CA1112607A - Electrodes faites d'oxydes de metal de transition - Google Patents

Electrodes faites d'oxydes de metal de transition

Info

Publication number: CA1112607A
Authority: CA; Canada
Prior art keywords: coating; semi; tin; transition metal; titanium
Prior art date: 1977-05-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA279,431A

Other languages

English (en)

Inventor

David L. Lewis

Charles R. Franks, (Deceased)

Barry A. Schenker

Mary R. Suchanski

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Diamond Shamrock Corp

Original Assignee

Diamond Shamrock Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-05-30

Filing date

1977-05-30

Publication date

1981-11-17

1977-05-30 Application filed by Diamond Shamrock Corp filed Critical Diamond Shamrock Corp

1977-05-30 Priority to CA279,431A priority Critical patent/CA1112607A/fr

1981-11-17 Application granted granted Critical

1981-11-17 Publication of CA1112607A publication Critical patent/CA1112607A/fr

Status Expired legal-status Critical Current

Links

229910000314 transition metal oxide Inorganic materials 0.000 title claims description 5
238000000576 coating method Methods 0.000 claims abstract description 84
239000011248 coating agent Substances 0.000 claims abstract description 70
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 52
229910052719 titanium Inorganic materials 0.000 claims abstract description 48
239000010936 titanium Substances 0.000 claims abstract description 48
238000000034 method Methods 0.000 claims abstract description 34
239000000758 substrate Substances 0.000 claims abstract description 26
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 25
229910052751 metal Inorganic materials 0.000 claims abstract description 24
239000002184 metal Substances 0.000 claims abstract description 24
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 14
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 14
230000008569 process Effects 0.000 claims abstract description 14
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052721 tungsten Inorganic materials 0.000 claims abstract description 11
239000010937 tungsten Substances 0.000 claims abstract description 11
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 10
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 10
239000011733 molybdenum Substances 0.000 claims abstract description 10
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052804 chromium Inorganic materials 0.000 claims abstract description 8
239000011651 chromium Substances 0.000 claims abstract description 8
229910017052 cobalt Inorganic materials 0.000 claims abstract description 8
239000010941 cobalt Substances 0.000 claims abstract description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052742 iron Inorganic materials 0.000 claims abstract description 7
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
239000000543 intermediate Substances 0.000 claims description 28
229910052718 tin Inorganic materials 0.000 claims description 19
150000001463 antimony compounds Chemical class 0.000 claims description 16
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 claims description 15
238000009713 electroplating Methods 0.000 claims description 12
229910052723 transition metal Inorganic materials 0.000 claims description 12
150000003624 transition metals Chemical class 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 8
229910052787 antimony Inorganic materials 0.000 claims description 7
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 7
238000001035 drying Methods 0.000 claims description 7
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
229910045601 alloy Inorganic materials 0.000 claims description 4
239000000956 alloy Substances 0.000 claims description 4
229910052782 aluminium Inorganic materials 0.000 claims description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
229910052758 niobium Inorganic materials 0.000 claims description 4
239000010955 niobium Substances 0.000 claims description 4
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
230000001590 oxidative effect Effects 0.000 claims description 4
238000010422 painting Methods 0.000 claims description 4
229910052715 tantalum Inorganic materials 0.000 claims description 4
229910052726 zirconium Inorganic materials 0.000 claims description 4
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
229910000385 transition metal sulfate Inorganic materials 0.000 claims description 2
229910002001 transition metal nitrate Inorganic materials 0.000 claims 3
229910000410 antimony oxide Inorganic materials 0.000 abstract description 8
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract description 8
229910001887 tin oxide Inorganic materials 0.000 abstract description 7
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 6
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 46
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 31
239000000243 solution Substances 0.000 description 22
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 15
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
239000000463 material Substances 0.000 description 12
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
239000007864 aqueous solution Substances 0.000 description 9
239000000203 mixture Substances 0.000 description 9
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 8
239000000126 substance Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 5
YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 5
-1 m~ybdenum Chemical compound 0.000 description 5
229910052697 platinum Inorganic materials 0.000 description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
229910000978 Pb alloy Inorganic materials 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
230000001680 brushing effect Effects 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
239000003792 electrolyte Substances 0.000 description 4
229940099596 manganese sulfate Drugs 0.000 description 4
235000007079 manganese sulphate Nutrition 0.000 description 4
239000011702 manganese sulphate Substances 0.000 description 4
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
230000004584 weight gain Effects 0.000 description 4
235000019786 weight gain Nutrition 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 3
238000007598 dipping method Methods 0.000 description 3
238000005363 electrowinning Methods 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000011148 porous material Substances 0.000 description 3
235000011149 sulphuric acid Nutrition 0.000 description 3
YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 3
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 2
239000002585 base Substances 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
238000011109 contamination Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000004070 electrodeposition Methods 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
230000006872 improvement Effects 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000001117 sulphuric acid Substances 0.000 description 2
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
229910001339 C alloy Inorganic materials 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
101100311312 Mus musculus Strip2 gene Proteins 0.000 description 1
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
229910008046 SnC14 Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
GZMKWMMWAHQTHD-UHFFFAOYSA-L [Mn++].OS([O-])(=O)=O.OS([O-])(=O)=O Chemical compound [Mn++].OS([O-])(=O)=O.OS([O-])(=O)=O GZMKWMMWAHQTHD-UHFFFAOYSA-L 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000007605 air drying Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
238000004210 cathodic protection Methods 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
229940045032 cobaltous nitrate Drugs 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000002848 electrochemical method Methods 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
238000004134 energy conservation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000005530 etching Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
229910001867 inorganic solvent Inorganic materials 0.000 description 1
239000003049 inorganic solvent Substances 0.000 description 1
239000011133 lead Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000005457 optimization Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000002161 passivation Methods 0.000 description 1
150000004686 pentahydrates Chemical class 0.000 description 1
238000007747 plating Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000012827 research and development Methods 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000005488 sandblasting Methods 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
FPADWGFFPCNGDD-UHFFFAOYSA-N tetraethoxystannane Chemical compound [Sn+4].CC[O-].CC[O-].CC[O-].CC[O-] FPADWGFFPCNGDD-UHFFFAOYSA-N 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
150000003606 tin compounds Chemical class 0.000 description 1
229910000375 tin(II) sulfate Inorganic materials 0.000 description 1
230000007704 transition Effects 0.000 description 1
239000002699 waste material Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Electrodes For Compound Or Non-Metal Manufacture (AREA)

