CA1110064A - Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable - Google Patents

Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable

Info

Publication number: CA1110064A
Authority: CA; Canada
Prior art keywords: hydrophobic; hydrophilic; emulsion component; liquid; wall
Prior art date: 1977-03-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA296,117A

Other languages

English (en)

Inventor

Yu-Sun Lee

Dale R. Shackle

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mead Corp

Original Assignee

Mead Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-03-03

Filing date

1978-01-31

Publication date

1981-10-06

1978-01-31 Application filed by Mead Corp filed Critical Mead Corp

1981-10-06 Application granted granted Critical

1981-10-06 Publication of CA1110064A publication Critical patent/CA1110064A/fr

Status Expired legal-status Critical Current

Links

230000005855 radiation Effects 0.000 title claims abstract description 77
239000003094 microcapsule Substances 0.000 title claims abstract description 58
238000000034 method Methods 0.000 title claims abstract description 45
230000008569 process Effects 0.000 title claims abstract description 37
238000011065 in-situ storage Methods 0.000 title description 4
239000011230 binding agent Substances 0.000 title description 3
239000007788 liquid Substances 0.000 claims abstract description 131
239000000463 material Substances 0.000 claims abstract description 100
230000002209 hydrophobic effect Effects 0.000 claims abstract description 94
239000000839 emulsion Substances 0.000 claims abstract description 78
238000000576 coating method Methods 0.000 claims abstract description 43
239000011248 coating agent Substances 0.000 claims abstract description 33
239000008199 coating composition Substances 0.000 claims abstract description 31
239000000758 substrate Substances 0.000 claims abstract description 26
238000012546 transfer Methods 0.000 claims abstract description 25
239000006185 dispersion Substances 0.000 claims abstract description 23
238000004519 manufacturing process Methods 0.000 claims abstract description 23
239000002775 capsule Substances 0.000 claims abstract description 15
238000013019 agitation Methods 0.000 claims abstract description 13
239000011162 core material Substances 0.000 claims abstract description 9
229920005989 resin Polymers 0.000 claims abstract description 8
239000011347 resin Substances 0.000 claims abstract description 8
239000003995 emulsifying agent Substances 0.000 claims abstract description 7
238000002156 mixing Methods 0.000 claims abstract description 7
210000002421 cell wall Anatomy 0.000 claims abstract 5
150000001875 compounds Chemical class 0.000 claims description 33
239000000203 mixture Substances 0.000 claims description 30
150000002894 organic compounds Chemical class 0.000 claims description 12
239000005056 polyisocyanate Substances 0.000 claims description 6
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RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 5
229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 5
IHIXIJGXTJIKRB-UHFFFAOYSA-N trisodium vanadate Chemical compound [Na+].[Na+].[Na+].[O-][V]([O-])([O-])=O IHIXIJGXTJIKRB-UHFFFAOYSA-N 0.000 claims description 5
XGGLLRJQCZROSE-UHFFFAOYSA-K ammonium iron(iii) sulfate Chemical group [NH4+].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGGLLRJQCZROSE-UHFFFAOYSA-K 0.000 claims description 3
230000005865 ionizing radiation Effects 0.000 claims description 3
HOIQWTMREPWSJY-GNOQXXQHSA-K iron(3+);(z)-octadec-9-enoate Chemical compound [Fe+3].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O HOIQWTMREPWSJY-GNOQXXQHSA-K 0.000 claims description 3
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate Chemical compound [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 3
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 2
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 2
SVOAENZIOKPANY-UHFFFAOYSA-L copper;octadec-9-enoate Chemical compound [Cu+2].CCCCCCCCC=CCCCCCCCC([O-])=O.CCCCCCCCC=CCCCCCCCC([O-])=O SVOAENZIOKPANY-UHFFFAOYSA-L 0.000 claims description 2
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239000012948 isocyanate Substances 0.000 claims 3
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239000000306 component Substances 0.000 description 17
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239000002904 solvent Substances 0.000 description 8
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 7
MTPIQEWGULCIPM-UHFFFAOYSA-N 2-ethylhexyl 3,4,5-trihydroxybenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC(O)=C(O)C(O)=C1 MTPIQEWGULCIPM-UHFFFAOYSA-N 0.000 description 7
239000000126 substance Substances 0.000 description 7
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 6
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238000002360 preparation method Methods 0.000 description 6
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238000004945 emulsification Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
NWGKJDSIEKMTRX-BFWOXRRGSA-N [(2r)-2-[(3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)C1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-BFWOXRRGSA-N 0.000 description 4
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238000006243 chemical reaction Methods 0.000 description 4
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239000000835 fiber Substances 0.000 description 4
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150000003254 radicals Chemical class 0.000 description 4
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
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RXDYOLRABMJTEF-UHFFFAOYSA-N 2-chloro-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(Cl)C(=O)C1=CC=CC=C1 RXDYOLRABMJTEF-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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239000012153 distilled water Substances 0.000 description 3
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239000003960 organic solvent Substances 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
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235000008411 Sumatra benzointree Nutrition 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
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RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
239000012965 benzophenone Substances 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
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229910052753 mercury Inorganic materials 0.000 description 2
YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 2
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DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
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239000000178 monomer Substances 0.000 description 1
150000002780 morpholines Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
DASJFYAPNPUBGG-UHFFFAOYSA-N naphthalene-1-sulfonyl chloride Chemical compound C1=CC=C2C(S(=O)(=O)Cl)=CC=CC2=C1 DASJFYAPNPUBGG-UHFFFAOYSA-N 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
229940117969 neopentyl glycol Drugs 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920006255 plastic film Polymers 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920006254 polymer film Polymers 0.000 description 1
150000008442 polyphenolic compounds Chemical class 0.000 description 1
235000013824 polyphenols Nutrition 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000000276 potassium ferrocyanide Substances 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000000644 propagated effect Effects 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
241000894007 species Species 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
229940035718 sular Drugs 0.000 description 1
235000015523 tannic acid Nutrition 0.000 description 1
229940033123 tannic acid Drugs 0.000 description 1
229920002258 tannic acid Polymers 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 1
229960001124 trientine Drugs 0.000 description 1
JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
229960000834 vinyl ether Drugs 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
239000002025 wood fiber Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/10—Complex coacervation, i.e. interaction of oppositely charged particles
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Color Printing (AREA)
Manufacturing Of Micro-Capsules (AREA)
Paints Or Removers (AREA)

