CA1112378A - Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium - Google Patents

Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium

Info

Publication number: CA1112378A
Authority: CA; Canada
Prior art keywords: water; coal; emulsion; oil; sodium polyacrylate
Prior art date: 1978-01-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA313,069A

Other languages

English (en)

Inventor

Robert E. Finch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ChampionX LLC

Original Assignee

Nalco Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-01-19

Filing date

1978-10-11

Publication date

1981-11-10

1978-01-19 Priority claimed from US05/870,559 external-priority patent/US4162966A/en

1978-10-11 Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co

1981-11-10 Application granted granted Critical

1981-11-10 Publication of CA1112378A publication Critical patent/CA1112378A/fr

Status Expired legal-status Critical Current

Links

239000003245 coal Substances 0.000 title claims abstract description 66
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 title claims abstract description 26
229920001495 poly(sodium acrylate) polymer Polymers 0.000 title claims abstract description 25
239000000839 emulsion Substances 0.000 title claims abstract description 24
238000005188 flotation Methods 0.000 title claims abstract description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
239000003795 chemical substances by application Substances 0.000 claims abstract description 12
238000000034 method Methods 0.000 claims abstract description 12
239000012190 activator Substances 0.000 claims abstract description 8
239000002245 particle Substances 0.000 claims abstract description 8
238000009291 froth flotation Methods 0.000 claims abstract description 5
239000002904 solvent Substances 0.000 claims abstract description 5
230000002209 hydrophobic effect Effects 0.000 claims abstract description 4
239000004094 surface-active agent Substances 0.000 claims abstract description 4
239000003995 emulsifying agent Substances 0.000 claims abstract description 3
239000007764 o/w emulsion Substances 0.000 claims abstract description 3
239000007762 w/o emulsion Substances 0.000 claims description 9
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
239000008346 aqueous phase Substances 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
239000003381 stabilizer Substances 0.000 claims description 2
230000000087 stabilizing effect Effects 0.000 claims description 2
229920000642 polymer Polymers 0.000 abstract description 16
239000004816 latex Substances 0.000 abstract description 14
229920000126 latex Polymers 0.000 abstract description 14
239000000203 mixture Substances 0.000 abstract description 7
239000012188 paraffin wax Substances 0.000 abstract description 3
ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 abstract description 2
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 abstract description 2
239000001593 sorbitan monooleate Substances 0.000 abstract description 2
229940035049 sorbitan monooleate Drugs 0.000 abstract description 2
235000011069 sorbitan monooleate Nutrition 0.000 abstract description 2
229920002367 Polyisobutene Polymers 0.000 abstract 1
125000003118 aryl group Chemical group 0.000 abstract 1
238000011084 recovery Methods 0.000 description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
229910052760 oxygen Inorganic materials 0.000 description 8
239000001301 oxygen Substances 0.000 description 8
239000007787 solid Substances 0.000 description 6
-1 butyl alcohols Chemical class 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 4
NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000178 monomer Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
230000003647 oxidation Effects 0.000 description 4
238000007254 oxidation reaction Methods 0.000 description 4
229920000058 polyacrylate Polymers 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000011707 mineral Substances 0.000 description 3
235000010755 mineral Nutrition 0.000 description 3
229940070721 polyacrylate Drugs 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
230000005484 gravity Effects 0.000 description 2
239000012071 phase Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000007858 starting material Substances 0.000 description 2
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
GONFBOIJNUKKST-UHFFFAOYSA-N 5-ethylsulfanyl-2h-tetrazole Chemical compound CCSC=1N=NNN=1 GONFBOIJNUKKST-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
235000006173 Larrea tridentata Nutrition 0.000 description 1
244000073231 Larrea tridentata Species 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229920006318 anionic polymer Polymers 0.000 description 1
238000013459 approach Methods 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229960002126 creosote Drugs 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
PYRZPBDTPRQYKG-UHFFFAOYSA-N cyclopentene-1-carboxylic acid Chemical compound OC(=O)C1=CCCC1 PYRZPBDTPRQYKG-UHFFFAOYSA-N 0.000 description 1
238000011161 development Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000005660 hydrophilic surface Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000010665 pine oil Substances 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920000582 polyisocyanurate Polymers 0.000 description 1
239000011495 polyisocyanurate Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000002002 slurry Substances 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
238000010301 surface-oxidation reaction Methods 0.000 description 1
FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
238000013519 translation Methods 0.000 description 1
230000014616 translation Effects 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/08—Coal ores, fly ash or soot

Landscapes

Liquid Carbonaceous Fuels (AREA)
Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Processing Of Solid Wastes (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Solid Fuels And Fuel-Associated Substances (AREA)

CA313,069A 1978-01-19 1978-10-11 Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium Expired CA1112378A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/870,559 US4162966A (en)	1976-06-16	1978-01-19	Flotation of deep mined coal with water-in-oil emulsions of sodium polyacrylate
US870,559		1978-01-19

Publications (1)

Publication Number	Publication Date
CA1112378A true CA1112378A (fr)	1981-11-10

Family

ID=25355647

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA313,069A Expired CA1112378A (fr)	1978-01-19	1978-10-11	Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium

Country Status (9)