CA279,431A 1977-05-30 1977-05-30 Electrodes faites d'oxydes de metal de transition Expired CA1112607A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA279,431A CA1112607A (fr)	1977-05-30	1977-05-30	Electrodes faites d'oxydes de metal de transition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA279,431A CA1112607A (fr)	1977-05-30	1977-05-30	Electrodes faites d'oxydes de metal de transition

Publications (1)

Publication Number	Publication Date
CA1112607A true CA1112607A (fr)	1981-11-17

Family

ID=4108762

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA279,431A Expired CA1112607A (fr)	1977-05-30	1977-05-30	Electrodes faites d'oxydes de metal de transition

Country Status (1)

Country	Link
CA (1)	CA1112607A (fr)

1977
- 1977-05-30 CA CA279,431A patent/CA1112607A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1998-11-17	MKEX	Expiry

Publication	Publication Date	Title
US4125449A (en)	1978-11-14	Transition metal oxide electrodes
US4243503A (en)	1981-01-06	Method and electrode with admixed fillers
US3882002A (en)	1975-05-06	Anode for electrolytic processes
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US4070504A (en)	1978-01-24	Method of producing a valve metal electrode with valve metal oxide semi-conductor face and methods of manufacture and use
US4142005A (en)	1979-02-27	Process for preparing an electrode for electrolytic cell having a coating of a single metal spinel, Co3 O4
EP0014596B1 (fr)	1983-09-14	Procédé de fabrication d'électrodes portant une couche de revêtement catalytiquement active à base de mélanges d'oxydes métalliques
CA1075202A (fr)	1980-04-08	Electrode au bioxyde de plomb
KR100735588B1 (ko)	2007-07-04	수용액의 전해용 캐쏘드
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US3986942A (en)	1976-10-19	Electrolytic process and apparatus
US4208450A (en)	1980-06-17	Transition metal oxide electrodes
US4265728A (en)	1981-05-05	Method and electrode with manganese dioxide coating
US4180445A (en)	1979-12-25	Oxygen selective anode
US4670122A (en)	1987-06-02	Low over-voltage electrodes for alkaline electrolytes
CA1112607A (fr)	1981-11-17	Electrodes faites d'oxydes de metal de transition
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JPS633031B2 (fr)	1988-01-21
IL38959A (en)	1974-12-31	Electrodes for electrochemical processes
JP5456744B2 (ja)	2014-04-02	金属電解採取方法
US3969217A (en)	1976-07-13	Electrolytic anode
박소영 et al.	1995	Characteristics of Ru and $ RuO_2 $ Thin Films on the Conductive Ceramics TiO and Ebonex ($ Ti_4O_7 $)
CA1110932A (fr)	1981-10-20	Methode d'enrobage d'electrodes
FI57448B (fi)	1980-04-30	Elektrod foer elektrokemiska processer
JPS6125789B2 (fr)	1986-06-17