CA1106576A - Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions - Google Patents

Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions

Info

Publication number: CA1106576A
Authority: CA; Canada
Prior art keywords: anion exchange; exchange resin; improvement; heat stable; absorbent solution
Prior art date: 1977-03-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA298,483A

Other languages

English (en)

Inventor

Alexander J. Kosseim

David A. Dunnery

Gilbert R. Atwood

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-03-25

Filing date

1978-03-08

Publication date

1981-08-11

1978-03-08 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1981-08-11 Application granted granted Critical

1981-08-11 Publication of CA1106576A publication Critical patent/CA1106576A/fr

Status Expired legal-status Critical Current

Links

239000003957 anion exchange resin Substances 0.000 title claims abstract description 52
150000003839 salts Chemical class 0.000 title claims abstract description 52
238000000034 method Methods 0.000 title claims abstract description 38
230000008569 process Effects 0.000 title claims abstract description 33
239000007789 gas Substances 0.000 title abstract description 63
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 161
239000002250 absorbent Substances 0.000 claims abstract description 148
230000002745 absorbent Effects 0.000 claims abstract description 148
229920005989 resin Polymers 0.000 claims abstract description 43
239000011347 resin Substances 0.000 claims abstract description 43
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 37
229910052717 sulfur Inorganic materials 0.000 claims abstract description 37
239000011593 sulfur Substances 0.000 claims abstract description 37
239000000203 mixture Substances 0.000 claims abstract description 27
230000006872 improvement Effects 0.000 claims abstract description 26
239000002585 base Substances 0.000 claims abstract description 24
-1 hydroxyl anions Chemical class 0.000 claims abstract description 24
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 12
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 8
150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 8
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 8
229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 6
239000000908 ammonium hydroxide Substances 0.000 claims abstract description 5
239000001569 carbon dioxide Substances 0.000 claims abstract description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 58
229910001868 water Inorganic materials 0.000 claims description 58
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 38
239000002699 waste material Substances 0.000 claims description 25
150000001450 anions Chemical class 0.000 claims description 21
238000011069 regeneration method Methods 0.000 claims description 21
230000008929 regeneration Effects 0.000 claims description 20
239000003456 ion exchange resin Substances 0.000 claims description 12
229920003303 ion-exchange polymer Polymers 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 12
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 10
230000001172 regenerating effect Effects 0.000 claims description 7
239000003595 mist Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
229910001853 inorganic hydroxide Inorganic materials 0.000 claims description 5
238000004064 recycling Methods 0.000 claims description 3
230000003134 recirculating effect Effects 0.000 claims description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 66
238000010926 purge Methods 0.000 description 38
239000006096 absorbing agent Substances 0.000 description 28
239000000243 solution Substances 0.000 description 27
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 22
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 18
238000010521 absorption reaction Methods 0.000 description 18
239000002912 waste gas Substances 0.000 description 18
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 12
239000002904 solvent Substances 0.000 description 11
238000005342 ion exchange Methods 0.000 description 10
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 10
238000005406 washing Methods 0.000 description 10
YMRKWTHZKSAVSR-UHFFFAOYSA-N hydrogen sulfite;tris(2-hydroxyethyl)azanium Chemical compound OS(O)=O.OCCN(CCO)CCO YMRKWTHZKSAVSR-UHFFFAOYSA-N 0.000 description 9
150000002500 ions Chemical class 0.000 description 8
238000011068 loading method Methods 0.000 description 8
150000003467 sulfuric acid derivatives Chemical class 0.000 description 8
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 7
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
238000005349 anion exchange Methods 0.000 description 7
239000003518 caustics Substances 0.000 description 7
229920001429 chelating resin Polymers 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
238000010791 quenching Methods 0.000 description 7
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
239000003153 chemical reaction reagent Substances 0.000 description 6
238000007323 disproportionation reaction Methods 0.000 description 6
