispersionen und deren verwendung
US5173523A (en) *	1985-12-07	1992-12-22	Basf Aktiengesellschaft	Aqueous polymer emulsions and their preparation
JPH0714985B2 (ja) *	1986-04-09	1995-02-22	旭化成工業株式会社	耐水性の優れたラテツクスの製造方法
AU596439B2 (en) *	1986-08-20	1990-05-03	Glidden Company, The	Emulsion polymers containing acrylonitrile or vinylidene chloride
JP3366736B2 (ja) *	1994-06-23	2003-01-14	旭化成株式会社	水系架橋型塗料用重合体ラテックスおよびそのラテックスを用いた塗料組成物
JPH0820604A (ja) *	1994-07-06	1996-01-23	Kanebo Nsc Ltd	中空重合体粒子の製法
US20030045427A1 (en) *	2000-01-19	2003-03-06	Shinijirou Sakurai	Emulsion for thermal recording material and thermal recording materials made by using the Same
US7008901B2 (en)	2000-01-19	2006-03-07	Mitsui Chemicals, Inc.	Emulsion for thermal recording material and thermal recording materials made by using the same
CN100384641C (zh) *	2002-05-21	2008-04-30	王子制纸株式会社	喷墨记录纸
PL3037488T3 (pl)	2004-10-20	2022-11-14	Swimc Llc	Kompozycje powlekające dla pojemników i sposoby powlekania
RU2549890C2 (ru)	2009-02-24	2015-05-10	Акцо Нобель Коатингс Интернэшнл Б.В.	Латексные эмульсии и композиции для покрытия, полученные из латексных эмульсий
EP2658933B1 (fr)	2010-12-29	2017-03-01	Akzo Nobel Coatings International B.V.	Émulsions latex et compositions de revêtement formées à partir d'émulsions latex
EP3016868B1 (fr)	2013-07-02	2023-09-27	Swimc Llc	Compositions de revêtement pour articles d'emballage tels que récipients pour aliments et boissons
MX2016000069A (es)	2013-07-02	2016-03-01	Valspar Sourcing Inc	Composiciones de revestimiento para articulos de envasado tales como envases de alimentos y bebidas.
EP4516861A3 (fr)	2014-12-24	2025-03-26	Swimc LLC	Compositions de revetement pour articles d'emballage tels que recipients pour aliments et boissons
US11059989B2 (en)	2017-06-30	2021-07-13	Valspar Sourcing, Inc.	Crosslinked coating compositions for packaging articles such as food and beverage containers
US11981822B2 (en)	2014-12-24	2024-05-14	Swimc Llc	Crosslinked coating compositions for packaging articles such as food and beverage containers
CA2970632A1 (fr)	2014-12-24	2016-06-30	Valspar Sourcing, Inc.	Compositions de revetement exemptes de styrene pour des articles d'emballage tels que les recipients pour aliments et pour boissons
AR108133A1 (es)	2016-04-15	2018-07-18	Valspar Sourcing Inc	Composiciones de revestimiento que contienen copolímeros libres de estireno
CN119570318A (zh)	2016-10-19	2025-03-07	宣伟投资管理有限公司	碱溶性树脂添加剂以及包含这种添加剂的涂料组合物
JP7703322B2 (ja)	2017-09-01	2025-07-07	エスダブリューアイエムシー・エルエルシー	多段階ポリマーラテックス、そのようなラテックスを含有するコーティング組成物、及びそれによりコーティングされた物品
EP3676342A4 (fr)	2017-09-01	2021-07-07	Swimc LLC	Latex polymères à étages multiples, compositions de revêtement contenant de tels latex, et articles en étant revêtus

1977
- 1977-07-25 CA CA283,467A patent/CA1102465A/fr not_active Expired
- 1977-08-25 GB GB3577277A patent/GB1555868A/en not_active Expired
- 1977-08-26 JP JP10178477A patent/JPS5328687A/ja active Pending

Also Published As

Publication number	Publication date
JPS5328687A (en)	1978-03-17
GB1555868A (en)	1979-11-14

Legal Events

Date	Code	Title	Description
1998-06-02	MKEX	Expiry

Publication	Publication Date	Title
CA1102465A (fr)	1981-06-02	Traduction non-disponible
EP0882080B1 (fr)	2001-07-11	Polymere dispersible dans l'eau et composition de revetement contenant un tel polymere
CA1340621C (fr)	1999-06-29	Preparation d'un revetement multicouche; compositions aqueuses de revetement; resines de polyacrylates hydrodiluables et preparation de ces resines
AU2011351456B2 (en)	2016-02-11	Latex emulsions and coating compositions formed from latex emulsions
US4647612A (en)	1987-03-03	Polymer emulsion products
CA1148289A (fr)	1983-06-14	Dispersions aqueuses de polymeres acryliques
CA1102028A (fr)	1981-05-26	Traduction non-disponible
JP2020532613A5 (fr)	2021-08-05
US4692491A (en)	1987-09-08	Polymer emulsion products
EP0450452B1 (fr)	1994-09-07	Polymères en émulsion et compositions de revêtement préparées à partir de ceux-ci
JP2934275B2 (ja)	1999-08-16	良好な色彩安定性および可撓性を有する容器塗料用塩化ビニル―オレフインコポリマー
RU2006106770A (ru)	2007-09-20	Водная дисперсия сополимеризатов, ее применение, способ ее получения (его варианты), водное средство для нанесения покрытия, полученное из него покрытие и способ получения покрытия
WO2020057999A1 (fr)	2020-03-26	Adhésifs de contact
CA1162344A (fr)	1984-02-14	Copolymeres d'epoxy-ester solubles dans l'eau, utilisables a l'interieur de contenants
JPH05501125A (ja)	1993-03-04	多層被覆を得る方法、水性被覆組成物及び水に希釈可能なポリアクリレート樹脂の製法
NZ206640A (en)	1986-08-08	Aqueous or water-dispersed coating composition containing epoxy copolymer
US4404336A (en)	1983-09-13	Water soluble epoxy ester copolymers for interior can use
KR910002081B1 (ko)	1991-04-03	아크릴 중합체 함유 열경화성 조성물 및 이 조성물로 코우팅하는 방법
KR100586126B1 (ko)	2006-06-07	아이소뷰틸렌형 단량체의 교호 공중합체를 함유하는 수계 열경화성 조성물
GB1603039A (en)	1981-11-18	Aqueous resin composition cross-linkable by oxidation
JPS5889602A (ja)	1983-05-28	ポリクロロプレンラテツクスの製造方法
EP0256500A2 (fr)	1988-02-24	Polymères en émulsion contenant de l'a2rylonitrile ou du chlorure de vinylidène
WO2025056403A1 (fr)	2025-03-20	Composition de revêtement aqueuse comprenant un copolymère acrylique dispersé
EP0015917A1 (fr)	1980-10-01	Copolymeres esters epoxydes solubles dans l'eau utilises pour les seaux hygieniques
JPH01279947A (ja)	1989-11-10	水性被覆用樹脂組成物及びその製造方法