CA1106149A - Methode d'elimination du sulfure d'hydrogene en presence dans un melange gazeux - Google Patents

Methode d'elimination du sulfure d'hydrogene en presence dans un melange gazeux

Info

Publication number: CA1106149A
Authority: CA; Canada
Prior art keywords: hydrogen sulfide; solvent; process according; gas; reaction
Prior art date: 1977-12-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA316,579A

Other languages

English (en)

Inventor

Jean Rossarie

Jean Maurin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Compagnie Francaise de Raffinage SA

Original Assignee

Compagnie Francaise de Raffinage SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-15

Filing date

1978-11-21

Publication date

1981-08-04

1978-11-21 Application filed by Compagnie Francaise de Raffinage SA filed Critical Compagnie Francaise de Raffinage SA

1981-08-04 Application granted granted Critical

1981-08-04 Publication of CA1106149A publication Critical patent/CA1106149A/fr

Status Expired legal-status Critical Current

Links

RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 74
229910000037 hydrogen sulfide Inorganic materials 0.000 title claims abstract description 74
238000000034 method Methods 0.000 title claims abstract description 39
230000008030 elimination Effects 0.000 title description 8
238000003379 elimination reaction Methods 0.000 title description 8
239000008246 gaseous mixture Substances 0.000 title description 5
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 61
239000002904 solvent Substances 0.000 claims abstract description 59
239000007789 gas Substances 0.000 claims abstract description 46
238000006243 chemical reaction Methods 0.000 claims abstract description 30
238000010521 absorption reaction Methods 0.000 claims abstract description 19
238000004064 recycling Methods 0.000 claims abstract 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 40
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 25
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 22
229910052717 sulfur Inorganic materials 0.000 claims description 22
239000011593 sulfur Substances 0.000 claims description 22
229910021529 ammonia Inorganic materials 0.000 claims description 20
229910001868 water Inorganic materials 0.000 claims description 19
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
150000002334 glycols Chemical class 0.000 claims description 5
238000005504 petroleum refining Methods 0.000 claims description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 3
239000003345 natural gas Substances 0.000 claims description 3
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
238000004523 catalytic cracking Methods 0.000 claims description 2
238000006477 desulfuration reaction Methods 0.000 claims description 2
230000023556 desulfurization Effects 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
239000000243 solution Substances 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
239000001257 hydrogen Substances 0.000 description 9
229910052739 hydrogen Inorganic materials 0.000 description 9
239000007788 liquid Substances 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 8
239000006096 absorbing agent Substances 0.000 description 5
239000000203 mixture Substances 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
-1 for example Chemical class 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
230000004927 fusion Effects 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 1
229960000965 nimesulide Drugs 0.000 description 1
229940099990 ogen Drugs 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000001256 steam distillation Methods 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
238000010792 warming Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
Health & Medical Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Biomedical Technology (AREA)
Treating Waste Gases (AREA)
Gas Separation By Absorption (AREA)
Industrial Gases (AREA)
Processing Of Solid Wastes (AREA)

CA316,579A 1977-12-15 1978-11-21 Methode d'elimination du sulfure d'hydrogene en presence dans un melange gazeux Expired CA1106149A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR7737936A FR2411802A1 (fr)	1977-12-15	1977-12-15	Procede d'elimination de l'hydrogene sulfure contenu dans un melange gazeux
FR7737936		1977-12-15

Publications (1)

Publication Number	Publication Date
CA1106149A true CA1106149A (fr)	1981-08-04

Family

ID=9198913

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA316,579A Expired CA1106149A (fr)	1977-12-15	1978-11-21	Methode d'elimination du sulfure d'hydrogene en presence dans un melange gazeux

Country Status (9)

Country	Link
JP (1)	JPS5490303A (fr)
BE (1)	BE872717A (fr)
CA (1)	CA1106149A (fr)
DE (1)	DE2851653A1 (fr)
FR (1)	FR2411802A1 (fr)
GB (1)	GB2012806B (fr)
IT (1)	IT1100646B (fr)
NL (1)	NL7812232A (fr)
TR (1)	TR20722A (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2532189A1 (fr) *	1982-08-25	1984-03-02	Raffinage Cie Francaise	Procede d'elimination de l'hydrogene sulfure contenu dans un melange gazeux
DE3939296C3 (de) *	1989-11-28	1996-02-08	Electrolux Siegen Gmbh	Vorrichtung zum Entsorgen des Kältemittels von Absorptions-Kältesystemen
FR2735460B1 (fr) *	1995-06-15	1997-07-25	Inst Francais Du Petrole	Procede et dispositif de traitement d'un gaz contenant de l'hydrogene sulfure, comportant une etape d'elimination du soufre cristallise par refroidissement
FR2753395B1 (fr) *	1996-09-16	1998-11-06	Inst Francais Du Petrole	Procede et dispositif de traitement d'un gaz contenant de l'hydrogene sulfure et de l'anhydride sulfureux, comportant une etape d'elimination du soufre par refroidissement de l'effluent gazeux
FR2753396B1 (fr)	1996-09-16	1998-10-30	Inst Francais Du Petrole	Procede et dispositif de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre comportant une etape d'appauvrissement en soufre du solvant recycle
JP2026503772A (ja)	2023-02-06	2026-01-29	クオンタムヴァリーインベストメントファンドリミテッドパートナーシップ	磁気共鳴システムにおける動作回路