235000010265 sodium sulphite Nutrition 0.000 description 6
241000196324 Embryophyta Species 0.000 description 5
238000001556 precipitation Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 5
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 5
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
230000008859 change Effects 0.000 description 4
239000012141 concentrate Substances 0.000 description 4
239000012530 fluid Substances 0.000 description 4
239000010881 fly ash Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000002245 particle Substances 0.000 description 4
229910052815 sulfur oxide Inorganic materials 0.000 description 4
AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
238000009825 accumulation Methods 0.000 description 3
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
229910052921 ammonium sulfate Inorganic materials 0.000 description 3
235000011130 ammonium sulphate Nutrition 0.000 description 3
239000011324 bead Substances 0.000 description 3
239000003245 coal Substances 0.000 description 3
238000003795 desorption Methods 0.000 description 3
238000010586 diagram Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
125000001453 quaternary ammonium group Chemical group 0.000 description 3
239000012492 regenerant Substances 0.000 description 3
238000007086 side reaction Methods 0.000 description 3
241000894007 species Species 0.000 description 3
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000011001 backwashing Methods 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000009835 boiling Methods 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000006073 displacement reaction Methods 0.000 description 2
229940116441 divinylbenzene Drugs 0.000 description 2
239000003546 flue gas Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000007530 organic bases Chemical class 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229920001568 phenolic resin Polymers 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
239000011148 porous material Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000000047 product Substances 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
238000003860 storage Methods 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
239000003643 water by type Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
244000046052 Phaseolus vulgaris Species 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
241001208007 Procas Species 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000005576 amination reaction Methods 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
239000002956 ash Substances 0.000 description 1
238000004380 ashing Methods 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
LVGQIQHJMRUCRM-UHFFFAOYSA-L calcium bisulfite Chemical compound [Ca+2].OS([O-])=O.OS([O-])=O LVGQIQHJMRUCRM-UHFFFAOYSA-L 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
235000010260 calcium hydrogen sulphite Nutrition 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
235000010261 calcium sulphite Nutrition 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical class O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000007265 chloromethylation reaction Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000000567 combustion gas Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
230000008602 contraction Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000012864 cross contamination Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
238000012674 dispersion polymerization Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
229940075933 dithionate Drugs 0.000 description 1
238000010828 elution Methods 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000010408 film Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000012458 free base Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
229910001411 inorganic cation Inorganic materials 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000006028 limestone Substances 0.000 description 1
239000010808 liquid waste Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical group [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
238000003303 reheating Methods 0.000 description 1
239000012508 resin bead Substances 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000013049 sediment Substances 0.000 description 1
238000004088 simulation Methods 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000010530 solution phase reaction Methods 0.000 description 1
239000002594 sorbent Substances 0.000 description 1
WQDSRJBTLILEEK-UHFFFAOYSA-N sulfurous acid Chemical compound OS(O)=O.OS(O)=O WQDSRJBTLILEEK-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
150000003512 tertiary amines Chemical group 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
239000010409 thin film Substances 0.000 description 1
239000002341 toxic gas Substances 0.000 description 1
KRURGYOKPVLRHQ-UHFFFAOYSA-L trithionate(2-) Chemical compound [O-]S(=O)(=O)SS([O-])(=O)=O KRURGYOKPVLRHQ-UHFFFAOYSA-L 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000002918 waste heat Substances 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Treating Waste Gases (AREA)