CA296,117A 1977-03-03 1978-01-31 Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable Expired CA1110064A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US77390177A	1977-03-03	1977-03-03
US773,901		1977-03-03

Publications (1)

Publication Number	Publication Date
CA1110064A true CA1110064A (fr)	1981-10-06

Family

ID=25099668

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA296,117A Expired CA1110064A (fr)	1977-03-03	1978-01-31	Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable

Country Status (4)

Country	Link
JP (1)	JPS53109709A (fr)
CA (1)	CA1110064A (fr)
DE (1)	DE2808904A1 (fr)
GB (1)	GB1601194A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN114746277B (zh) *	2019-10-11	2024-04-09	多哈科技大学	在环境条件下快速无汞光化学微包封/纳米包封

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2692812B1 (fr) *	1992-06-24	1994-12-30	Flamel Tech Sa	Microcapsules contenant au moins un principe actif, leurs applications et procédé de préparation de microcapsules renfermant au moins un principe actif.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE790373A (fr) *	1971-10-21	1973-02-15	Fuji Photo Film Co Ltd	Feuille d'enregistrement sensible a la pression comportant des micro-capsules ayant des parois en polyuree
US4091122A (en) *	1976-05-07	1978-05-23	The Mead Corporation	Process for producing pressure-sensitive copy sheets using novel radiation curable coatings

1978
- 1978-01-26 JP JP782378A patent/JPS53109709A/ja active Pending
- 1978-01-31 CA CA296,117A patent/CA1110064A/fr not_active Expired
- 1978-02-27 GB GB774578A patent/GB1601194A/en not_active Expired
- 1978-03-02 DE DE19782808904 patent/DE2808904A1/de not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN114746277B (zh) *	2019-10-11	2024-04-09	多哈科技大学	在环境条件下快速无汞光化学微包封/纳米包封

Also Published As

Publication number	Publication date
DE2808904A1 (de)	1978-09-07
JPS53109709A (en)	1978-09-25
GB1601194A (en)	1981-10-28

Legal Events

Date	Code	Title	Description
1998-10-06	MKEX	Expiry

Publication	Publication Date	Title
CA1110063A (fr)	1981-10-06	Methode de production de feuilles de transfert sensibles a la pression a l'aide de revetements radio- curables nouveau genre
US4110511A (en)	1978-08-29	Process for the production of a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder
US4112138A (en)	1978-09-05	Manifold carbonless form and process for the production thereof
US4200667A (en)	1980-04-29	Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder
US4073968A (en)	1978-02-14	Method for desensitization of a color developer
US4097619A (en)	1978-06-27	Manifold carbonless form and process for the continuous production thereof
US4162165A (en)	1979-07-24	Process for the production of microcapsular coating compositions containing pigment particles and compositions produced thereby
US4228216A (en)	1980-10-14	Production of radiation curable microcapsular coating compositions, pressure-sensitive transfer paper and its production
DE2527154A1 (de)	1976-01-08	Verfahren zur herstellung von oel enthaltenden mikrokapseln
US4230495A (en)	1980-10-28	Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder
DE69002521T2 (de)	1994-01-05	Verfahren zur Herstellung von Mikrokapseln.
US4138508A (en)	1979-02-06	Process for producing pressure-sensitive transfer sheets using novel radiation curable coatings
EP0139543A2 (fr)	1985-05-02	Papier pour l'enregistrement localement sensible à la pression
US4191404A (en)	1980-03-04	Process for producing a pressure-sensitive carbonless copy sheet using microcapsules formed in situ in a radiation curable binder
CA1107955A (fr)	1981-09-01	Formules sans carbone pliees en accordeon, et methode de production continue connexe
US4296947A (en)	1981-10-27	Pressure-sensitive transfer sheets using novel radiation curable coatings
CA1110064A (fr)	1981-10-06	Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable
US4161570A (en)	1979-07-17	Process for the production of radiation curable coating compositions containing microcapsules
CA1109258A (fr)	1981-09-22	Methode de production de compositions de revetement microcapsulaires nouveau genre radiocurables
US4186115A (en)	1980-01-29	Novel radiation curable coating compositions for pressure-sensitive transfer sheets
GB1603448A (en)	1981-11-25	Microcapsules and their use
GB1603239A (en)	1981-11-18	Coating compositions and their production
EP0442507B1 (fr)	1995-05-17	Procédé pour le durcissement et la fixation de particules émulsifiées et feuille d'enregistrement sans carbone sensible à la pression l'utilisant
JP2759936B2 (ja)	1998-05-28	乳化粒子を保護固定化する方法並にこの方法を用いたノーカーボン感圧複写紙
GB1570042A (en)	1980-06-25	Producing manifold carbonless forms

CA1110064A - Methode de production d'une feuille de transfert sans carbone a l'aide de microcapules produites en place dans un liant radiocurable - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=25099668

Family Applications (1)

Country Status (4)

Cited By (1)

Families Citing this family (1)

Family Cites Families (2)

Cited By (1)

Also Published As

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