1977
- 1977-12-15 FR FR7737936A patent/FR2411802A1/fr active Granted
1978
- 1978-11-21 CA CA316,579A patent/CA1106149A/fr not_active Expired
- 1978-11-29 DE DE19782851653 patent/DE2851653A1/de not_active Withdrawn
- 1978-12-13 TR TR20722A patent/TR20722A/xx unknown
- 1978-12-13 BE BE192278A patent/BE872717A/fr not_active IP Right Cessation
- 1978-12-15 GB GB7848772A patent/GB2012806B/en not_active Expired
- 1978-12-15 IT IT30935/78A patent/IT1100646B/it active
- 1978-12-15 JP JP15567078A patent/JPS5490303A/ja active Pending
- 1978-12-15 NL NL7812232A patent/NL7812232A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
JPS5490303A (en)	1979-07-18
FR2411802B1 (fr)	1981-04-17
BE872717A (fr)	1979-06-13
TR20722A (tr)	1982-05-27
GB2012806A (en)	1979-08-01
DE2851653A1 (de)	1979-06-21
NL7812232A (nl)	1979-06-19
GB2012806B (en)	1982-05-12
FR2411802A1 (fr)	1979-07-13
IT7830935A0 (it)	1978-12-15
IT1100646B (it)	1985-09-28

Legal Events

Date	Code	Title	Description
1998-08-04	MKEX	Expiry

Publication	Publication Date	Title
US4254094A (en)	1981-03-03	Process for producing hydrogen from synthesis gas containing COS
KR100810188B1 (ko)	2008-03-07	황화수소 함유 가스 스트림의 처리방법
CA1261118A (fr)	1989-09-26	Procede haute pression pour la separation du soufre d'un gaz a teneur d'agent sulfhydrique
US4552746A (en)	1985-11-12	Process for the reduction of the sulfur content in a gaseous stream
CA1131883A (fr)	1982-09-21	Traitement avance de gaz contenant du sulfure d'hydrogene
US4088735A (en)	1978-05-09	Process for purifying gases from the gasification of fossil fuels
JPS627960B2 (fr)	1987-02-19
US4280990A (en)	1981-07-28	High pressure process for recovery of sulphur from gases
EP1456123B1 (fr)	2009-04-29	Procede de recuperation de constituants sulfureux dans un processus de recuperation de soufre
US4124685A (en)	1978-11-07	Method for substantially complete removal of hydrogen sulfide from sulfur bearing industrial gases
US3896215A (en)	1975-07-22	Process for the removal of hydrogen sulfide from a gas stream
EP0073074B1 (fr)	1987-11-25	Procédé pour réduire le contenu total en soufre d'un gaz d'alimentation à haut contenu en CO2
US4057403A (en)	1977-11-08	Gas treating process
CA1205277A (fr)	1986-06-03	Procede de regeneration de solutions absorbantes pour gaz sulfureux
EP0046061B1 (fr)	1984-11-07	Procédé pour la séparation sélective de l'hydrogène sulfuré des mélanges de gaz contenant de l'anhydride carbonique et de l'hydrogène sulfuré
US4155988A (en)	1979-05-22	Reduction of sulfur concentration in physical scrubbing agents
CA1106149A (fr)	1981-08-04	Methode d'elimination du sulfure d'hydrogene en presence dans un melange gazeux
GB1589231A (en)	1981-05-07	Process for the removal of acidic gases
US3656275A (en)	1972-04-18	Process for the removal and concentration of a component gas from a multi-gaseous stream
US4297330A (en)	1981-10-27	Process of selectively desulfurizing gases
US3953586A (en)	1976-04-27	Process for purifying gases containing H2 S
CA1099897A (fr)	1981-04-28	Traduction non-disponible
WO2003047730A1 (fr)	2003-06-12	Procede de recuperation de soufre a partir de gaz sulfureux d'origine industrielle
CA1085590A (fr)	1980-09-16	Procede d'extraction de gaz acides
US4267162A (en)	1981-05-12	Process and apparatus for the exploitation of the sulfur compounds contained in gases containing oxygen and a high water vapor content