CA1106724A - Aqueous acid solution gelling agents - Google Patents

Aqueous acid solution gelling agents

Info

Publication number: CA1106724A
Authority: CA; Canada
Prior art keywords: range; acid; solution; carbon atoms; gelling agent
Prior art date: 1978-01-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA313,028A

Other languages

English (en)

French (fr)

Inventor

Lewis R. Norman

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Halliburton Co

Original Assignee

Halliburton Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-01-23

Filing date

1978-10-10

Publication date

1981-08-11

1978-10-10 Application filed by Halliburton Co filed Critical Halliburton Co

1981-08-11 Application granted granted Critical

1981-08-11 Publication of CA1106724A publication Critical patent/CA1106724A/en

Status Expired legal-status Critical Current

Links

239000003349 gelling agent Substances 0.000 title claims abstract description 68
239000011260 aqueous acid Substances 0.000 title abstract description 41
150000001412 amines Chemical class 0.000 claims abstract description 54
239000000203 mixture Substances 0.000 claims abstract description 45
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
239000003960 organic solvent Substances 0.000 claims abstract description 19
150000007522 mineralic acids Chemical class 0.000 claims abstract description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 36
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
229920006395 saturated elastomer Polymers 0.000 claims description 9
125000001931 aliphatic group Chemical group 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
150000002576 ketones Chemical class 0.000 claims description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
150000002170 ethers Chemical class 0.000 claims description 4
125000003158 alcohol group Chemical group 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
150000002596 lactones Chemical class 0.000 claims description 3
239000000243 solution Substances 0.000 description 151
239000002253 acid Substances 0.000 description 98
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 83
229960000443 hydrochloric acid Drugs 0.000 description 39
235000011167 hydrochloric acid Nutrition 0.000 description 39
230000015572 biosynthetic process Effects 0.000 description 29
238000005755 formation reaction Methods 0.000 description 29
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 24
150000007513 acids Chemical class 0.000 description 12
230000001965 increasing effect Effects 0.000 description 12
239000003760 tallow Substances 0.000 description 10
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 9
229960000583 acetic acid Drugs 0.000 description 9
239000001110 calcium chloride Substances 0.000 description 9
229910001628 calcium chloride Inorganic materials 0.000 description 9
239000000499 gel Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
235000010469 Glycine max Nutrition 0.000 description 6
244000068988 Glycine max Species 0.000 description 6
235000019738 Limestone Nutrition 0.000 description 6
230000007797 corrosion Effects 0.000 description 6
238000005260 corrosion Methods 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
239000006028 limestone Substances 0.000 description 6
238000000034 method Methods 0.000 description 6
238000002156 mixing Methods 0.000 description 6
239000000126 substance Substances 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
206010017076 Fracture Diseases 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
150000007524 organic acids Chemical class 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
238000011282 treatment Methods 0.000 description 5
239000010459 dolomite Substances 0.000 description 4
229910000514 dolomite Inorganic materials 0.000 description 4
229940093915 gynecological organic acid Drugs 0.000 description 4
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
235000005985 organic acids Nutrition 0.000 description 4
238000000926 separation method Methods 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
208000010392 Bone Fractures Diseases 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
239000000654 additive Substances 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
239000012362 glacial acetic acid Substances 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
239000011148 porous material Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
-1 beta-propyl lactone Chemical class 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000012530 fluid Substances 0.000 description 2
235000019253 formic acid Nutrition 0.000 description 2
239000000174 gluconic acid Substances 0.000 description 2
235000012208 gluconic acid Nutrition 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000035699 permeability Effects 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
244000089742 Citrus aurantifolia Species 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
229940005991 chloric acid Drugs 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000003925 fat Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
229950006191 gluconic acid Drugs 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
150000002440 hydroxy compounds Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
229930189585 ingamine Natural products 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229940040102 levulinic acid Drugs 0.000 description 1
239000004571 lime Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
229940095574 propionic acid Drugs 0.000 description 1
238000005086 pumping Methods 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/06—Solidifying liquids
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/72—Eroding chemicals, e.g. acids
- C09K8/74—Eroding chemicals, e.g. acids combined with additives added for specific purposes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
General Life Sciences & Earth Sciences (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Colloid Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA313,028A 1978-01-23 1978-10-10 Aqueous acid solution gelling agents Expired CA1106724A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US87173678A	1978-01-23	1978-01-23
US871,736		1997-06-09

Publications (1)

Publication Number	Publication Date
CA1106724A true CA1106724A (en)	1981-08-11

Family

ID=25358016

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA313,028A Expired CA1106724A (en)	1978-01-23	1978-10-10	Aqueous acid solution gelling agents

Country Status (7)

Country	Link
AU (1)	AU4068778A (pt)
BR (1)	BR7807830A (pt)
CA (1)	CA1106724A (pt)
FR (1)	FR2415139A1 (pt)
IT (1)	IT1110842B (pt)
NO (1)	NO790211L (pt)
PT (1)	PT68629A (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NO170944C (no) *	1987-01-24	1992-12-30	Akzo Nv	Fortykkede, vandige preparater, samt anvendelse av slike

1978
- 1978-10-09 PT PT68629A patent/PT68629A/pt unknown
- 1978-10-10 CA CA313,028A patent/CA1106724A/en not_active Expired
- 1978-10-13 AU AU40687/78A patent/AU4068778A/en active Pending
- 1978-11-02 FR FR7831061A patent/FR2415139A1/fr not_active Withdrawn
- 1978-11-29 BR BR7807830A patent/BR7807830A/pt unknown
1979
- 1979-01-22 NO NO790211A patent/NO790211L/no unknown
- 1979-01-23 IT IT19543/79A patent/IT1110842B/it active

Also Published As

Publication number	Publication date
IT7919543A0 (it)	1979-01-23
PT68629A (en)	1978-11-01
BR7807830A (pt)	1979-07-31
IT1110842B (it)	1986-01-06
AU4068778A (en)	1980-04-17
FR2415139A1 (fr)	1979-08-17
NO790211L (no)	1979-07-24

Legal Events

Date	Code	Title	Description
1998-08-11	MKEX	Expiry

Publication	Publication Date	Title
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US4542790A (en)	1985-09-24	Process for extracting extensively emulsion-free oil from a subterranean reservoir
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