CA298,483A 1977-03-25 1978-03-08 Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions Expired CA1106576A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US78116677A	1977-03-25	1977-03-25
US781,166		1985-09-30

Publications (1)

Publication Number	Publication Date
CA1106576A true CA1106576A (fr)	1981-08-11

Family

ID=25121903

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA298,483A Expired CA1106576A (fr)	1977-03-25	1978-03-08	Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions

Country Status (9)

Country	Link
JP (1)	JPS53119275A (fr)
AU (1)	AU3435178A (fr)
BE (1)	BE865330A (fr)
CA (1)	CA1106576A (fr)
DE (1)	DE2812839A1 (fr)
FR (1)	FR2384714A1 (fr)
GB (1)	GB1598999A (fr)
MX (1)	MX5276E (fr)
NL (1)	NL7803172A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2017184591A1 (fr) *	2016-04-18	2017-10-26	Mecs, Inc.	Élimination de sulfate à partir de solutions de solvant à l'aide d'une résine d'échange d'anions
US9884289B2 (en)	2013-03-15	2018-02-06	Mecs Inc	Regenerative recovery of contaminants from effluent gases
US11185812B2 (en)	2010-10-29	2021-11-30	Mecs, Inc.	Regenerative recovery of sulfur dioxide from effluent gases

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Publication number	Priority date	Publication date	Assignee	Title
CA1168027A (fr) *	1980-05-27	1984-05-29	Union Carbide Corporation	Procede a regeneration pour l'extraction selective de l'anhydride sulfureux des gaz d'echappement
NL8400108A (nl) *	1984-01-12	1985-08-01	Hooft Eric T	Werkwijze en inrichting voor het behandelen van een lichaamsdeel met radioactief materiaal.
FR2697171B1 (fr) *	1992-10-28	1994-12-16	Paris Pavage Asphaltes	Procédé et installation de traitement d'effluents gazeux de brassage à chaud de produits bitumineux .
US7776296B2 (en) *	2006-03-10	2010-08-17	Cansolv Technologies Inc.	Regeneration of ion exchangers that are used for salt removal from acid gas capture plants
JP4895769B2 (ja) *	2006-11-16	2012-03-14	株式会社メディディア	テープホルダ
US8063112B2 (en) *	2008-12-08	2011-11-22	Cansolv Technologies Inc.	Process for the regeneration of an ion exchange resin using sulfurous acid
JP5660303B2 (ja) *	2010-11-18	2015-01-28	栗田エンジニアリング株式会社	アミン液の再生方法
CN102489153A (zh) *	2011-11-24	2012-06-13	王传良	四甲基胍羟基酸盐复合脱硫剂在烟气脱硫中的再生方法

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US1639905A (en) *	1921-04-04	1927-08-23	Koppers Co Inc	Manufacture of sodium thiosulphate
DE1030315B (de) *	1954-04-12	1958-05-22	Willi Peter Dipl Ing	Verfahren zum Auswaschen und Gewinnen von Schwefeldioxyd und gegebenenfalls anderen schwach loeslichen sauren Gasen
FR95415E (fr) *	1967-12-28	1970-11-06	Ugine Kuhlmann	Procédé et dispositif pour la récupération de l'anhydride sulfureux se trouvant a de tres faibles concentrations dans des gaz résiduaires.
FR2161188A6 (fr) *	1971-06-08	1973-07-06	Inst Francais Du Petrole
CA1001568A (en) *	1971-07-21	1976-12-14	Robert Kunin	Removal of sulfur trioxide and acid mist from gaseous streams
US3904735A (en) *	1972-03-07	1975-09-09	Union Carbide Corp	Process for the selective removal of sulfur dioxide from effluent gases
JPS4972196A (fr) *	1972-10-04	1974-07-12
US3879521A (en) *	1973-01-02	1975-04-22	Diamond Shamrock Corp	Removal of SO{HD 2 {B from flue gas
JPS5333196A (en) *	1976-09-09	1978-03-28	Tokyo Electric Co Ltd	Printer

1978
- 1978-03-08 CA CA298,483A patent/CA1106576A/fr not_active Expired
- 1978-03-17 MX MX786938U patent/MX5276E/es unknown
- 1978-03-21 AU AU34351/78A patent/AU3435178A/en active Pending
- 1978-03-23 NL NL7803172A patent/NL7803172A/xx not_active Application Discontinuation
- 1978-03-23 GB GB11554/78A patent/GB1598999A/en not_active Expired
- 1978-03-23 DE DE19782812839 patent/DE2812839A1/de not_active Withdrawn
- 1978-03-24 BE BE186286A patent/BE865330A/fr not_active IP Right Cessation
- 1978-03-24 JP JP3319578A patent/JPS53119275A/ja active Pending
- 1978-03-24 FR FR7808599A patent/FR2384714A1/fr not_active Withdrawn

