CA1106673A - Images formees par la decomposition de composes de coordination de te (ii) - Google Patents

Images formees par la decomposition de composes de coordination de te (ii)

Info

Publication number: CA1106673A
Authority: CA; Canada
Prior art keywords: complex; tellurium; nuclei; ligands; image
Prior art date: 1976-07-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA280,163A

Other languages

English (en)

Inventor

Henry J. Gysling

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-07-08

Filing date

1977-06-09

Publication date

1981-08-11

1977-06-09 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1981-08-11 Application granted granted Critical

1981-08-11 Publication of CA1106673A publication Critical patent/CA1106673A/fr

Status Expired legal-status Critical Current

Links

238000000354 decomposition reaction Methods 0.000 title claims abstract description 8
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims abstract description 126
229910052714 tellurium Inorganic materials 0.000 claims abstract description 119
239000003446 ligand Substances 0.000 claims abstract description 83
229910052717 sulfur Inorganic materials 0.000 claims abstract description 50
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 47
239000011593 sulfur Substances 0.000 claims abstract description 47
230000007935 neutral effect Effects 0.000 claims abstract description 18
125000000129 anionic group Chemical group 0.000 claims abstract description 13
238000000034 method Methods 0.000 claims description 35
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 33
230000008569 process Effects 0.000 claims description 27
150000001875 compounds Chemical class 0.000 claims description 24
229910052709 silver Inorganic materials 0.000 claims description 22
239000002904 solvent Substances 0.000 claims description 19
230000003197 catalytic effect Effects 0.000 claims description 18
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 17
238000010438 heat treatment Methods 0.000 claims description 14
150000004696 coordination complex Chemical class 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
230000015572 biosynthetic process Effects 0.000 claims description 10
239000002879 Lewis base Substances 0.000 claims description 8
150000007527 lewis bases Chemical class 0.000 claims description 8
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 6
229910052802 copper Inorganic materials 0.000 claims description 6
AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 5
DZZWKUMHMSNBSG-UHFFFAOYSA-N 1,3-bis(prop-2-enyl)thiourea Chemical compound C=CCNC(=S)NCC=C DZZWKUMHMSNBSG-UHFFFAOYSA-N 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
DTMHTVJOHYTUHE-UHFFFAOYSA-N thiocyanogen Chemical compound N#CSSC#N DTMHTVJOHYTUHE-UHFFFAOYSA-N 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 claims description 2
230000002269 spontaneous effect Effects 0.000 claims description 2
125000004151 quinonyl group Chemical group 0.000 claims 1
229940100890 silver compound Drugs 0.000 claims 1
150000003379 silver compounds Chemical class 0.000 claims 1
239000003054 catalyst Substances 0.000 abstract description 7
150000004695 complexes Chemical class 0.000 abstract description 2
239000000243 solution Substances 0.000 description 50
-1 silver halide Chemical class 0.000 description 47
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 27
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 21
239000004332 silver Substances 0.000 description 18
239000005020 polyethylene terephthalate Substances 0.000 description 16
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
229920000139 polyethylene terephthalate Polymers 0.000 description 15
239000011248 coating agent Substances 0.000 description 14
238000000576 coating method Methods 0.000 description 14
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
239000007864 aqueous solution Substances 0.000 description 11
239000003638 chemical reducing agent Substances 0.000 description 11
239000010949 copper Substances 0.000 description 11
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 10
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 9
229910052753 mercury Inorganic materials 0.000 description 9
238000012545 processing Methods 0.000 description 9
238000006722 reduction reaction Methods 0.000 description 9
239000012043 crude product Substances 0.000 description 8
238000011161 development Methods 0.000 description 8
229910052763 palladium Inorganic materials 0.000 description 8
230000009467 reduction Effects 0.000 description 8
239000011230 binding agent Substances 0.000 description 7
239000000047 product Substances 0.000 description 7
229920002554 vinyl polymer Polymers 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
230000003321 amplification Effects 0.000 description 6
