CA1111074A - Methode de preparation d'hydrocarbures aromatiques - Google Patents

Methode de preparation d'hydrocarbures aromatiques

Info

Publication number: CA1111074A
Authority: CA; Canada
Prior art keywords: catalyst; mixture; hydrocarbons; catalysts; process according
Prior art date: 1977-10-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA310,511A

Other languages

English (en)

Inventor

Lambert Schaper

Swan T. Sie

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-10-26

Filing date

1978-09-01

Publication date

1981-10-20

1978-09-01 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1981-10-20 Application granted granted Critical

1981-10-20 Publication of CA1111074A publication Critical patent/CA1111074A/fr

Status Expired legal-status Critical Current

Links

150000004945 aromatic hydrocarbons Chemical class 0.000 title claims abstract description 15
238000004519 manufacturing process Methods 0.000 title claims abstract description 5
239000003054 catalyst Substances 0.000 claims abstract description 133
239000000203 mixture Substances 0.000 claims abstract description 94
229910052751 metal Inorganic materials 0.000 claims abstract description 46
239000002184 metal Substances 0.000 claims abstract description 46
238000006243 chemical reaction Methods 0.000 claims abstract description 42
229930195733 hydrocarbon Natural products 0.000 claims abstract description 39
239000007789 gas Substances 0.000 claims abstract description 36
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 35
229910001868 water Inorganic materials 0.000 claims abstract description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 25
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 17
239000001301 oxygen Substances 0.000 claims abstract description 17
229910052760 oxygen Inorganic materials 0.000 claims abstract description 17
229910052742 iron Inorganic materials 0.000 claims abstract description 10
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract 3
238000000034 method Methods 0.000 claims description 36
230000008569 process Effects 0.000 claims description 36
230000003197 catalytic effect Effects 0.000 claims description 29
239000000306 component Substances 0.000 claims description 28
229910052739 hydrogen Inorganic materials 0.000 claims description 23
239000001257 hydrogen Substances 0.000 claims description 23
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 20
229910002091 carbon monoxide Inorganic materials 0.000 claims description 20
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
229910017052 cobalt Chemical group 0.000 claims description 9
239000010941 cobalt Chemical group 0.000 claims description 9
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
239000010949 copper Substances 0.000 claims description 7
239000000377 silicon dioxide Substances 0.000 claims description 7
239000011701 zinc Substances 0.000 claims description 7
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
229910052802 copper Inorganic materials 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
150000001768 cations Chemical class 0.000 claims description 4
229910052681 coesite Inorganic materials 0.000 claims description 4
229910052906 cristobalite Inorganic materials 0.000 claims description 4
230000018044 dehydration Effects 0.000 claims description 4
238000006297 dehydration reaction Methods 0.000 claims description 4
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims description 4
229920006395 saturated elastomer Polymers 0.000 claims description 4
235000012239 silicon dioxide Nutrition 0.000 claims description 4
229910052682 stishovite Inorganic materials 0.000 claims description 4
229910052905 tridymite Inorganic materials 0.000 claims description 4
238000006555 catalytic reaction Methods 0.000 claims description 3
QZQVBEXLDFYHSR-UHFFFAOYSA-N gallium(III) oxide Inorganic materials O=[Ga]O[Ga]=O QZQVBEXLDFYHSR-UHFFFAOYSA-N 0.000 claims description 2
239000011859 microparticle Substances 0.000 claims description 2
150000002739 metals Chemical class 0.000 abstract description 12
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 30
229940105305 carbon monoxide Drugs 0.000 description 18
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
150000004760 silicates Chemical class 0.000 description 12
230000006870 function Effects 0.000 description 10
239000003502 gasoline Substances 0.000 description 10
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 9
239000000463 material Substances 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
239000002245 particle Substances 0.000 description 8
-1 acyclic hydrocarbons Chemical class 0.000 description 7
238000009835 boiling Methods 0.000 description 7
238000002309 gasification Methods 0.000 description 7
238000005470 impregnation Methods 0.000 description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
229910052799 carbon Inorganic materials 0.000 description 6
230000000694 effects Effects 0.000 description 6
239000002480 mineral oil Substances 0.000 description 6
235000010446 mineral oil Nutrition 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
238000001354 calcination Methods 0.000 description 4
229910002092 carbon dioxide Inorganic materials 0.000 description 4
239000003245 coal Substances 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000007858 starting material Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
229910052784 alkaline earth metal Inorganic materials 0.000 description 3
239000004411 aluminium Substances 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
239000001569 carbon dioxide Substances 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
239000011651 chromium Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
150000002892 organic cations Chemical class 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000000634 powder X-ray diffraction Methods 0.000 description 3
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
229910052776 Thorium Inorganic materials 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000012876 carrier material Substances 0.000 description 2
238000001833 catalytic reforming Methods 0.000 description 2
DQIPXGFHRRCVHY-UHFFFAOYSA-N chromium zinc Chemical compound [Cr].[Zn] DQIPXGFHRRCVHY-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
229910052733 gallium Inorganic materials 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
238000011835 investigation Methods 0.000 description 2
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(III) nitrate Inorganic materials [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
238000007670 refining Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
JCVAWLVWQDNEGS-UHFFFAOYSA-N 1-(2-hydroxypropylamino)propan-2-ol;thiolane 1,1-dioxide;hydrate Chemical compound O.O=S1(=O)CCCC1.CC(O)CNCC(C)O JCVAWLVWQDNEGS-UHFFFAOYSA-N 0.000 description 1
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 1
102100031830 Afadin- and alpha-actinin-binding protein Human genes 0.000 description 1
101710182459 Afadin- and alpha-actinin-binding protein Proteins 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
QEFDIAQGSDRHQW-UHFFFAOYSA-N [O-2].[Cr+3].[Fe+2] Chemical compound [O-2].[Cr+3].[Fe+2] QEFDIAQGSDRHQW-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
239000003830 anthracite Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
XUZDJUDKWXESQE-UHFFFAOYSA-N chromium copper zinc Chemical compound [Cr].[Zn].[Cu] XUZDJUDKWXESQE-UHFFFAOYSA-N 0.000 description 1
239000000571 coke Substances 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
150000002291 germanium compounds Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000003077 lignite Substances 0.000 description 1
230000002101 lytic effect Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000011148 porous material Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
229960001866 silicon dioxide Drugs 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000011275 tar sand Substances 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
239000002918 waste heat Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/88—Ferrosilicates; Ferroaluminosilicates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
- C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/88—Ferrosilicates; Ferroaluminosilicates
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA310,511A 1977-10-26 1978-09-01 Methode de preparation d'hydrocarbures aromatiques Expired CA1111074A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL7711719		1977-10-26
NL7711719A NL7711719A (nl)	1977-10-26	1977-10-26	Werkwijze voor de bereiding van koolwater- stoffen.