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11185812B2 (en)	2010-10-29	2021-11-30	Mecs, Inc.	Regenerative recovery of sulfur dioxide from effluent gases
US9884289B2 (en)	2013-03-15	2018-02-06	Mecs Inc	Regenerative recovery of contaminants from effluent gases
WO2017184591A1 (fr) *	2016-04-18	2017-10-26	Mecs, Inc.	Élimination de sulfate à partir de solutions de solvant à l'aide d'une résine d'échange d'anions

Also Published As

Publication number	Publication date
DE2812839A1 (de)	1978-09-28
JPS53119275A (en)	1978-10-18
FR2384714A1 (fr)	1978-10-20
GB1598999A (en)	1981-09-30
BE865330A (fr)	1978-09-25
MX5276E (es)	1983-05-31
NL7803172A (nl)	1978-09-27
AU3435178A (en)	1979-09-27

Legal Events

Date	Code	Title	Description
1998-08-11	MKEX	Expiry

Publication	Publication Date	Title
US4170628A (en)	1979-10-09	Process for removing SO2 from effluent gases and for removing heat stable salts from systems in which they accumulate using an anion exchange resin
CA1106152A (fr)	1981-08-04	Methode d'extraction du so.sub.2 en presence dans des gaz d'echappement, et pour l'extraction de sels thermostables des systemes dans lesquels ils s'accumulent
CA1106147A (fr)	1981-08-04	Recuperation du soufre contenu dans des effluents gazeux comportant du sulfure d'hydrogene
US4385039A (en)	1983-05-24	Process for removal of sulfur oxides from waste gases
CN104519979B (zh)	2017-06-09	排出气体中污染物的再生回收
CN105209157B (zh)	2018-05-01	废气中污染物的再生回收
CA1259165A (fr)	1989-09-12	Methode de depollution des gaz d'echappement
RU2742639C2 (ru)	2021-02-09	Удаление сульфата из растворителей анионообменной смолой
CA1106576A (fr)	1981-08-11	Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions
WO2012058558A2 (fr)	2012-05-03	Récupération régénérative du dioxyde de soufre présent dans des effluents gazeux
US4071602A (en)	1978-01-31	Selective separation of sulfur oxides from carbon dioxide in an effluent gas stream
US4389383A (en)	1983-06-21	Regenerable process for the selective removal of sulfur dioxide from effluent gases
US3833711A (en)	1974-09-03	Removal of sulfur dioxide from gas streams
US4510124A (en)	1985-04-09	System for recovery of CO2 from flue gases containing SO2
US4448899A (en)	1984-05-15	Process for removing SOx and NOx compounds from gas streams
US3767777A (en)	1973-10-23	Method of separating sulfur dioxide from gaseous mixtures
US4481172A (en)	1984-11-06	Process for removal of sulfur oxides from waste gases
CA1047739A (fr)	1979-02-06	Methode d'extraction des gaz a teneur de soufre en presence dans les gaz perdus
US3879521A (en)	1975-04-22	Removal of SO{HD 2 {B from flue gas
US4377557A (en)	1983-03-22	Process for removal of sulfur oxides from waste gases
US4442083A (en)	1984-04-10	Method of desulfurizing waste gases containing sulfur dioxide
CA1168027A (fr)	1984-05-29	Procede a regeneration pour l'extraction selective de l'anhydride sulfureux des gaz d'echappement
US4372932A (en)	1983-02-08	Process for removing SOx and NOx compounds from gas streams
US4201752A (en)	1980-05-06	Process for the selective removal of sulfur dioxide from effluent gases
US4837001A (en)	1989-06-06	Production of sulfur from sulfur dioxide obtained from flue gas

CA1106576A - Methode d'extraction du so.sub.2 des gaz d'echappement, et d'extraction des sels thermostables des systemes dans lesquels ils s'accumulent a l'aide d'une resine echangeuse d'ions - Google Patents

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Cited By (3)

Families Citing this family (8)

Family Cites Families (9)

Cited By (3)

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