229920006217 cellulose acetate butyrate Polymers 0.000 description 6
230000003138 coordinated effect Effects 0.000 description 6
238000009826 distribution Methods 0.000 description 6
238000003199 nucleic acid amplification method Methods 0.000 description 6
125000005843 halogen group Chemical group 0.000 description 5
238000003384 imaging method Methods 0.000 description 5
239000000463 material Substances 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
150000003497 tellurium Chemical class 0.000 description 5
238000005979 thermal decomposition reaction Methods 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
UPLMJIUMVHVVAB-UHFFFAOYSA-N 2-propan-2-yloxynaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(OC(C)C)=CC(=O)C2=C1 UPLMJIUMVHVVAB-UHFFFAOYSA-N 0.000 description 4
229910003069 TeO2 Inorganic materials 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
239000011521 glass Substances 0.000 description 4
LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 4
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
239000008199 coating composition Substances 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000007323 disproportionation reaction Methods 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
238000007654 immersion Methods 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
239000002243 precursor Substances 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
230000001603 reducing effect Effects 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
125000004434 sulfur atom Chemical group 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
150000003585 thioureas Chemical class 0.000 description 3
FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000007983 Tris buffer Substances 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000002585 base Substances 0.000 description 2
KSTSKZBJCVLLKS-UHFFFAOYSA-N benzene;propan-2-ol Chemical compound CC(C)O.C1=CC=CC=C1 KSTSKZBJCVLLKS-UHFFFAOYSA-N 0.000 description 2
239000012990 dithiocarbamate Substances 0.000 description 2
150000004659 dithiocarbamates Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
238000007429 general method Methods 0.000 description 2
229960004337 hydroquinone Drugs 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
150000002484 inorganic compounds Chemical class 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
238000003475 lamination Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000005649 metathesis reaction Methods 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000000203 mixture Substances 0.000 description 2
CSOYVKQCJFQSMZ-OUCADQQQSA-N n-[9-[(2r,4s,5r)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-6-oxo-3h-purin-2-yl]-2-phenoxyacetamide Chemical compound C1[C@H](O)[C@@H](CO)O[C@H]1N1C(N=C(NC(=O)COC=2C=CC=CC=2)NC2=O)=C2N=C1 CSOYVKQCJFQSMZ-OUCADQQQSA-N 0.000 description 2
125000001624 naphthyl group Chemical group 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
150000002940 palladium Chemical class 0.000 description 2
238000001953 recrystallisation Methods 0.000 description 2
238000011160 research Methods 0.000 description 2
239000010944 silver (metal) Substances 0.000 description 2
MQRWPMGRGIILKQ-UHFFFAOYSA-N sodium telluride Chemical compound [Na][Te][Na] MQRWPMGRGIILKQ-UHFFFAOYSA-N 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
239000012991 xanthate Substances 0.000 description 2
JFHXWMRFXORESD-UHFFFAOYSA-N 1-phenyl-3-pyridin-2-ylthiourea Chemical compound C=1C=CC=NC=1NC(=S)NC1=CC=CC=C1 JFHXWMRFXORESD-UHFFFAOYSA-N 0.000 description 1
ZAMUDYFFFFHBNY-UHFFFAOYSA-N 10-diazonioanthracen-9-olate Chemical class C1=CC=C2C([O-])=C(C=CC=C3)C3=C([N+]#N)C2=C1 ZAMUDYFFFFHBNY-UHFFFAOYSA-N 0.000 description 1
GEOQDCBHAVUVST-UHFFFAOYSA-N 10-diazoniophenanthren-9-olate Chemical class C1=CC=C2C([O-])=C([N+]#N)C3=CC=CC=C3C2=C1 GEOQDCBHAVUVST-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
VSTRESXSGAUGKC-UHFFFAOYSA-N 4H-benzimidazole Chemical class C1C=CC=C2N=CN=C12 VSTRESXSGAUGKC-UHFFFAOYSA-N 0.000 description 1
PIVQQUNOTICCSA-UHFFFAOYSA-N ANTU Chemical compound C1=CC=C2C(NC(=S)N)=CC=CC2=C1 PIVQQUNOTICCSA-UHFFFAOYSA-N 0.000 description 1
ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229930192627 Naphthoquinone Natural products 0.000 description 1
239000000020 Nitrocellulose Substances 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
206010034972 Photosensitivity reaction Diseases 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
MNOILHPDHOHILI-UHFFFAOYSA-N Tetramethylthiourea Chemical compound CN(C)C(=S)N(C)C MNOILHPDHOHILI-UHFFFAOYSA-N 0.000 description 1
150000001224 Uranium Chemical class 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001541 aziridines Chemical class 0.000 description 1
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
229910001864 baryta Inorganic materials 0.000 description 1