Publications (1)

Publication Number	Publication Date
CA1111074A true CA1111074A (fr)	1981-10-20

Family

ID=19829409

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA310,511A Expired CA1111074A (fr)	1977-10-26	1978-09-01	Methode de preparation d'hydrocarbures aromatiques

Country Status (10)

Country	Link
JP (1)	JPS5470230A (fr)
AU (1)	AU521103B2 (fr)
BE (1)	BE871276A (fr)
CA (1)	CA1111074A (fr)
DE (1)	DE2846254A1 (fr)
FR (1)	FR2407190A1 (fr)
GB (1)	GB2006819B (fr)
IT (1)	IT1099503B (fr)
NL (1)	NL7711719A (fr)
ZA (1)	ZA785979B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5344849A (en) *	1990-10-31	1994-09-06	Canada Chemical Corporation	Catalytic process for the production of hydrocarbons

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5612628A (en) *	1979-07-11	1981-02-07	Olympus Optical Co Ltd	Single-lens reflex camera
NL182469C (nl) *	1979-08-02	1988-03-16	Shell Int Research	Werkwijze voor de bereiding van kristallijne ijzersilicaten; werkwijze voor het uitvoeren van katalytische processen.
NL184214C (nl)	1979-08-06	1989-05-16	Shell Int Research	Werkwijze voor de bereiding van een koolwaterstofmengsel uit een mengsel, dat koolmonoxide en waterstof met een h2/co mol. verhouding van minder dan 1,0 bevat.
NL8001342A (nl) *	1980-03-06	1980-07-31	Shell Int Research	Werkwijze voor het uitvoeren van katalytische omzettingen.
FR2496095B1 (fr) *	1980-12-15	1985-11-15	Shell Int Research	Procede de preparation d'un melange hydrocarbone a partir d'un melange h2/co
NL8101447A (nl) *	1981-03-24	1982-10-18	Shell Int Research	Werkwijze voor de bereiding van koolwaterstoffen uit koolstofhoudend materiaal.
NL8102470A (nl) *	1981-05-20	1982-12-16	Shell Int Research	Werkwijze voor de bereiding van een aromatisch koolwaterstofmengsel.
FR2509719A1 (fr) *	1981-07-17	1983-01-21	Shell Int Research	Procede de production d'hydrocarbures
CA1196617A (fr) *	1982-07-14	1985-11-12	George E. Morris	Lit de catalyse, sa preparation et son emploi en production d'hydrocarbures a partir de gaz de synthese