Country	Link
AU (1)	AU507430B2 (fr)
CA (1)	CA1112378A (fr)
DE (1)	DE2850988A1 (fr)
ES (1)	ES475446A2 (fr)
FR (1)	FR2414958A2 (fr)
GB (1)	GB2012621B (fr)
GR (1)	GR70023B (fr)
MX (1)	MX154137A (fr)
ZA (1)	ZA786278B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5599356A (en) *	1979-01-25	1980-07-29	Dow Chemical Co	Additive for alkanol amineetolu oil fatty acid coal flotation method
GB2171929B (en) *	1985-03-08	1988-09-01	Cargo Fleet Chemical Co	Improvements relating to particle separation
US6959815B2 (en)	2002-01-28	2005-11-01	The Governors Of The University Of Alberta	Selective reactive oily bubble carriers in flotation processes and methods of generation and uses thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1002702B (de) *	1955-12-29	1957-02-21	Basf Ag	Verfahren zur Schaumschwimmaufbereitung, insbesondere von Steinkohle
US3079331A (en) *	1959-08-27	1963-02-26	American Cyanamid Co	Process of recovering coal fines
FR1252870A (fr) *	1960-01-29	1961-02-03	United States Borax Chem	Procédé d'élimination de l'argile à partir de sylvinite
FR1519540A (fr) *	1966-05-11	1968-04-05	Prod Chim D Auby Soc D	Procédé et produits pour la flottation de minéraux et minerais à gangue calcaire et dolomitique, tels que minerais oxydés, de cuivre notamment
AU4720072A (en) *	1971-10-08	1974-04-04	Tci. AUSTRALIAN MINERAL DEVELOPMENT LABORATORIES	Ore flotation process

1978
- 1978-10-11 CA CA313,069A patent/CA1112378A/fr not_active Expired
- 1978-11-07 ZA ZA00786278A patent/ZA786278B/xx unknown
- 1978-11-08 GB GB7843583A patent/GB2012621B/en not_active Expired
- 1978-11-08 GR GR57608A patent/GR70023B/el unknown
- 1978-11-21 AU AU41771/78A patent/AU507430B2/en not_active Expired
- 1978-11-23 DE DE19782850988 patent/DE2850988A1/de not_active Withdrawn
- 1978-11-24 MX MX175745A patent/MX154137A/es unknown
- 1978-11-27 FR FR7833423A patent/FR2414958A2/fr active Granted
- 1978-11-27 ES ES475446A patent/ES475446A2/es not_active Expired

Also Published As

Publication number	Publication date
MX154137A (es)	1987-05-26
FR2414958A2 (fr)	1979-08-17
FR2414958B2 (fr)	1981-12-31
ZA786278B (en)	1979-10-31
GR70023B (fr)	1982-07-23
AU4177178A (en)	1979-08-23
ES475446A2 (es)	1980-01-16
AU507430B2 (en)	1980-02-14
GB2012621B (en)	1982-06-16
GB2012621A (en)	1979-08-01
DE2850988A1 (de)	1979-07-19

Legal Events

Date	Code	Title	Description
1998-11-10	MKEX	Expiry

Publication	Publication Date	Title
EP3052242B1 (fr)	2022-06-29	Méthode d'amélioration de la performance des collecteurs dans la flottation des minéraux
EP0662865B1 (fr)	1997-04-02	Procede de flottation de charbon
US4340467A (en)	1982-07-20	Flotation of coal with latex emulsions of hydrocarbon animal or vegetable based oil
US4338185A (en)	1982-07-06	Recovery of oil from oil sands
US4162966A (en)	1979-07-31	Flotation of deep mined coal with water-in-oil emulsions of sodium polyacrylate
US4392892A (en)	1983-07-12	Process for separating hydrocarbons from particulate solids
US7992718B1 (en)	2011-08-09	Method for enhancing selectivity and recovery in the fractional flotation of particles in a flotation column
US4222862A (en)	1980-09-16	Flotation of oxidized coal with a latex emulsion of sodium polyacrylate used as a promoter
US4532032A (en)	1985-07-30	Polyorganosiloxane collectors in the beneficiation of fine coal by froth flotation
US4857221A (en)	1989-08-15	Recovering coal fines
US4756823A (en)	1988-07-12	Particle separation
CA1112378A (fr)	1981-11-10	Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium
JPH0148822B2 (fr)	1989-10-20
US4222861A (en)	1980-09-16	Treatment and recovery of larger particles of fine oxidized coal
CN107427841A (zh)	2017-12-01	矿石浮选的抑制剂
US8136669B2 (en)	2012-03-20	Process and composition for froth flotation
CA2064383A1 (fr)	1992-09-29	Flottation par moussage de fines particules
Burkin et al.	1963	Flotation with insoluble reagents. II. Effects of surface‐active reagents on the spreading of oil at coal‐water interfaces
Ellis et al.	1973	Clarifying oilfield and refinery waste waters by gas flotation
CN1021415C (zh)	1993-06-30	用于从煤中分离天然二硫化铁的天然泡沫浮选方法
GB1593805A (en)	1981-07-22	Flotation of oxidized coal with a latex emulsion of sodium polyacrylate
US4272364A (en)	1981-06-09	Frother for coal flotation
Tsai et al.	1984	Oil shale beneficiation by froth flotation
US4482454A (en)	1984-11-13	Process for treating cassiterite ore
CN103772626B (zh)	2016-04-27	梳型高分子浮选剂的制备方法