RAMQAMYGQDRQKW-UHFFFAOYSA-N benzene;butan-1-ol Chemical compound CCCCO.C1=CC=CC=C1 RAMQAMYGQDRQKW-UHFFFAOYSA-N 0.000 description 1
150000001556 benzimidazoles Chemical class 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229920002301 cellulose acetate Polymers 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
150000004699 copper complex Chemical class 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
OKGXJRGLYVRVNE-UHFFFAOYSA-N diaminomethylidenethiourea Chemical compound NC(N)=NC(N)=S OKGXJRGLYVRVNE-UHFFFAOYSA-N 0.000 description 1
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
239000012954 diazonium Substances 0.000 description 1
150000001989 diazonium salts Chemical class 0.000 description 1
FHHZOYXKOICLGH-UHFFFAOYSA-N dichloromethane;ethanol Chemical compound CCO.ClCCl FHHZOYXKOICLGH-UHFFFAOYSA-N 0.000 description 1
TYWAKIKWTGMYJY-UHFFFAOYSA-N dicyclohexyl-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound C1CCCCC1P(=S)(S)C1CCCCC1 TYWAKIKWTGMYJY-UHFFFAOYSA-N 0.000 description 1
IRDLUHRVLVEUHA-UHFFFAOYSA-N diethyl dithiophosphate Chemical compound CCOP(S)(=S)OCC IRDLUHRVLVEUHA-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
150000002019 disulfides Chemical class 0.000 description 1
ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
229960004642 ferric ammonium citrate Drugs 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
238000005213 imbibition Methods 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
125000002346 iodo group Chemical group I* 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
235000000011 iron ammonium citrate Nutrition 0.000 description 1
239000004313 iron ammonium citrate Substances 0.000 description 1
125000001518 isoselenocyanato group Chemical group *N=C=[Se] 0.000 description 1
125000000239 isotellurocyanato group Chemical group *N=C=[Te] 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
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238000002844 melting Methods 0.000 description 1
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NIQQIJXGUZVEBB-UHFFFAOYSA-N methanol;propan-2-one Chemical compound OC.CC(C)=O NIQQIJXGUZVEBB-UHFFFAOYSA-N 0.000 description 1
125000004092 methylthiomethyl group Chemical group [H]C([H])([H])SC([H])([H])* 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
UICCSKORMGVRCB-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]-n',n'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCNCCN(CC)CC UICCSKORMGVRCB-UHFFFAOYSA-N 0.000 description 1
150000002791 naphthoquinones Chemical class 0.000 description 1
229920001220 nitrocellulos Polymers 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
BMBJSXKEXRFGAV-UHFFFAOYSA-N phenylcarbamothioic s-acid Chemical compound SC(=O)NC1=CC=CC=C1 BMBJSXKEXRFGAV-UHFFFAOYSA-N 0.000 description 1
238000007540 photo-reduction reaction Methods 0.000 description 1
238000006303 photolysis reaction Methods 0.000 description 1
230000036211 photosensitivity Effects 0.000 description 1
230000015843 photosynthesis, light reaction Effects 0.000 description 1
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
229920006289 polycarbonate film Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
ZMWBGRXFDPJFGC-UHFFFAOYSA-M potassium;propan-2-yloxymethanedithioate Chemical compound [K+].CC(C)OC([S-])=S ZMWBGRXFDPJFGC-UHFFFAOYSA-M 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 1
SLUHLANJIVXTRQ-UHFFFAOYSA-N pyridin-2-ylthiourea Chemical compound NC(=S)NC1=CC=CC=N1 SLUHLANJIVXTRQ-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000012260 resinous material Substances 0.000 description 1
230000004044 response Effects 0.000 description 1
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
238000002791 soaking Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000002311 subsequent effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
GWIKYPMLNBTJHR-UHFFFAOYSA-M thiosulfonate group Chemical group S(=S)(=O)[O-] GWIKYPMLNBTJHR-UHFFFAOYSA-M 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
AUALKMYBYGCYNY-UHFFFAOYSA-E triazanium;2-hydroxypropane-1,2,3-tricarboxylate;iron(3+) Chemical compound [NH4+].[NH4+].[NH4+].[Fe+3].[Fe+3].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O AUALKMYBYGCYNY-UHFFFAOYSA-E 0.000 description 1
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
238000010792 warming Methods 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/58—Processes for obtaining metallic images by vapour deposition or physical development
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
- G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
- G03C1/734—Tellurium or selenium compounds
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/56—Processes using photosensitive compositions covered by the groups G03C1/64 - G03C1/72 or agents therefor