1977
- 1977-10-26 NL NL7711719A patent/NL7711719A/xx not_active Application Discontinuation
1978
- 1978-09-01 CA CA310,511A patent/CA1111074A/fr not_active Expired
- 1978-10-16 BE BE1009099A patent/BE871276A/xx not_active IP Right Cessation
- 1978-10-24 GB GB7841670A patent/GB2006819B/en not_active Expired
- 1978-10-24 IT IT29061/78A patent/IT1099503B/it active
- 1978-10-24 AU AU41006/78A patent/AU521103B2/en not_active Expired
- 1978-10-24 ZA ZA00785979A patent/ZA785979B/xx unknown
- 1978-10-24 FR FR7830188A patent/FR2407190A1/fr active Granted
- 1978-10-24 JP JP13012878A patent/JPS5470230A/ja active Pending
- 1978-10-24 DE DE19782846254 patent/DE2846254A1/de not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5344849A (en) *	1990-10-31	1994-09-06	Canada Chemical Corporation	Catalytic process for the production of hydrocarbons

Also Published As

Publication number	Publication date
IT7829061A0 (it)	1978-10-24
DE2846254A1 (de)	1979-05-03
AU4100678A (en)	1980-05-01
FR2407190A1 (fr)	1979-05-25
AU521103B2 (en)	1982-03-18
GB2006819A (en)	1979-05-10
GB2006819B (en)	1982-03-17
BE871276A (nl)	1979-04-17
JPS5470230A (en)	1979-06-05
IT1099503B (it)	1985-09-18
FR2407190B1 (fr)	1984-02-03
NL7711719A (nl)	1979-05-01
ZA785979B (en)	1979-10-31

Legal Events

Date	Code	Title	Description
1998-10-20	MKEX	Expiry

Publication	Publication Date	Title
Dry	1981	The fischer-tropsch synthesis
US4385193A (en)	1983-05-24	Process for the preparation of middle distillates
CA1258669A (fr)	1989-08-22	Conversion a selectivite accrue des gaz de synthese en carburants moteur
CA1140157A (fr)	1983-01-25	Methode de preparation d'hydrocarbures
EP0030751B1 (fr)	1984-01-25	Procédé pour la préparation de silicates de fer cristallins
US4443561A (en)	1984-04-17	Process for the preparation of organic compounds
US5338437A (en)	1994-08-16	Method for hydrocracking a heavy hydrocarbon oil utilizing a faujasite aluminosilicate
CA1141779A (fr)	1983-02-22	Methode de preparation d'hydrocarbures, et produits obtenus par la mise en oeuvre de ladite methode
US4410637A (en)	1983-10-18	Process for the preparation of a hydrocarbon mixture from H2 /CO mixtures
Das et al.	1997	Conversion of syngas to light olefins over silicalite-1 supported iron and cobalt catalysts: Effect of manganese addition
GB2073237A (en)	1981-10-14	Process for the Preparation of Hydrocarbons and Hydrocarbons so Prepared
JPS6411566B2 (fr)	1989-02-27
GB2053713A (en)	1981-02-11	A process for the preparation of Fischer-Tropsch catalysts
US4617320A (en)	1986-10-14	Enhanced conversion of syngas to liquid motor fuels
CA1121834A (fr)	1982-04-13	Methode de preparation des hydrocarbures
JPH01500571A (ja)	1989-03-01	改良されたバナジウム、稀土類金属含有スピネル組成物及びその使用方法
US4218388A (en)	1980-08-19	Process for preparing hydrocarbons from gasification of coal
JPS631297B2 (fr)	1988-01-12
EP0018683A1 (fr)	1980-11-12	Procédé de préparation d'hydrocarbures et hydrocarbures ainsi préparés
CA1111073A (fr)	1981-10-20	Procede de preparation d'hydrocarbures aromatiques
CA1127670A (fr)	1982-07-13	Methode de production d'hydrocarbures
EP0192289B1 (fr)	1989-12-13	Procédé pour la production d'un mélange contenant des hydrocarbures aromatiques
EP0051326B1 (fr)	1984-07-04	Procédé pour la préparation d'hydrocarbures
CA1117054A (fr)	1982-01-26	Methode de preparation d'un carburant automobile a partir de la houille
JPH0113453B2 (fr)	1989-03-06

CA1111074A - Methode de preparation d'hydrocarbures aromatiques - Google Patents

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Applications Claiming Priority (2)

Publications (1)

Family

ID=19829409

Family Applications (1)

Country Status (10)

Cited By (1)

Families Citing this family (9)

Cited By (1)

Also Published As

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