Landscapes

Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

CA280,163A 1976-07-08 1977-06-09 Images formees par la decomposition de composes de coordination de te (ii) Expired CA1106673A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US70340576A	1976-07-08	1976-07-08
US703,405		1976-07-08

Publications (1)

Publication Number	Publication Date
CA1106673A true CA1106673A (fr)	1981-08-11

Family

ID=24825252

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA280,163A Expired CA1106673A (fr)	1976-07-08	1977-06-09	Images formees par la decomposition de composes de coordination de te (ii)

Country Status (6)

Country	Link
JP (1)	JPS537227A (fr)
BE (1)	BE856655A (fr)
CA (1)	CA1106673A (fr)
DE (1)	DE2730970A1 (fr)
FR (1)	FR2357933A1 (fr)
GB (1)	GB1574787A (fr)

1977
- 1977-06-09 CA CA280,163A patent/CA1106673A/fr not_active Expired
- 1977-07-07 FR FR7720875A patent/FR2357933A1/fr active Granted
- 1977-07-08 JP JP8187777A patent/JPS537227A/ja active Pending
- 1977-07-08 BE BE179221A patent/BE856655A/fr not_active IP Right Cessation
- 1977-07-08 GB GB2879377A patent/GB1574787A/en not_active Expired
- 1977-07-08 DE DE19772730970 patent/DE2730970A1/de not_active Withdrawn

Also Published As

Publication number	Publication date
GB1574787A (en)	1980-09-10
FR2357933B1 (fr)	1979-03-30
DE2730970A1 (de)	1978-01-12
FR2357933A1 (fr)	1978-02-03
JPS537227A (en)	1978-01-23
BE856655A (fr)	1978-01-09

Legal Events

Date	Code	Title	Description
1998-08-11	MKEX	Expiry

Publication	Publication Date	Title
US4152155A (en)	1979-05-01	Organotellurium (II) and (IV) compounds in heat-developable imaging materials and process with physically developable nuclei
CA1051705A (fr)	1979-04-03	Formation d'images au moyen d'un complexe a metal de transition a gain eleve
US4188218A (en)	1980-02-12	Images formed by decomposition of Te (II) coordination complexes
US3887374A (en)	1975-06-03	Tetrazolium alt photoreductive imaging
US4251623A (en)	1981-02-17	Imaging process involving thermal decomposition of Te(II) coordination complexes
US3859092A (en)	1975-01-07	Photographic systems based on photosensitive copper (i) complexes
US3880659A (en)	1975-04-29	Triazolium salt photoreductive imaging
US3887372A (en)	1975-06-03	Photographic elements and processes for producing formazan dye images of enhanced stability
CA1148013A (fr)	1983-06-14	Composition de visualisation au tellure, renfermant un glycerol-ether ou un glycerol-thioether, comme source d'hydrogene labile pour un precurseur de reduction
US4258128A (en)	1981-03-24	Tellurium(II) compounds and complexes having organic moieties containing silicon containing compositions, articles and photoimaging processes
US4239846A (en)	1980-12-16	Tellurium (IV) compounds and compositions
US3860501A (en)	1975-01-14	Photosensitive copper (i) complexes and the use thereof in photographic development
CA1101261A (fr)	1981-05-19	Traduction non-disponible
US3510308A (en)	1970-05-05	Light sensitive complexes of benzoindolinospiropyrans and halides of group ii-b metals
JPS5922048A (ja)	1984-02-04	還元剤先駆物質を含む画像形成組成物および方法
GB1574787A (en)	1980-09-10	Process of making tellurium images
US4208478A (en)	1980-06-17	Tellurium(II) photographic materials
US4187240A (en)	1980-02-05	Process for preparing tellurium(II) materials
US4178180A (en)	1979-12-11	Copper physical development using heterocyclic ligand copper (I) complexes
CA1134663A (fr)	1982-11-02	Formation de composes physiques du cuivre au moyen de complexes de cuivre (i) et de ligandes heterocycliques
US4355097A (en)	1982-10-19	Tellurium (IV) compounds and compositions
US3661574A (en)	1972-05-09	A photographic process with an amine metavanadate
US4698184A (en)	1987-10-06	Tellurium imaging composition including improved reductant precursor and method
US4532078A (en)	1985-07-30	Reductant precursor for tellurium imaging compositions
US3927055A (en)	1975-12-16	Photosensitive copper (I) complexes